RESUMEN
Anchorage to concrete is a recurring application in construction. For such applications, bonded anchors, formed by means of a polymer adhesive injection into a borehole, are a widely used product due to their flexibility in regards to the construction logistics and positioning of the attached element as well as high load capacities. At the same time, fibre-reinforced concrete is the material of choice for many engineering applications where anchors have to be installed. Moreover, the use of steel fibre-reinforced concrete is likely to increase, since it now falls in the scope of the second-generation Eurocode 2 (exp. 2023). Therefore, the condition of the anchor installation borehole-mainly the roughness and grip of its internal surface-is known to play a critical role in the stress transfer from the attached component, through the fastening and into the concrete, and, hence, to the load-bearing performance. At the same time, drilling through the steel fibre reinforcement, along with the accelerated wear of the drilling tools, can in turn influence the borehole's roughness and the overall installation quality. Furthermore, steel fibre may lead to an additional local stiffening of the concrete where the anchor is installed. These complex elements are discussed herein on the basis of multiple tests on anchors in plain and steel fibre concrete, as well as numerical analyses. The results indicate particular aspects of bonded anchor design and product certification for different polymer-based construction adhesives.
RESUMEN
The miscibility and phase separation of poly(methyl methacrylate) (PMMA) and styrene-acrylonitrile (SAN) have already been investigated using various methods. However, these methods have limitations that often result in inconsistent characterization. Consequently, the reasons for the dependence of miscibility on composition as well as on processing temperature have not yet been proved. The phase separation of PMMA/SAN blends was therefore investigated for the first time using a novel technique, nanoscale AFM-IR. It couples nanoscale atomic force microscopy (AFM) with infrared (IR) spectroscopy. Therefore, the phase morphology can be chemically identified and precisely classified within the nm-regime. The PMMA/SAN blends, on the other hand, were analyzed of their changes in morphology under different thermal treatments. It was possible to visualize and define the phase separation, as well as dependence of the miscibility on the mixing ratio. In the miscible domain, no two individual phases could be detected down to the nanometer range. It was shown that with increasing temperature, the morphology changes and two different phases are formed, where the phase boundaries can be sharply defined. The onset of these changes could be identified at temperatures of about 100 °C.
RESUMEN
Polylactide (PLA) is one of the most important bioplastics worldwide and thus represents a good potential substitute for bead foams made of the fossil-based Polystyrene (PS). However, foaming of PLA comes with a few challenges. One disadvantage of commercially available PLA is its low melt strength and elongation properties, which play an important role in foaming. As a polyester, PLA is also very sensitive to thermal and hydrolytic degradation. Possibilities to overcome these disadvantages can be found in literature, but improving the properties for foaming of PLA as well as the degradation behavior during foaming have not been investigated yet. In this study, reactive extrusion on a twin-screw extruder is used to modify PLA in order to increase the melt strength and to protect it against thermal degradation and hydrolysis. PLA foams are produced in an already known process from the literature and the influence of the modifiers on the properties is estimated. The results show that it is possible to enhance the foaming properties of PLA and to protect it against hydrolysis at the same time.