Design of biomass-based composite photocatalysts for wastewater treatment: a review over the past decade and future prospects.

This investigation applied a systematic review approach on publications covering primary data during 2012-2022 with a focus on photocatalytic degradation of pollutants in aqueous solution by composite materials synthesized with biomass and, at least, TiO2 and/or ZnO semiconductors to form biomass-based composite photocatalysts (BCPs). After applying a set of eligibility criteria, 107 studies including 832 observations/entries were analyzed. The average removal efficiency and degradation kinetic rate reported for all model pollutants and BCPs were 77.5 ± 21.5% and 0.064 ± 0.174 min-1, respectively. Principal component analysis (PCA) was applied to analyze BCPs synthesis methods, experimental conditions, and BCPs' characteristics correlated with the removal efficiency and photodegradation kinetics. The relevance of adsorption processes on the pollutants' removal efficiency was highlighted by PCA applied to all categories of pollutants (PCA_pol). The PCA applied to textile dyes (PCA_dyes) and pharmaceutical compounds (PCA_pharma) also indicate the influence of variables related to the composite synthesis (i.e., thermal treatment and time spent on BCPs synthesis) and photocatalytic experimental parameters (catalyst concentration, pollutant concentration, and irradiation time) on the degradation kinetic accomplished by BCPs. Furthermore, the multivariate analysis (PCA_pol) revealed that the specific surface area and the narrow band gap are key characteristics for BCPs to serve as a competitive photocatalyst. The effect of scavengers on pollutants' degradation and the recyclability of BCPs are also discussed, as necessary aspects for scalability trends. Further investigations are recommended to compare the performance of BCPs and commercial catalysts, as well as to assess the costs to treat real wastewater.

Immobilized TiO2 on glass spheres applied to heterogeneous photocatalysis: photoactivity, leaching and regeneration process.

Heterogeneous photocatalysis using titanium dioxide as catalyst is an attractive advanced oxidation process due to its high chemical stability, good performance and low cost. When immobilized in a supporting material, additional benefits are achieved in the treatment. The purpose of this study was to develop a simple protocol for impregnation of TiO2-P25 on borosilicate glass spheres and evaluate its efficiency in the photocatalytic degradation using an oxidizable substrate (methylene blue), in a Compound Parabolic Concentrator (CPC) reactor. The assays were conducted at lab-scale using radiation, which simulated the solar spectrum. TiO2 leaching from the glass and the catalyst regeneration were both demonstrated. A very low leaching ratio (0.03%) was observed after 24 h of treatment, suggesting that deposition of TiO2 resulted in good adhesion and stability of the photocatalyst on the surface of borosilicate. This deposition was successfully achieved after calcination of the photocatalyst at 400 °C (TiO2-400 °C). The TiO2 film was immobilized on glass spheres and the powder was characterized by scanning electron microscopy (SEM), X-ray diffraction and BET. This characterization suggested that thermal treatment did not introduce substantial changes in the measured microstructural characteristics of the photocatalyst. The immobilized photocatalyst degraded more than 96% of the MB in up to 90 min of reaction. The photocatalytic activity decreased after four photocatalytic cycles, but it was recovered by the removal of contaminants adsorbed on the active sites after washing in water under UV-Vis irradiation. Based on these results, the TiO2-400 °C coated on glass spheres is potentially a very attractive option for removal of persistent contaminants present in the environment.

Psychoactive drugs: occurrence in aquatic environment, analytical methods, and ecotoxicity-a review.

This review focused on seven psychoactive drugs being six benzodiazepines (alprazolam, bromazepam, clonazepam, diazepam, lorazepam, and oxazepam) and one antidepressant (citalopram) widely consumed by modern society and detected in different aqueous matrices (drinking water, surface water, groundwater, seawater, estuary water, influent and effluent of wastewater treatment plants). The review included 219 selected scientific papers from which 1642 data/entries were obtained, each entry corresponding to one target compound in one aqueous matrix. Concentrations of all investigated drugs in all aqueous matrices varied from 0.14 to 840,000 ng L-1. Citalopram presented the highest concentrations in the aqueous matrices. Based on the Wilcoxon-Mann-Whitney test, differences between wastewater influents and effluents were not significant for most wastewater categories, suggesting that conventional wastewater treatment systems as such do not remove or remove partially these compounds. High-income countries showed much lower concentrations in surface water than the group formed by upper-middle-, lower-middle-, and low-income countries. Regarding analytical methods, solid-phase extraction (SPE) was by far the most used extraction method (83%) and performance liquid chromatography (HPLC) (73%) coupled to mass spectrometry (99%) the most common analytical method. Changes in behavior and in survival rates were the most common effects reported on bioindicators (aquatic species) due to the presence of these drugs in water. Concentrations of psychoactive drugs found in surface waters were most of the time within the range that caused measurable toxic effects in ecotoxicity assays.