Non-blinking semiconductor nanocrystals.

The photoluminescence from a variety of individual molecules and nanometre-sized crystallites is defined by large intensity fluctuations, known as 'blinking', whereby their photoluminescence turns 'on' and 'off' intermittently, even under continuous photoexcitation. For semiconductor nanocrystals, it was originally proposed that these 'off' periods corresponded to a nanocrystal with an extra charge. A charged nanocrystal could have its photoluminescence temporarily quenched owing to the high efficiency of non-radiative (for example, Auger) recombination processes between the extra charge and a subsequently excited electron-hole pair; photoluminescence would resume only after the nanocrystal becomes neutralized again. Despite over a decade of research, completely non-blinking nanocrystals have not been synthesized and an understanding of the blinking phenomenon remains elusive. Here we report ternary core/shell CdZnSe/ZnSe semiconductor nanocrystals that individually exhibit continuous, non-blinking photoluminescence. Unexpectedly, these nanocrystals strongly photoluminesce despite being charged, as indicated by a multi-peaked photoluminescence spectral shape and short lifetime. To model the unusual photoluminescence properties of the CdZnSe/ZnSe nanocrystals, we softened the abrupt confinement potential of a typical core/shell nanocrystal, suggesting that the structure is a radially graded alloy of CdZnSe into ZnSe. As photoluminescence blinking severely limits the usefulness of nanocrystals in applications requiring a continuous output of single photons, these non-blinking nanocrystals may enable substantial advances in fields ranging from single-molecule biological labelling to low-threshold lasers.

Suppression of auger processes in confined structures.

We explore how the size and shape of the microscopic confinement potential affects the nonradiative Auger decay rate of confined carriers. Calculations conducted in the two-band, effective mass Kane model unambiguously show that smoothing out the confinement potential could reduce the rate by more than 3 orders of magnitude relative to the rate in structures with abruptly terminating boundaries. As the confinement potential width is increased, the calculated rate decreases overall, exhibiting very deep minima at regular widths. Such minima suggest that nanocrystals of "magic sizes" can exist for which nonradiative Auger processes are strongly suppressed.

Coherent decay of Bose-Einstein condensates.

Atomic Bose-Einstein condensates are singular forms of matter with the coherence between constituent atoms as a defining characteristic. Although this viewpoint is increasingly validated through experimental findings, the mechanisms behind the observed losses are still understood with classical recombinant collision arguments between particles within the condensate itself. By incorporating a general interparticle interaction into the Hamiltonian, a coherent decay rate can be obtained, thus providing a direct link between the observed losses and the microscopic two-body parameters. Appearing in the lifetime, the interaction strength, lambda, is expressed as lambda=8 pia/(1-delta), where the small parameter delta is obtained from a fit to experimental loss data. Most importantly, the lowest order rate exhibits a novel density dependence (rho{3/2}) that can be identified in low temperature tests.

Complex chemical potential: signature of decay in a bose-einstein condensate.

We explore the zero-temperature statics of an atomic Bose-Einstein condensate in which a Feshbach resonance creates a coupling to a second condensate component of quasibound molecules. Using a variational procedure to find the equation of state, the appearance of this binding is manifest in a collapsing ground state, where only the molecular condensate is present up to some critical density. Further, an excited state is seen to reproduce the usual low-density atomic condensate behavior in this system, but the molecular component is found to produce a coherent, many-body decay, quantified by the imaginary part of the chemical potential. Most importantly, the unique decay rate dependencies on density (approximately rho (3/2)) and on scattering length (approximately (5/2)) can be measured in experimental tests of this result.