High performance and bendable few-layered InSe photodetectors with broad spectral response.

Two-dimensional crystals with a wealth of exotic dimensional-dependent properties are promising candidates for next-generation ultrathin and flexible optoelectronic devices. For the first time, we demonstrate that few-layered InSe photodetectors, fabricated on both a rigid SiO2/Si substrate and a flexible polyethylene terephthalate (PET) film, are capable of conducting broadband photodetection from the visible to near-infrared region (450-785 nm) with high photoresponsivities of up to 12.3 AW(-1) at 450 nm (on SiO2/Si) and 3.9 AW(-1) at 633 nm (on PET). These photoresponsivities are superior to those of other recently reported two-dimensional (2D) crystal-based (graphene, MoS2, GaS, and GaSe) photodetectors. The InSe devices fabricated on rigid SiO2/Si substrates possess a response time of ∼50 ms and exhibit long-term stability in photoswitching. These InSe devices can also operate on a flexible substrate with or without bending and reveal comparable performance to those devices on SiO2/Si. With these excellent optoelectronic merits, we envision that the nanoscale InSe layers will not only find applications in flexible optoelectronics but also act as an active component to configure versatile 2D heterostructure devices.

Waveguiding properties of perylene microcrystals synthesized by retarding the growth along the π-stack direction.

Selective, hard to realize growth retardation of the π-stacking direction over the edge-packing direction has been achieved in perylene microcrystals using an aryl amphiphile. The perylene microcrystals grow predominantly along the edge-packing direction resulting in novel and hitherto unknown perylene square rods. The rods show exciton-polariton waveguiding along the rod axis even though it corresponds to pure edge-packing of the molecules, which is unprecedented in organic microcrystals.

Energy Transport of Hybrid Charge-Transfer Excitons.

We investigate the energy transport in an organic-inorganic hybrid platform formed between semiconductors that support stable room-temperature excitons. We find that following photoexcitation, fast-moving hot hybrid charge-transfer excitons (HCTEs) are formed in about 36 ps via scattering with optical phonons at the interface between j-aggregates of organic dye and inorganic monolayer MoS2. Once the energy falls below the optical phonon energy, the excess kinetic energy is relaxed slowly via acoustic phonon scattering, resulting in energy transport that is dominated by fast-moving hot HCTEs that transition into cold HCTEs in about 110 ps. We model the exciton-phonon interactions using Fröhlich and deformation potential theory and attribute the prolonged transport of hot HCTEs to phonon bottleneck. We find that the measured diffusivity of HCTEs in both hot and cold regions of transport was higher than the diffusivity of MoS2 A exciton and verify these results by conducting the experiments with different excitation energies. This work not only provides significant insight into the initial energy transport of HCTEs at organic-inorganic hybrid interfaces but also contributes to the formulation of a complete physical picture of the energy dynamics in hybrid materials, which are poised to advance applications in energy conversion and optoelectronic devices.

Efficient Energy Transfer across Organic-2D Inorganic Heterointerfaces.

Combining organic and inorganic semiconductors enables us to integrate complementary advantages of each material system into a single hybrid material platform. Here, we report a study on the energy transport across a hybrid interface consisting of j-aggregates of organic dye and monolayer molybdenum disulfide (MoS2). The excellent overlap between the photoluminescence spectra of j-aggregates and the absorption of MoS2 B-exciton enables the material system to be used to study Förster resonance energy transfer (FRET) across the hybrid interface. We report a short Förster radius of 1.88 nm for the hybrid system. We achieve this by fabricating photodetectors based on the hybrid organic-inorganic interface that combine the high absorption of organics with the high-charge mobility of inorganics. Concomitantly, the hybrid photodetectors show nearly 93 ± 5% enhancement of photoresponsivity in the excitonic spectral overlap regime due to efficient energy transfer (ET) from j-aggregate to MoS2. This work not only provides valuable insight into the ET mechanism across such hybrid organic-inorganic interfaces but also demonstrates the feasibility of the platform for designing efficient energy conversion and optoelectronic devices.