RESUMEN
The terahertz perfect absorber can be applied in the control, sensing and modulation of optical fields in micro- and nanostructures. However, they are only single function, complex device structure and low sensing sensitivity. Based on this, by introducing the bound state in the continuum (BIC) with infinite quality factor and field enhancement effect, and taking advantage of the phase transition characteristics of vanadium dioxide (VO2), we designed a terahertz perfect absorber device which can actively switch between ultra-wideband and ultra-narrowband. The absorption mechanism is explained by multipole analysis theory, impedance matching theory and electromagnetic field distribution. The broadband absorption is mainly due to the electric dipole resonance on metallic VO2 materials, and the absorption is more than 99% across 3.64-6.96 THz, and it has excellent characteristics such as robustness. Ultra-narrowband perfect absorption has a quality factor greater than 2200 due mainly to the implementation of symmetrically protected BIC with a sensing sensitivity of 2.575 THz per RIU. Therefore, this research could be widely used in the fields of integrated optical circuits, optoelectronic sensing and perceptual modulation of energy, as well as providing additional design ideas for the design of terahertz multifunctional devices.
RESUMEN
Removal of amaranth, a commercial synthetic azo dye widely used in the dye and food industry, was examined as a possible remediation technology for treating dye-contaminated water. Effects of various parameters such as gas flow rate, solution conductivity, pulse repetition frequency, etc., on decolorization kinetics were investigated. Experimental results show that an aqueous solution of 24 mg/l dye is 81.24% decolorized following 30 min plasma treatment for a 50 kV voltage and 0.75 m(3)/h gas flow rate. Decolorization reaction of amaranth in the plasma reactor is a pseudo first order reaction. Rate constant (k) of decolorization increases quickly with increasing the applied voltage, pulse repetition frequency and the gas flow rate. However, when the applied voltage is beyond 50 kV and increases further, increase rate of k decreases. In addition, k decreases quickly when the solution conductivity increases from 200 to 1481 microS/cm. The decolorization reaction has a high rate constant (k=0.0269 min(-1)) when the solution pH is beyond 10. Rate constant k decreases with the decrease of pH and reaches minimum at a pH of about 5 (k(min)=0.01603 min(-1)), then increases to 0.02105 min(-1) when pH decreases to 3.07. About 15% of the initial TOC can be degraded only in about 120 min non-thermal plasma treatment.