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1.
Materials (Basel) ; 17(10)2024 May 16.
Artículo en Inglés | MEDLINE | ID: mdl-38793461

RESUMEN

Wood, a natural material with versatile industrial applications, faces limitations such as low dimensional stability and decay resistance. To address these issues, there has been significant progress in wood modification research. Oil heat treatment has emerged as an effective method among environmentally friendly wood treatment options. Studies have indicated that treating wood with hot vegetable oils yields superior properties compared to traditional methods involving gaseous atmospheres, which is attributed to the synergistic effect of oils and heat. This comprehensive review investigates the physical, chemical, and mechanical modifications induced by the oil heat treatment of wood, along with its impact on biological durability against biotic agents. The review synthesizes recent research findings, elucidates underlying mechanisms, and discusses the implications for wood material science and engineering.

2.
Ultrason Sonochem ; 23: 148-55, 2015 Mar.
Artículo en Inglés | MEDLINE | ID: mdl-25453212

RESUMEN

Agricultural and forest residues obtained after harvesting are promising renewable sources, suitable as a source of pulp for cellulose nanocrystal manufacturing. Cavitation-assisted softening of the lignin-carbohydrate matrix offers sample opportunity for cellulose fibril liberation and degradation of amorphous cellulose. The present work addresses cavitation assisted cellulose fibril and crystal liberation and film forming properties of the supernatant phase of treated agricultural and forest residues. The effectiveness of this method has been evaluated according to crystallinity indices and hydrogen bond energies, as measured by FT-IR analysis. It has been observed that the use of cavitation increased the crystallinity and caused partial removal and degradation of the lignin matrix. Overall, it appears that considerable improvement of crystallinity can be obtained from agricultural and forest residues through the use of cavitation.


Asunto(s)
Lignina/química , Lignina/aislamiento & purificación , Ultrasonido , Conformación de Carbohidratos , Química Farmacéutica , Tecnología Química Verde , Modelos Moleculares , Agua/química
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