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1.
Environ Res ; 241: 117551, 2024 Jan 15.
Artículo en Inglés | MEDLINE | ID: mdl-37939801

RESUMEN

The present study investigated the sustainable approach for wastewater treatment using waste algal blooms. The current study investigated the removal of toxic metals namely chromium (Cr), nickel (Ni), and zinc (Zn) from aqueous solutions in batch and column studies using biochar produced by the marine algae Ulva reticulata. SEM/EDX, FTIR, and XRD were used to examine the adsorbents' properties and stability. The removal efficiency of toxic metals in batch operations was investigated by varying the parameters, which included pH, biochar dose, initial metal ion concentration, and contact time. Similarly, in the column study, the removal efficiency of heavy metal ions was investigated by varying bed height, flow rate, and initial metal ion concentration. Response Surface Methodology (Central Composite Design (CCD)) was used to confirm the linearity between the observed and estimated values of the adsorption quantity. The packed bed column demonstrated successful removal rates of 90.38% for Cr, 91.23% for Ni, and 89.92% for Zn heavy metals from aqueous solutions, under a controlled environment. The breakthrough analysis also shows that the Thomas and Adams-Bohart models best fit the regression values, allowing prior breakthroughs in the packed bed column to be predicted. Desorption studies were conducted to understand sorption and elution during different regeneration cycles. Adding 0.3 N sulfuric acid over 40 min resulted in the highest desorption rate of the column and adsorbent used for all three metal ions.


Asunto(s)
Metales Pesados , Algas Marinas , Contaminantes Químicos del Agua , Metales Pesados/análisis , Níquel , Zinc/análisis , Cromo/análisis , Agua , Iones , Adsorción , Contaminantes Químicos del Agua/análisis , Concentración de Iones de Hidrógeno , Cinética
2.
Environ Res ; 238(Pt 2): 117233, 2023 12 01.
Artículo en Inglés | MEDLINE | ID: mdl-37793591

RESUMEN

All living things depend on their natural environment, either directly or indirectly, for their high quality of life, growth, nutrition, and development. Due to the fast emissions of greenhouse gases (GHGs), the Earth's climate system is being negatively impacted by global warming. Stresses caused by climate change, such as rising and hotter seas, increased droughts and floods, and acrid waters, threaten the world's most populated areas and aquatic ecosystems. As a result, the aquatic ecosystems of the globe are quickly reaching hazardous conditions. Marine ecosystems are essential parts of the world's environment and provide several benefits to the human population, such as water for drinking and irrigation, leisure activities, and habitat for commercially significant fisheries. Although local human activities have influenced coastal zones for millennia, it is still unclear how these impacts and stresses from climate change may combine to endanger coastal ecosystems. Recent studies have shown that rising levels of greenhouse gases are causing ocean systems to experience conditions not seen in several million years, which may cause profound and irreversible ecological shifts. Ocean productivity has declined, food web dynamics have changed, habitat-forming species are less common, species ranges have changed, and disease prevalence has increased due to human climate change. We provide an outline of the interaction between global warming and the influence of humans along the coastline. This review aims to demonstrate the significance of long-term monitoring, the creation of ecological indicators, and the applications of understanding how aquatic biodiversity and ecosystem functioning respond to global warming. This review discusses the effects of current climate change on marine biological processes both now and in the future, describes present climate change concerning historical change, and considers the potential roles aquatic systems could play in mitigating the effects of global climate change.


Asunto(s)
Ecosistema , Gases de Efecto Invernadero , Humanos , Cambio Climático , Efectos Antropogénicos , Calidad de Vida , Cadena Alimentaria
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