Evaluation of Open-Source Large Language Models for Metal-Organic Frameworks Research.

Along with the development of machine learning, deep learning, and large language models (LLMs) such as GPT-4 (GPT: Generative Pre-Trained Transformer), artificial intelligence (AI) tools have been playing an increasingly important role in chemical and material research to facilitate the material screening and design. Despite the exciting progress of GPT-4 based AI research assistance, open-source LLMs have not gained much attention from the scientific community. This work primarily focused on metal-organic frameworks (MOFs) as a subdomain of chemistry and evaluated six top-rated open-source LLMs with a comprehensive set of tasks including MOFs knowledge, basic chemistry knowledge, in-depth chemistry knowledge, knowledge extraction, database reading, predicting material property, experiment design, computational scripts generation, guiding experiment, data analysis, and paper polishing, which covers the basic units of MOFs research. In general, these LLMs were capable of most of the tasks. Especially, Llama2-7B and ChatGLM2-6B were found to perform particularly well with moderate computational resources. Additionally, the performance of different parameter versions of the same model was compared, which revealed the superior performance of higher parameter versions.

An intelligent detecting system for permeability prediction of MBR.

The membrane bioreactor (MBR) has been widely used to purify wastewater in wastewater treatment plants. However, a critical difficulty of the MBR is membrane fouling. To reduce membrane fouling, in this work, an intelligent detecting system is developed to evaluate the performance of MBR by predicting the membrane permeability. This intelligent detecting system consists of two main parts. First, a soft computing method, based on the partial least squares method and the recurrent fuzzy neural network, is designed to find the nonlinear relations between the membrane permeability and the other variables. Second, a complete new platform connecting the sensors and the software is built, in order to enable the intelligent detecting system to handle complex algorithms. Finally, the simulation and experimental results demonstrate the reliability and effectiveness of the proposed intelligent detecting system, underlying the potential of this system for the online membrane permeability for detecting membrane fouling of MBR.

Prediction of sludge bulking using the knowledge-leverage-based fuzzy neural network.

One of the most important steps and the main bottleneck of the activated sludge wastewater treatment process (WWTP) is the secondary clarification, where sludge bulking is still a widespread problem. In this paper, an intelligent method, based on a knowledge-leverage-based fuzzy neural network (KL-FNN), is developed to predict sludge bulking online. This proposed KL-FNN can make full use of the data and the existing knowledge from the operation of WWTP. Meanwhile, a transfer learning mechanism is applied to adjust the parameters of the proposed method to improve the predicting accuracy. Finally, this proposed method is applied to a real wastewater treatment plant for predicting the sludge bulking risk, and then for predicting the sludge bulking. The experimental results indicate that the proposed prediction method can be used as a tool to achieve better performance and adaptability than the existing methods in terms of predicting accuracy for sludge bulking.

Double-Closed-Loop Robust Optimal Control for Uncertain Nonlinear Systems.

Optimal control methods have gained significant attention due to their promising performance in nonlinear systems. In general, an optimal control method is regarded as an optimization process for solving the optimal control laws. However, for uncertain nonlinear systems with complex optimization objectives, the solving of optimal reference trajectories is difficult and significant that might be ignored to obtain robust performance. For this problem, a double-closed-loop robust optimal control (DCL-ROC) is proposed to maintain the optimal control reliability of uncertain nonlinear systems. First, a double-closed-loop scheme is established to divide the optimal control process into a closed-loop optimization process that solves optimal reference trajectories and a closed-loop control process that solves optimal control laws. Then, the ability of the optimal control method can be improved to solve complex uncertain optimization problems. Second, a closed-loop robust optimization (CL-RO) algorithm is developed to express uncertain optimization objectives as data-driven forms and adjust optimal reference trajectories in a close loop. Then, the optimality of reference trajectories can be improved under uncertainties. Third, the optimal reference trajectories are tracked by an adaptive controller to derive the optimal control laws without certain system dynamics. Then, the adaptivity and reliability of optimal control laws can be improved. The experimental results demonstrate that the proposed method can achieve better performance than other optimal control methods.

Foreground Capture Feature Pyramid Network-Oriented Object Detection in Complex Backgrounds.

Feature pyramids are widely adopted in visual detection models for capturing multiscale features of objects. However, the utilization of feature pyramids in practical object detection tasks is prone to complex background interference, resulting in suboptimal capture of discriminative multiscale foreground semantic features. In this article, a foreground capture feature pyramid network (FCFPN) for multiscale object detection is proposed, to address the problem of inadequate feature learning in complex backgrounds. FCFPN consists of a foreground dual attention (FDA) module and a pathway aggregation (PA) structure. Specifically, the FDA mechanism activates top-down foreground channel responses and lateral spatial foreground location features, so that channel and spatial foreground features are adequately captured. Then, the PA module adaptively learns the fusion weights of multiscale features at different levels of the feature pyramid, which enhances the complementarity of semantic information between different levels of the foreground feature maps. Since the fusion weights are learned adaptively based on different pyramid levels, the detection model accordingly retains the gained information of feature sizes and suppresses the conflicting information. The evaluations on public datasets and the self-built complex background dataset demonstrate that the detection average precision (AP) and the feature learning performance of the proposed method are superior compared with other FPNs, which proves the effectiveness of the proposed FCFPN.

Robust Multiobjective Particle Swarm Optimization With Feedback Compensation Strategy.

Multiobjective particle swarm optimization (MOPSO) has been proven effective in solving multiobjective problems (MOPs), in which the evolutionary parameters and leaders are selected randomly to develop the diversity. However, the randomness would cause the evolutionary process uncertainty, which deteriorates the optimization performance. To address this issue, a robust MOPSO with feedback compensation (RMOPSO-FC) is proposed. RMOPSO-FC provides a novel closed-loop optimization framework to reduce the negative influence of uncertainty. First, Gaussian process (GP) models are established by dynamically updated archives to obtain the posterior distribution of particles. Then, the feedback information of particle evolution can be collected. Second, an intergenerational binary metric is designed based on the feedback information to evaluate the evolutionary potential of particles. Then, the particles with negative evolutionary directions can be identified. Third, a compensation mechanism is presented to correct the negative evolution of particles by modifying the particle update paradigm. Then, the compensated particles can maintain the positive exploration toward the true PF. Finally, the comparative simulation results illustrate that the proposed RMOPSO-FC can provide superior search capability of PFs and algorithmic robustness over multiple runs.

A Novel Set-Based Discrete Particle Swarm Optimization for Wastewater Treatment Process Effluent Scheduling.

With the escalating severity of environmental pollution caused by effluent, the wastewater treatment process (WWTP) has gained significant attention. The wastewater treatment efficiency and effluent quality are significantly impacted by effluent scheduling that adjusts the hydraulic retention time. However, the sequential batch and continuous nature of the effluent pose challenges, resulting in complex scheduling models with strong constraints that are difficult to tackle using existing scheduling methods. To optimize maximum completion time and effluent quality simultaneously, this article proposes a restructured set-based discrete particle swarm optimization (RS-DPSO) algorithm to address the WWTP effluent scheduling problem (WWTP-ESP). First, an effective encoding and decoding method is designed to effectively map solutions to feasible schedules using temporal and spatial information. Second, a restructured set-based discrete particle swarm algorithm is introduced to enhance the searching ability in discrete solution space via restructuring the solution set. Third, a constraint handling strategy based on violation degree ranking is designed to reduce the waste of computational resources. Fourth, a Sobel filter based local search is proposed to guide particle search direction to enhance search efficiency ability. The RS-DPSO provides a novel method for solving WWTP-ESP problems with complex discrete solution space. The comparative experiments indicate that the novel designs are effective and the proposed algorithm has superior performance over existing algorithms in solving the WWTP-ESP.

Diversified Knowledge Transfer Strategy for Multitasking Particle Swarm Optimization.

Evolutionary multitasking optimization (EMTO) has capability of performing a population of individuals together by sharing their intrinsic knowledge. However, the existed methods of EMTO mainly focus on improving its convergence using parallelism knowledge belonging to different tasks. This fact may lead to the problem of local optimization in EMTO due to unexploited knowledge on behalf of the diversity. To address this problem, in this article, a diversified knowledge transfer strategy is proposed for multitasking particle swarm optimization algorithm (DKT-MTPSO). First, according to the state of population evolution, an adaptive task selection mechanism is introduced to manage the source tasks that contribute to the target tasks. Second, a diversified knowledge reasoning strategy is designed to capture the knowledge of convergence, as well as the knowledge associated with diversity. Third, a diversified knowledge transfer method is developed to expand the region of generated solutions guided by acquired knowledge with different transfer patterns so that the search space of tasks can be explored comprehensively, which is favor of EMTO alleviating local optimization. Finally, the performance of the proposed algorithm is evaluated in comparison with some other state-of-the-art EMTO algorithms on multiobjective multitasking benchmark test suits, and the practicality of the algorithm is verified in a real-world application study. The results of experiments demonstrate the superiority of DKT-MTPSO compared to other algorithms.

Robust Model Free Adaptive Predictive Control for Wastewater Treatment Process With Packet Dropouts.

External disturbances and packet dropouts will lead to poor control performance for the wastewater treatment process (WWTP). To address this issue, a robust model-free adaptive predictive control (RMFAPC) strategy with a packet dropout compensation mechanism (PDCM) is proposed for WWTP. First, a dynamic linearization approach (DLA), relying only on perturbed process data, is employed to approximate the system dynamics. Second, a predictive control strategy is introduced to avoid a short-sighted control decision, and an extended state observer (ESO) is used to attenuate the disturbance effectively. Furthermore, a PDCM strategy is designed to handle the packet dropout problem, and the stability of RMFAPC is rigorously analyzed. Finally, the correctness and effectiveness of RMFAPC are verified through extensive simulations. The simulation results indicate that RMFAPC can significantly reduce IAE by 0.0223 and 0.1976 in two scenarios, regardless of whether the expected value remains constant or varies. This comparison to MFAPC demonstrates the superior robustness of RMFAPC against disturbances. The ablation experiment on PDCM further confirms its capability in handling the packet dropout problem.

Knowledge-Data Driven Optimal Control for Nonlinear Systems and Its Application to Wastewater Treatment Process.

Optimal control is developed to guarantee nonlinear systems run in an optimum operating state. However, since the operation demands of systems are dynamically changeable, it is difficult for optimal control to obtain reliable optimal solutions to achieve satisfying operation performance. To overcome this problem, a knowledge-data driven optimal control (KDDOC) for nonlinear systems is designed in this article. First, an adaptive initialization strategy, using the knowledge from historical operation information of nonlinear systems, is employed to dynamically preset parameters of KDDOC. Then, the initial performance of KDDOC can be enhanced for nonlinear systems. Second, a knowledge guide-based global best selection mechanism is used to assist KDDOC in searching for the optimal solutions under different operation demands. Then, dynamic optimal solutions of KDDOC can be obtained to adapt to flexible changes in nonlinear systems. Third, a knowledge direct-based exploitation mechanism is presented to accelerate the solving process of KDDOC. Then, the demand response speed of KDDOC can be improved to ensure nonlinear systems with optimal operation performance in different states. Finally, the performance of KDDOC is validated on a simulation and a practical process. Several experimental results illustrate the effectiveness of the proposed optimal control for nonlinear systems.

Leader-Following Sampled-Data Consensus of Multiagent Systems With Successive Packet Losses and Stochastic Sampling.

In practical applications, sampled-data systems are often affected by unforeseen physical constraints that cause the sampling interval to deviate from the expected value and fluctuate according to a certain probability distribution. This probability distribution can be determined in advance through statistical analysis. Taking into account this stochastic sampling interval, this article focuses on addressing the leader-following sampled-data consensus problem for linear multiagent systems (MASs) with successive packet losses. First, the relationship of the equivalent sampling interval between two successive update instants is established, taking into account the double randomness introduced by both SPLs and stochastic sampling. Then, the equivalent discrete-time MAS is obtained, and the overall leader-following consensus problem is formulated as a stochastic stability problem of the equivalent system by incorporating the sampled-data consensus protocol and properties of the Laplacian matrix. Based on the equivalent the discrete-time system, a consensus criterion is derived under a directed graph by using the Lyapunov theory and leveraging a vectorization technique. By the introduction of a matrix reconstruction approach, the mathematical expectation of a product of three matrices, including the system matrix and its transpose, can be determined. Then, the consensus protocol gain is designed. Finally, an example is provided to validate our theoretical results.

Dynamic Surface Intelligent Robust Control of Nonlinear Systems With Fixed-Time Sliding-Mode Observer.

The high tracking control precision and fast finite-time convergence for nonlinear systems is a significant challenge due to complex nonlinearity and unknown disturbances. To address this challenge, a dynamic surface intelligent robust control strategy with fixed-time sliding-mode observer (DSIRC-SMO) is proposed to improve the tracking control performance in a finite time. First, adaptive fuzzy neural network based on a predictor (P-AFNN) is designed to imitate the complex nonlinearity. In particular, the weight adaptive law is formulated by utilizing the prediction error information, which improves the accuracy of approximating the nonlinear system. Second, the fixed-time sliding-mode observer (SMO) is integrated into the dynamic surface control technique to deal with unknown disturbances and modeling errors in a fixed time. This integration allows for timely updates the dynamic surface using observation information, thereby enhancing the system's anti-interference capability. Then, the fixed-time convergence of SMO is proven. Third, the proposed DSIRC-SMO can be effectively implemented and the finite-time convergence of DSIRC-SMO is proven in detail based on the fixed-time convergence of SMO. Finally, numerical simulation and actual wastewater treatment processes simulation are conducted to validate the effectiveness of DSIRC-SMO.

Adaptive Ant Colony Optimization Algorithm Based on Real-Time Logistics Features for Instant Delivery.

Ant colony optimization (ACO) algorithm is widely used in the instant delivery order scheduling because of its distributed computing capability. However, the order delivery efficiency decreases when different logistics statuses are faced. In order to improve the performance of ACO, an adaptive ACO algorithm based on real-time logistics features (AACO-RTLFs) is proposed. First, features are extracted from the event dimension, spatial dimension, and time dimension of the instant delivery to describe the real-time logistics status. Five key factors are further selected from the above three features to assist in problem modeling and ACO designing. Second, an adaptive instant delivery model is built considering the customer's acceptable delivery time. The acceptable time is calculated by emergency order mark and weather conditions in the event dimension feature. Third, an adaptive ACO algorithm is proposed to obtain the instant delivery order schedules. The parameters of the probability equation in ACO are adjusted according to the extracted key factors. Finally, the Gurobi solver in Python is used to perform numerical experiments on the classical datasets to verify the effectiveness of the instant delivery model. The proposed AACO-RTLF algorithm shows its advantages in instant delivery order scheduling when compared to the other state-of-the-art algorithms.

Sampled-Data H∞ Dynamic Output-Feedback Control for NCSs With Successive Packet Losses and Stochastic Sampling.

The problem of sampled-data H∞ dynamic output-feedback control for networked control systems with successive packet losses (SPLs) and stochastic sampling is investigated in this article. The aim of using sampled-data control techniques is to alleviate network congestion. SPLs that occur in the sensor-to-controller (S-C) and controller-to-actuator (C-A) channels are modeled using a packet loss model. Additionally, it is assumed that stochastic sampling follows a Bernoulli distribution. A model is established to capture the stochastic characteristics of both the SPL model and stochastic sampling. This model is crucial as it allows us to determine the probability distribution of the sampling interval between successive update instants, which is essential for stability analysis. An exponential mean-square stability condition for the constructed equivalent discrete-time stochastic system, which also guarantees the prescribed H∞ performance, is established by incorporating probability theory. The desired controller is designed using a step-by-step synthesis approach, which may offer lower design conservatism compared to some existing methods. Finally, our designed approach using a networked F-404 engine system model is validated and its merits relative to existing results are discussed. The proposed method is finally validated by employing a networked model of the F-404 engine system. Furthermore, the advantages of our method are presented in comparison to previous results.

Data-Driven Tube-Based Robust Predictive Control for Constrained Wastewater Treatment Process.

The wastewater treatment process (WWTP) is characterized by unknown nonlinearity and external disturbances, which complicates the tracking control of dissolved oxygen concentration (DOC) within operational constraints. To address this issue, a data-driven tube-based robust predictive control (DTRPC) strategy is proposed to achieve stable tracking control of DOC and satisfy the system constraints. First, a tube-based robust predictive control (TRPC) strategy is designed to deal with system constraints and external disturbances. Specifically, a nominal controller is designed to ensure that the nominal output accurately tracks the set-point under tightened constraints, while an auxiliary feedback controller is designed to suppress disturbances and restore the nominal performance of the disturbed WWTP. Second, two fuzzy neural network identifiers are employed to provide accurate predictive outputs for the control process, overcoming the challenges of modeling the WWTP with strong nonlinearity and unknown dynamics. Third, the generalized multiplier method is utilized to solve the constrained optimization problem to obtain the nominal control law, and the gradient descent algorithm is used to obtain the auxiliary control law. The implementation of this composite controller ensures the satisfaction of the system constraints and the effective suppression of disturbances. Finally, the feasibility and stability of the proposed DTRPC strategy are guaranteed through rigorous theoretical analysis, and its effectiveness is demonstrated through the simulations on the benchmark simulation model No.1.

Energy consumption model for wastewater treatment process control.

Wastewater treatment must satisfy discharge requirements under specified constraints and have minimal operating costs (OC). The operating results of wastewater treatment processes (WWTPs) have significantly focused on both the energy consumption (EC) and effluent quality (EQ). To reflect the relationship between the EC and EQ of WWTPs directly, an extended Elman neural network-based energy consumption model (EENN-ECM) was studied for WWTP control in this paper. The proposed EENN-ECM was capable of predicting EC values in the treatment process. Moreover, the self-adaptive characteristic of the EENN ensured the modeling accuracy. A performance demonstration was carried out through a comparison of the EC between the benchmark simulation model No.1 (BSM1) and the EENN-ECM. The experimental results demonstrate that this EENN-ECM is more effective to model the EC of WWTPs.

Adaptive optimal control for a wastewater treatment plant based on a data-driven method.

In order to optimize the operating points of the dissolved oxygen concentration and the nitrate level in a wastewater treatment plant (WWTP) benchmark, a data-driven adaptive optimal controller (DDAOC) based on adaptive dynamical programming is proposed. This DDAOC consists of an evaluation module and an optimization module. When a certain group of operating points is given, first the evaluation module estimates the energy consumption and the effluent quality in the future under this policy, and then the optimization module adjusts the operating points according to the evaluation result generated by the evaluation module. The optimal operating points will be found gradually as this process continues repeatedly. During the optimization, only the input-output data measured from the plant are needed, while a mechanistic model is unnecessary. The DDAOC is tested and evaluated on BSM1 (Benchmark Simulation Model No.1), and its performance is compared to the performance of a proportional-integral-derivative (PID) controller with fixed operating points under the full range of operating conditions. The results show that DDAOC can reduce the energy consumption significantly.

Deterministic Learning-Based Adaptive Neural Control for Nonlinear Full-State Constrained Systems.

In this article, an adaptive neural learning method is introduced for a category of nonlinear strict-feedback systems with time-varying full-state constraints. The two challenging problems of state constraints and learning capability are investigated and solved in a unified framework. To obtain the learning of unknown functions and satisfy full-state constraints, three main steps are considered. First, an adaptive dynamic surface controller (DSC) based on barrier Lyapunov functions (BLFs) is structured to implement that the closed-loop systems signals are bounded and full-state variables remain within the prescribed time-varying intervals. Moreover, the radial basis function neural networks (RBF NNs) are used to identify unknown functions. The output of the first-order filter, instead of virtual control derivatives, is used to simplify the complexity of the RBF NN input variables. Second, the state transformation is used to obtain a class of linear time-varying subsystems with small perturbations such that the recurrence of the RBF NN input variables and the partial persistent excitation condition are actualized. Therefore, the unknown functions can be accurately approximated, and the learned knowledge is kept as constant NN weights. Third, the obtained constant weights are borrowed into an adaptive learning scheme to achieve the batter control performance. Finally, simulation studies illustrate the advantage of the reported adaptive learning method on higher tracking accuracy, faster convergence rate, and lower computational expense by reusing learned knowledge.

Neural Network-Based Adaptive Tracking Control for Denitrification and Aeration Processes With Time Delays.

Wastewater treatment process (WWTP), consisting of a class of physical, chemical, and biological phenomena, is an important means to reduce environmental pollution and improve recycling efficiency of water resources. Considering characteristics of the complexities, uncertainties, nonlinearities, and multitime delays in WWTPs, an adaptive neural controller is presented to achieve the satisfying control performance for WWTPs. With the advantages of radial basis function neural networks (RBF NNs), the unknown dynamics in WWTPs are identified. Based on the mechanistic analysis, the time-varying delayed models of the denitrification and aeration processes are established. Based on the established delayed models, the Lyapunov-Krasovskii functional (LKF) is used to compensate for the time-varying delays caused by the push-flow and recycle flow phenomenon. The barrier Lyapunov function (BLF) is used to ensure that the dissolved oxygen (DO) and nitrate concentrations are always kept within the specified ranges though the time-varying delays and disturbances exist. Using Lyapunov theorem, the stability of the closed-loop system is proven. Finally, the proposed control method is carried out on the benchmark simulation model 1 (BSM1) to verify the effectiveness and practicability.

Multistate-Constrained Multiobjective Differential Evolution Algorithm With Variable Neighborhood Strategy.

Multiobjective differential evolution (DE) algorithm (MODE) has been widely used in multiobjective optimization problems. However, due to the complex feasible regions, the optimization efficiency of MODE may decrease when solving constrained multiobjective problems. It is challenging to promote the evolution of population with few feasible solutions. In this article, a multistate-constrained MODE with variable neighborhood strategy (MSCMODE-VNS) is proposed to enhance the optimization effectiveness with complex feasible regions. First, a variable neighborhood DE strategy, based on a specially designed convergence indicator, is designed to accelerate the generation of feasible solutions. Second, a multistate population updating strategy with a comprehensive solution evaluation mechanism is devised to update the population of the next generation to improve the performance of solutions. Third, the convergence analysis, based on the probability theory, is derived to verify the effectiveness of the proposed MSCMODE-VNS algorithm. Finally, experimental results indicate that MSCMODE-VNS can achieve a satisfactory performance on three benchmark test suites and two real-world-constrained multiobjective problems.