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We theoretically demonstrate the possibility of inversion of solvent migration in charged membranes, opposing osmosis. Inversion of solvent migration is ascribed to the finite volume of ions in the solution permeating the membrane, a quantity that has been neglected in the literature so far. We propose a model of the electrochemistry in the proximity of an electrode, illustrating the range of the molar volume of ions that can yield the inversion of solvent migration. This study poses the basis for novel applications in microfluidics, nanofluidics, and electrochemistry, along with new inquiries in biology.
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We demonstrate a novel principle of contactless actuation for ionic membranes in salt solution based on solvation. Actuation is driven by differential swelling of the sides of the membrane, due to comigrating water in the solvation shells of mobile ions. We validate our theory through a series of experiments, which unravel a strong dependence of membrane deflection on the hydration numbers of mobile ions in the external solution and membrane. Our study suggests a critical role of solvation in the chemoelectromechanics of natural and artificial selectively permeable membranes.
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Membranas/química , Modelos Químicos , Cationes/química , Electroquímica , Soluciones/químicaRESUMEN
Recurrence plots and recurrence quantification analysis are powerful tools to study the behavior of dynamical systems. What we learn through these tools is typically determined by the choice of a distance threshold in the phase space, which introduces arbitrariness in the definition of recurrence. Not only does symbolic recurrence overcome this difficulty, but also it offers a richer representation that book-keeps the recurrent portions of the phase space. Using symbolic recurrences, we can construct recurrence plots, perform quantification analysis, and examine causal links between dynamical systems from their time-series. Although previous efforts have demonstrated the feasibility of such a symbolic framework on synthetic data, the study of real time-series remains elusive. Here, we seek to bridge this gap by systematically examining a wide range of experimental datasets, from firearm prevalence and media coverage in the United States to the effect of sex on the interaction of swimming fish. This work offers a compelling demonstration of the potential of symbolic recurrence in the study of real-world applications across different research fields while providing a computer code for researchers to perform their own time-series explorations.
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Bases de Datos Factuales , Modelos Teóricos , Humanos , Estados UnidosRESUMEN
Stigmergy, the indirect communication between agents of a swarm through dynamic environmental modifications, is a fundamental self-organization mechanism of animal swarms. Engineers have drawn inspiration from stigmergy to establish strategies for the coordination of swarms of robots and of mixed societies of robots and animals. Currently, all models of stigmergy are algorithmic, in the form of behavioural rules implemented at an individual level. A critical challenge for the understanding of stigmergic behaviour and translation of stigmergy to engineering is the lack of a holistic approach to determine which modifications of the environment are necessary to achieve desired behaviours for the swarm. Here, we propose a mathematical framework that rigorously describes the relationship between environmental modifications and swarm behaviour. Building on recent strides in continuification techniques, we model the swarm and environmental modifications as continua. This approach allows us to design the environmental modifications required for the swarm to behave as desired. Through analytical derivations and numerical simulations of one- and two-dimensional examples, we show that our framework yields the distribution of traces required to achieve a desired formation. Such an approach provides an adaptable framework for different implementation platforms, from robotic swarms to mixed societies of robots and animals.
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Haptic technology is a critical component of human-computer interfaces. Traditional haptic actuators are often unable to provide the broad frequency range and latency that is required in many advanced applications. To address this problem, we propose a new type of tactor based on macro-fiber composites (MFCs), composites of piezoelectric fibers. We propose a physics-based model for the actuation of the tactors, calibrated and validated through experiments. As our tactors are intended for haptic applications, we consider the role of skin on their response, an aspect seldom analyzed in the literature. In our experiments, we simulate the presence of the skin with a rubber membrane in contact with the tactor, with varying pre-stretch, mimicking different indentations of the tactor on the skin. The MFC-based tactor can always generate vibration amplitudes higher than skin discrimination thresholds, over the range of frequencies of interest for haptics, with a latency much smaller than traditional actuators. We theoretically investigate the effect of the skin on tactor vibrations, highlighting the individual roles of skin stiffness and damping and their combined effect across a series of pre-stretches. Our tactor shows promise in haptic applications, including assistive technologies and real-time feedback systems for training, safety, and monitoring.
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Percepción del Tacto , Humanos , Percepción del Tacto/fisiología , Interfaces Hápticas , Tecnología Háptica , Piel , RetroalimentaciónRESUMEN
Visual impairment represents a significant health and economic burden affecting 596 million globally. The incidence of visual impairment is expected to double by 2050 as our population ages. Independent navigation is challenging for persons with visual impairment, as they often rely on non-visual sensory signals to find the optimal route. In this context, electronic travel aids are promising solutions that can be used for obstacle detection and/or route guidance. However, electronic travel aids have limitations such as low uptake and limited training that restrict their widespread use. Here, we present a virtual reality platform for testing, refining, and training with electronic travel aids. We demonstrate the viability on an electronic travel aid developed in-house, consist of a wearable haptic feedback device. We designed an experiment in which participants donned the electronic travel aid and performed a virtual task while experiencing a simulation of three different visual impairments: age-related macular degeneration, diabetic retinopathy, and glaucoma. Our experiments indicate that our electronic travel aid significantly improves the completion time for all the three visual impairments and reduces the number of collisions for diabetic retinopathy and glaucoma. Overall, the combination of virtual reality and electronic travel aid may have a beneficial role on mobility rehabilitation of persons with visual impairment, by allowing early-phase testing of electronic travel aid prototypes in safe, realistic, and controllable settings.
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A variety of modeling frameworks have been proposed for ionic polymer metal composites (IPMCs), but the physical underpinnings of their actuation remain elusive. A critical step toward the validation of existing theories and transition to engineering practice entails the design of new experimental paradigms that could support hypothesis-driven research. While several factors exacerbate the complexity of experimenting with IPMCs, the presence of the electrodes plays a major role by hindering the repeatability of the results and bringing a number of difficult-to-measure parameters into the picture. Here, we seek to address these experimental confounds by investigating contactless actuation of perfluorinated ionomer membranes in salt solution. In contrast to IPMCs that bend toward the anode in response to an applied voltage, ionomer membranes display a consistent deflection toward the cathode. Through hypothesis-driven experiments where the membrane width, solution concentration, and voltage applied across the electrodes are systematically varied, we elucidate electrochemistry and mechanics of contactless actuation. The applied voltage and solution concentration have a dominant role on the electrochemistry, while mechanics is mainly affected by the applied voltage and membrane width. Our results depict a complex scenario, which is expected to inform future theoretical inquiries about IPMC actuation.