Geochemical processes, salinity sources and utility characterization of groundwater in a semi-arid region of Iraq through geostatistical and isotopic techniques.

Identifying factors contributing to water salinity is paramount in efficiently managing limited water resources in arid environments. The primary objective of this study is to enhance understanding regarding the hydrochemistry, source, and mechanism of water salinity, as well as to assess the suitability of water for various uses in southern Iraq. The groundwater samples were collected from water wells and springs and analyzed for major cations and anions along with stable isotopes (δ18O and δ2H) to accomplish the objective. The analysis of major ion chemistry, hydrochemical techniques, principal component analysis (PCA), and isotope signatures were adopted to determine the primary factors contributing to water mineralization. The study inferred that evaporation and geological processes encompassing water-rock interactions, such as dissolution precipitation and ion exchange, were key processes. The stable isotope analysis revealed that the water originated from meteoric sources and underwent significant evaporation during or before infiltration. The utility assessment of water samples indicates that most samples are not appropriate for consumption and are significantly below the established standards for potable water. In contrast, a significant portion of the groundwater samples were found to meet the criteria for irrigation suitability by adopting Wilcox and the US Salinity Laboratory criteria. The groundwater could be considered for irrigation with proper salinity control management. Overall, this study has significantly improved the understanding of the hydrogeochemical regimes and acts as a first step toward the sustainable utilization of water resources.

Flood susceptibility mapping utilizing the integration of geospatial and multivariate statistical analysis, Erbil area in Northern Iraq as a case study.

Climate extreme events such as floods and droughts in any area have a significant impact on human life, infrastructure, agriculture, and the economy. In the last two years, flash floods caused by heavy rainstorms have become frequent and destructive in many catchments in Northern Iraq. The present study aims to examine flash floods in the Erbil region, Northern Iraq using Remote sensing (RS), Geographic Information System (GIS), and Principal Component Analysis (PCA) for geomorphic data. PCA results revealed that 12 geomorphic parameters exhibited a significant correlation with two different statistical components. To facilitate practical application, ranks are assigned based on the calculated parameters for flood susceptibility mapping. Out of the 24 basins in the current study, three basins (16, 3, and 14) have the highest geomorphometric values (36-39), indicating the zone most susceptible to flash floods and making up a maximum area of 38.58% of the studied region. Six basins (4, 8, 9, 10, 12, and 15), which have geomorphometric values between 30 and 35 and cover a land area of 27.86%, are the most moderately vulnerable to floods. The remaining basins, which make up 33.47% of the research, are occasionally subject to floods and have geomorphometric scores below 30. The precision of the flood susceptibility mapping was validated using the bifurcation ratio and drainage density relationship as well as past flood damages, such as economic losses and human casualties. Most of the recorded injuries and fatalities took place in areas that were particularly prone to severe past flooding. Additionally, the investigation revealed that 44.56% of all populated areas are located in extremely vulnerable basins. The findings demonstrate a notable correlation between the identified flood-susceptible areas and the occurrence of past flood damage.

Novel concept for water scarcity quantification considering nonconventional and virtual water resources in arid countries: Application in Gulf Cooperation Council countries.

The lack of perennial streams or surface water in most arid countries necessitates input modification and water scarcity/security equation calculation as per the water resource systems and physiographic conditions in these countries. The contributions of nonconventional and virtual water resources to water security have been disregarded or undervalued in previous research on global water scarcity. This study addresses this knowledge gap by developing a new framework for estimating water scarcity/security. The proposed framework considers the contributions of unconventional and virtual water resources and the roles of economics, technology, water availability, service accessibility, water safety and quality, water management, and resilience to threats on water and food security, and considers institutional changes required to adjust to water scarcity. To manage water demand, the new framework incorporates metrics for all categories of water resources. Although the framework was specifically designed for arid regions, particularly the Gulf Cooperation Council (GCC) countries, it is applicable to non-arid nations too. The framework was implemented in GCC countries, which are suitable examples of arid countries with notable virtual commerce. The ratio of abstraction from freshwater resources to renewability from conventional water sources was calculated to determine the extent of water stress in each country. The values obtained from measurement varied from 0.4 (the optimal threshold level for Bahrain) to 22 (severe water stress/low water security in Kuwait). Considering the nonconventional and abstracted nonrenewable groundwater volumes from the total water demand in the GCC, the minimum water stress value measured was 0.13 in Kuwait, suggesting considerable reliance on nonconventional water resources along with little domestic food production to achieve water security. The novel water scarcity/stress index framework was found to be appropriate for arid and hyper-arid regions, such as the GCC, where virtual water trade has a major positive impact on water security.

A multi-isotopic evaluation of groundwater in a rapidly developing area and implications for water management in hyper-arid regions.

Management of water resources in hyper-arid areas faces vital challenges in a global climate change context. Consequently, understanding the effects on groundwater sources can help mitigating the problem of water scarcity and the negative impact of human intervention on the environment. A case study area in the hyper-arid climate of the United Arab Emirates, was tackled here with the focus on applying stable isotopes as tools for evaluating groundwater sources and quality assessment. The results of major ions indicate variable increase in groundwater salinity moving away from Al Hajar Mountains recharge areas to the discharge areas (Arabian Gulf coast). The data of stable isotopes (δ18OH2O, δ2HH2O, δ18ONO3, δ15NNO3, δ18OSO4, δ34SSO4, δ11B) suggest impact of paleo-groundwater in the abstractions of the wells nearest to the coast. Nitrate isotopes indicate farming activities sources that can be masked due to the contribution from the nitrate-poor paleo-groundwater. Nitrate reduction processes are expected near to the recharge front. Sulphate and boron isotopes further suggest that influence of ancient evaporite dissolution in salinization. Management efforts should be focused on the diffuse sources of quality mitigations that can be vital in fingerprinting local and regional (transboundary) effects.