Investigation of Water Safety in Non-treated Drinking Water with Trace Toxic Metals
Toxicological Research
;
: 211-215, 2013.
Article
in English
| WPRIM
| ID: wpr-193672
ABSTRACT
The trace toxic metal copper was assayed using mercury immobilized on a carbon nanotube electrode (MCW), with a graphite counter and a reference electrode. In this study, a macro-scale convection motor was interfaced with a MCW three-electrode system, in which a handmade MCW was optimized using cyclic-and square-wave stripping voltammetry. An analytical electrolyte for tap water was used instead of an expensive acid or base ionic solution. Under these conditions, optimum parameters were 0.09 V amplitude, 40 Hz frequency, 0.01 V incremental potential, and a 60-s accumulation time. A diagnostic working curve was obtained from 50.0 to 350 microg/L. At a constant Cu(II) concentration of 10.0 microg/L, the statistical relative standard deviation was 1.78% (RSD, n = 15), the analytical accumulation time was only 60 s, and the analytical detection limit approached 4.6 microg/L (signal/noise = 3). The results were applied to non-treated drinking water. The content of the analyzed copper using 9.0 and 4.0 microg/L standards were 8.68 microg/L and 3.96 microg/L; statistical values R2 = 0.9987 and R2 = 0.9534, respectively. This method is applicable to biological diagnostics or food surveys.
Full text:
Available
Index:
WPRIM (Western Pacific)
Main subject:
Organothiophosphorus Compounds
/
Reference Standards
/
Drinking Water
/
Convection
/
Copper
/
Nanotubes, Carbon
/
Diagnosis
/
Drinking
/
Electrodes
/
Limit of Detection
Type of study:
Diagnostic study
/
Practice guideline
Language:
English
Journal:
Toxicological Research
Year:
2013
Type:
Article
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