RESUMEN
Accurate online water quality measurements have gained attention during the last decades in the oil and gas industry for improving operational performance and protecting the surrounding environment. One potential solution to extend the reservoirs' economic life and put less strain on the environment is by re-injecting the produced water, but the injected water quality must be high and consistent to prevent injectivity reduction. This paper evaluates two different online microscopy analyzers that utilize a high-resolution video camera for capturing images of the particles passing their view cell. The calibration procedure for both online microscopy analyzers has been thoroughly validated for steady-state and real-time measurements. The real-time measurements were achieved by post-processing the data captured by the microscopes and applying a trailing moving average window. The performance of measuring the oil-in-water concentration was compared with an online fluorescence-based monitor. The paper addresses the statistical considerations when defining the level of accuracy of the predicted particle size distribution within a defined confidence interval. Both microscopes showed promising results for measuring known particle sizes and oil-in-water concentrations, both in steady-state and real-time.
RESUMEN
Offshore oil and gas facilities are currently measuring the oil-in-water (OiW) concentration in the produced water manually before discharging it into the ocean, which in most cases fulfills the government regulations. However, as stricter regulations and environmental concerns are increasing over time, the importance of measuring OiW in real-time intensifies. The significant amount of uncertainties associated with manual samplings, that is currently not taken into consideration, could potentially affect the acceptance of OiW monitors and lower the reputation of all online OiW measurement techniques. This work presents the performance of four fluorescence-based monitors on an in-house testing facility. Previous studies of a fluorescence-based monitor have raised concerns about the measurement of OiW concentration being flow-dependent. The proposed results show that the measurements from the fluorescence-based monitors are not or insignificantly flow-dependent. However, other parameters, such as gas bubbles and droplet sizes, do affect the measurement. Testing the monitors' calibration method revealed that the weighted least square is preferred to achieve high reproducibility. Due to the high sensitivity to different compositions of atomic structures, other than aromatic hydrocarbons, the fluorescence-based monitor might not be feasible for measuring OiW concentrations in dynamic separation facilities with consistent changes. Nevertheless, they are still of interest for measuring the separation efficiency of a deoiling hydrocyclone to enhance its deoiling performance, as the separation efficiency is not dependent on OiW trueness but rather the OiW concentration before and after the hydrocyclone.