1.
Acta Crystallogr Sect E Struct Rep Online
; 64(Pt 11): m1435, 2008 Oct 18.
Artículo
en Inglés
| MEDLINE
| ID: mdl-21580878
RESUMEN
A discrete neutral Cu(II) complex, [Cu(CF(3)SO(3))(2)(C(16)H(18)N(4))], has been derived from the symmetrical tetra-dentate Schiff base, N,N'-bis-[1-(pyridin-2-yl)ethyl-idene]ethane-1,2-diamine. The copper centre assumes a tetra-gonally distorted pseudo-octa-hedral geometry with the O atoms of two trifluoro-methane-sulfonate anions coordinated weakly in the axial positions. The Cu-N distances lie in the range 1.941â (3)-2.011â (3)â Å and the Cu-O distances are 2.474â (3) and 2.564â (3)â Å.