Risk of groundwater contamination widely underestimated because of fast flow into aquifers.

Groundwater pollution threatens human and ecosystem health in many regions around the globe. Fast flow to the groundwater through focused recharge is known to transmit short-lived pollutants into carbonate aquifers, endangering the quality of groundwaters where one quarter of the world's population lives. However, the large-scale impact of such focused recharge on groundwater quality remains poorly understood. Here, we apply a continental-scale model to quantify the risk of groundwater contamination by degradable pollutants through focused recharge in the carbonate rock regions of Europe, North Africa, and the Middle East. We show that focused recharge is the primary reason for widespread rapid transport of contaminants to the groundwater. Where it occurs, the concentration of pollutants in groundwater recharge that have not yet degraded increases from <1% to around 20 to 50% of their concentrations during infiltration. Assuming realistic application rates, our simulations show that degradable pollutants like glyphosate can exceed their permissible concentrations by 3 to 19 times when reaching the groundwater. Our results are supported by independent estimates of young water fractions at 78 carbonate rock springs over Europe and a dataset of observed glyphosate concentrations in the groundwater. They imply that in times of continuing and increasing industrial and agricultural productivity, focused recharge may result in an underestimated and widespread risk to usable groundwater volumes.

The interplay of social rank perceptions of Trump and Biden and emotions following the U.S. presidential election 2020.

The outcome of the 2020 U.S. election between Trump and Biden evoked strong emotions. In U.S. American (Study 1; N = 405) and German (Study 2; N = 123) samples, we investigated how observers' group membership (i.e. political orientation) and the social rank attainment of both candidates (i.e. dominance vs. prestige) predicted emotional reactions. Trump was generally perceived as more dominant, and Biden as more prestigious. However, perceptions of social rank attainment differed depending on the observers' political orientation, either matching or not matching with the leaders (i.e. Republicans and Democrats, respectively). The candidate who did not share the participants' political orientation was perceived as less prestigious and more dominant and elicited stronger contrastive emotions (i.e. schadenfreude, malicious envy) and weaker assimilative emotions (i.e. happy-for-ness, sympathy, anger), and vice versa. Crucially, dominance and prestige perceptions explained variance in the emotional reactions of more conservative and more liberal participants. Prestige positively predicted assimilative emotions and dominance contrastive emotions. Our work advances theorising by providing evidence that dominance and prestige perceptions contribute to the elicitation of various emotions. Furthermore, it suggests that prestige and dominance are not fixed characteristics of liberal and conservative leaders but depend on the observers' group membership.

Surprise me! On the impact of unexpected benefits on other-praising gratitude expressions.

Gratitude reinforces social bonds. This relationship-regulating function depends on whether and how it is expressed. People can express gratitude in different ways: Beneficiaries may emphasise how they profited from a benefit (self-benefiting) or focus on the benefactor's actions and characteristics related to it (other-praising). What underlies these expressive styles remains unclear. Based on findings that other-praising gratitude expressions have unique positive effects on interpersonal relationships, four studies (N = 1,188) investigated a novel antecedent of these expressions: unexpectedness of the benefit. In Study 1, we content-coded participants' thank-you notes for an actual Christmas present. Path modelling revealed that unexpectedness of the benefit predicted other-praising, whereas happiness with the present predicted self-benefiting. These results were robust to relevant covariates and mirrored by participants' self-reported self-benefiting and other-praising intentions. Studies 2-4 (preregistered) investigated samples from two different populations and experimentally manipulated (un)expectedness of recalled or imagined benefits. Given mixed experimental results, we conducted an internal meta-analysis. Across experimental studies, unexpected benefits increased other-praising, albeit weakly so, but not self-benefiting. In addition, the effect of unexpectedness on other-praising was significantly different from that on self-benefiting. We discuss potential processes and moderators of the effect of unexpected benefits on gratitude expressions.

Identification and location tasks rely on different mental processes: a diffusion model account of validity effects in spatial cueing paradigms with emotional stimuli.

Spatial cueing paradigms are popular tools to assess human attention to emotional stimuli, but different variants of these paradigms differ in what participants' primary task is. In one variant, participants indicate the location of the target (location task), whereas in the other they indicate the shape of the target (identification task). In the present paper we test the idea that although these two variants produce seemingly comparable cue validity effects on response times, they rest on different underlying processes. Across four studies (total N = 397; two in the supplement) using both variants and manipulating the motivational relevance of cue content, diffusion model analyses revealed that cue validity effects in location tasks are primarily driven by response biases, whereas the same effect rests on delay due to attention to the cue in identification tasks. Based on this, we predict and empirically support that a symmetrical distribution of valid and invalid cues would reduce cue validity effects in location tasks to a greater extent than in identification tasks. Across all variants of the task, we fail to replicate the effect of greater cue validity effects for arousing (vs. neutral) stimuli. We discuss the implications of these findings for best practice in spatial cueing research.

Does the shape of the copper intrauterine device play a role in expulsion? Results from the ongoing European Active Surveillance Study on LCS12.

OBJECTIVE: To compare the incidence of expulsion for different copper intrauterine device (IUD) shapes. STUDY DESIGN: We conducted a secondary analysis of the ongoing, prospective, non-interventional European Active Surveillance Study on LCS12 (EURAS-LCS12). Users of newly inserted IUDs were recruited in 10 European countries via a network of approximately 1200 clinicians. We restricted the analysis to copper IUD users. In the main analysis, we classified copper IUDs by shape [Nova-T frame, Tatum-T frame, Multiload frame, frameless IUDs and intrauterine balls], without differentiation of size. We calculated the cumulative incidence, crude, and adjusted hazard ratios for expulsion. Covariates included in the adjusted analyses were age, BMI, parity, education, income, IUD user status, marital status, length of device, heavy menstrual bleeding, and clinician's experience. RESULTS: We included 26,381 copper IUD users from the EURAS-LCS12 dataset for this study. The most frequently used IUD shape was the Nova-T frame (14,724 [55.8%]) followed by the Tatum-T frame (4276 [16.2%]), frameless IUDs (3374 [12.8%]), Multiload frame (2962 [11.2%]), and intrauterine balls (IUBs) (1045 [4.0%]). Cox regression analysis regarding expulsions yielded an adjusted hazard ratio of 0.8 (95% CI, 0.7-1.0), 1.3 (95% CI, 1.0-1.8), 1.6 (95% CI, 1.2-2.1) and 3.6 (95% CI, 2.7-4.9) for Nova-T frame IUD, frameless IUDs, Multiload frame IUDs and IUBs versus Tatum-T frame IUD, respectively. CONCLUSION: The risk of expulsion following placement of a copper IUD is related to IUD shape, with Nova-T frame and Tatum-T frame IUDs demonstrating the lowest risk. IMPLICATIONS: Our finding of a higher risk of expulsion observed with Multiload frame, frameless, and intrauterine ball copper IUDs compared to Tatum-T frame and Nova-T frame devices during real world use has clinical importance. Clinicians may choose to use these data when counseling patients.

Safety and effectiveness of a nurse-led outreach program for assessment and treatment of chronic hepatitis C in the custodial setting.

BACKGROUND: The global burden of disease attributable to chronic hepatitis C virus (HCV) is very large, yet the uptake of curative antiviral therapies remains very low, reflecting the marginalized patient population and the arduous nature of current treatments. METHODS: The safety and effectiveness of a nurse-led model of care of inmates with chronic HCV was evaluated in 3 Australian correctional centers. The model featured protocol-driven assessment, triage, and management of antiviral therapy by specifically trained nurses, with specialist physician support utilizing telemedicine. Outcomes were evaluated qualitatively with key informant interviews, and quantitatively with patient numbers completing key clinical milestones and adverse events. RESULTS: A total of 391 patients with chronic HCV infection were enrolled, of whom 141 (36%) completed the clinical and laboratory evaluations for eligibility for antiviral therapy over 24 months. Treatment was initiated in 108 patients (28%), including 85 (79%) triaged for specialist review conducted by telemedicine only. The demographic and clinical characteristics of the patients who entered the model and completed workup and those who initiated treatment featured a high prevalence of individuals of indigenous background, injection drug users, and those with psychiatric disorder. Serious adverse events occurred in 13 of 108 treated patients (12%) with discontinuation in 8 (7%). The sustained virologic response rate among those with complete follow-up data (n=68) was 69%, and by intention-to treat analysis was 44%. CONCLUSIONS: This nurse-led and specialist-supported assessment and treatment model for inmates with chronic HCV offers potential to substantively increase treatment uptake and reduce the burden of disease.

Embedding Research on Emotion Duration in a Network Model.

Contrary to early theorizing, emotions often last for longer periods of time. Variability in people's emotion duration contributes to psychopathologies. Therefore, emotion theories need to account for this variability. So far, reviews only list predictors of emotion duration without integrating them in a theoretical framework. Mechanisms explaining why these predictors relate to emotion duration remain unknown. I propose to embed research on emotion duration in a network model of emotions and illustrate the central ideas with simulations using a formal network model. In the network model, the components of an emotion have direct causal effects on each other. According to the model, emotions last longer (a) when the components are more strongly connected or (b) when the components have higher thresholds (i.e., they are more easily activated). High connectivity prolongs emotions because components are constantly reactivated. Higher thresholds prolong emotions because components are more easily reactivated even when connectivity is lower. Indirect evidence from research on emotion coherence and research on the relationship of predictors of emotion duration with components outside of emotional episodes supports the usefulness of the network model. I further argue and show in simulations that a common cause model, in which a latent emotion causes changes in emotion components, cannot account for research on emotion duration. Finally, I describe future directions for research on emotion duration and emotion dynamics from a network perspective. Supplementary Information: The online version contains supplementary material available at 10.1007/s42761-023-00203-3.

Comparing implications of distinct emotion, network, and dimensional approaches for co-occurring emotions.

Many situations elicit multiple emotions at the same time. Therefore, emotion theories should explain when and how emotions co-occur. We compared four parsimonious, formal theories that could explain emotion co-occurrence inspired by distinct emotion, network, and dimensional approaches to emotions. In three studies (N = 1,038), diverse participants rated the intensity of awe and kama muta (Study 1; US community sample; conducted in 2020), shame and guilt (Study 2; Dutch students; conducted in 2006), or awe and fear (Study 3; GB community sample; conducted in 2022) on multi-componential scales in response to emotion-eliciting stimuli (i.e., vignettes or videos). All three studies indicated that the network theory explains the data best. The theory implies that emotions co-occur because the networks of interacting components representing different emotions partly overlap. The parsimonious model can serve as a starting point for a comprehensive formal theory that is able to integrate seemingly inconsistent findings in research on co-occurring emotions. (PsycInfo Database Record (c) 2023 APA, all rights reserved).

The impact of floating photovoltaic power plants on lake water temperature and stratification.

Floating photovoltaics (FPV) refers to photovoltaic power plants anchored on water bodies with modules mounted on floats. FPV represents a relatively new technology in Europe and is currently showing a rapid growth in deployment. However, effects on thermal characteristics of lakes are largely unknown, yet these are crucial for licensing and approval of such plants. Here, we quantify FPV impacts on lake water temperature, energy budget and thermal stratification of a lake through measurements of near-surface lateral wind flow, irradiance, air and water temperatures at one of the largest commercial German facilities, situated on a 70 m deep dredging lake in the Upper Rhine Valley, South-West Germany. Underneath the FPV facility, a 73% reduction in irradiance on the lake surface and an average 23% reduction in near-surface wind speed at module height are detected. A three month data set is then used to set up the General Lake Model and simulate scenarios of different FPV occupancies and changing climatic conditions. We observe that a lake coverage with FPV result in a more unstable and shorter thermal stratification during summer, which could mitigate the effects of climate change. The reduction of water temperatures follows a non-linear relationship with increased FPV occupancy. A sensitivity analysis showed that an increased wind reduction by FPV can have a considerable impact on the thermal properties of the lake. However, measurements only suggest small deviations with regard to the thermal properties of the investigated lake. These findings can be used in approval procedures and allow for a more accurate assessment of environmental impacts of future installations.

Pregnancy and pregnancy outcomes in a prospective cohort study: Final results from the Nexplanon Observational Risk Assessment Study (NORA).

OBJECTIVES: To monitor pregnancy occurrence and outcomes among Nexplanon users in the United States during standard clinical practice. STUDY DESIGN: The Nexplanon Observational Risk Assessment (NORA) study was a large prospective cohort study conducted in the United States (US). Study participants with a newly inserted Nexplanon implant were recruited by health care professionals (HCPs) who had completed the Nexplanon clinical training. Via a survey, study participants were followed up at 6-month intervals for 36 months and 6 months after implant removal. Reported unintended pregnancies were validated and classified as noninsertion, preinsertion, during-use, or postremoval. RESULTS: Four hundred and twenty-eight HCPs in 47 states recruited 7364 Nexplanon users. Pregnancies included one noninsertion, eight preinsertion, three during-use, and 14 postremoval pregnancies; of these 26 pregnancies, 22 resulted in the birth of a healthy child, two resulted in an induced abortion, one resulted in a spontaneous abortion, and one resulted in an ectopic pregnancy. Six pregnancies occurred during-use (n = 3) or within 7 days following implant removal (n = 3), yielding a Pearl Index of 0.04 (95% CI, 0.02-0.09). CONCLUSIONS: Nexplanon is an effective contraceptive in real-world users; the Pearl Index was 0.02 (95% CI, 0.00-0.06) for during-use pregnancies, and 0.04 when including pregnancies that occurred within 7 days following implant removal. IMPLICATIONS: This large real-world-use study indicates that Nexplanon is as effective as shown in the preapproval clinical trials.

TEMPORARILY WITHDRAWN: Does the shape of the copper intrauterine device play a role in expulsion? Results from the ongoing European Active Surveillance Study on LCS12.

This article has been temporarily withdrawn at the request of the author(s) and/or editor. The Publisher apologizes for any inconvenience this may cause. The full Elsevier Policy on Article Withdrawal can be found at https://www.elsevier.com/about/policies/article-withdrawal

Surface plasmon assisted optical nonlinearities of uniformly oriented metal nano-ellipsoids in glass.

The nonlinear optical properties of nanocomposites consisting of non-spherical silver nanoparticles in glass matrix have been studied using the femtosecond Z-scan technique. The spheroidal nanoparticles were uniformly oriented along a common direction. By polarization sensitive studies, longitudinal and transverse plasmon resonances can be addressed separately. A sign reversal in optical nonlinearity from negative to positive is observed while switching the light interaction from near to non-resonant regime, which can be done by simply rotating the light polarization by 90°. Studying samples with different aspect ratio, we obtained the dispersion of third-order nonlinearity in the near-resonant regime, showing an enhancement of the nonlinear processes by more than two orders of magnitude due to the electric field enhancement at the surface plasmon resonance.

Reading emotions, reading people: Emotion perception and inferences drawn from perceived emotions.

Emotional expressions play an important role in coordinating social interaction. We review research on two critical processes that underlie such coordination: (1) perceiving emotions from emotion expressions and (2) drawing inferences from perceived emotions. Broad evidence indicates that (a) observers can accurately perceive emotions from a person's facial, bodily, vocal, verbal, and symbolic expressions and that such emotion perception is further informed by contextual information. Moreover, (b) observers draw consequential and contextualized inferences from these perceived emotions about the expresser, the situation, and the self. Thus, emotion expressions enable coordinated action by providing information that facilitates adaptive behavioral responses. We recommend that future studies investigate how people integrate information from different expressive modalities and how this affects consequential inferences.

"You're just envious": Inferring benign and malicious envy from facial expressions and contextual information.

Envy shapes social hierarchies. To protect their rank, envied persons react to the threat posed by enviers. Doing so requires that envied persons initially perceive who envies them. However, a common perspective is that envy lacks a unique expression and that enviers disguise their experience, preventing the social perception of envy. In contrast to this perspective, recent evidence indicates that observers perceive benign and malicious forms of envy accurately when they can integrate information about targets. These findings suggest that observers infer envy based on multiple, contextual cues. We hypothesized that observers infer envy from facial and bodily expressions in comparison situations. Specifically, observers should infer benign envy when a target, who encounters an advantaged person, turns with disappointment toward the advantage. Conversely, observers should infer malicious envy when the target turns with anger toward the advantaged person. Three preregistered studies tested these hypotheses (total N = 693). In Studies 1 and 2, targets turned with an emotional or neutral expression either toward a person silhouette or a valuable object, and participants rated targets' envy. In Study 3, participants performed the same task with more realistic stimuli. Across studies, emotional display and head turning had independent effects on inferences of benign and malicious envy. Furthermore, observers inferred envy more when the target expressed an emotion instead of remaining neutral. We discuss how the results inform research on the social perception of envy. (PsycInfo Database Record (c) 2022 APA, all rights reserved).

Gain and retain - On the efficiency of modified agricultural drainage ponds for pesticide retention.

Drainage ponds have the potential to serve as long-term interface measures primarily for flood control, and mass retention. They are often considered as promising supplements for the mitigation of drainage pipe loads to improve the water quality in agricultural landscapes. In this study, a highly dynamic drainage pond system with non-steady inflows and groundwater interaction was modified and investigated regarding its potential for pesticide and transformation product (TP) retention. For this purpose, two 104-day monitoring campaigns were conducted before and after pond modification. Field experiments with fluorescent tracers, Uranine and Sulforhodamine-B, proved that structural modifications improved the hydraulic functionality of the ponds. The effective volume (Ɛ) increased from 20% to almost 100% in the modified pond and the mean hydraulic residence time (τ) was ten times longer. After a dry period, pesticide retention was high during slow refilling of the ponds, still TP loads posed a risk by infiltration into shallow groundwater due to the permeable ground. During wet periods, short nominal detention times together with high inflows led to rare high retention rates through peak attenuation. Moderate inflows resulted in extremely variable retention values, owing to the small pond storage capacity. Along with this, the total retention efficiency after modification reached up to 38% for mobile, 29% for sorptive pesticides, and 32% for mobile TPs. To achieve the best performances for ponds as natural landscape elements, they should be analysed for their hydrological functionality as a prerequisite and then modified for delayed pesticide and TP transport. Then, dynamic drainage ponds can utilize their full potential regarding mitigation of pesticide and TP loads in agricultural catchments.

Counterfactual thoughts distinguish benign and malicious envy.

When people encounter others surpassing them in terms of an important quality, possession, or achievement, they often think about what might have happened differently so that they would have obtained a better outcome. Such upward counterfactual thoughts have been shown to contribute to the intensity of envy. We investigated whether specific counterfactual thoughts distinguish different forms of envy, namely benign envy, which entails upward motivation, and malicious envy-which entails hostility. A meta-analysis of 8 studies (1 preregistered, N = 1,264) of a first line of research supports that recalled episodes of benign versus malicious envy are characterized by more additive, self-focused counterfactuals or by more other-focused counterfactuals, respectively. Furthermore, a meta-analysis of 6 studies (1 preregistered, N = 1,299) of a second line of research supports that eliciting these counterfactuals promotes the corresponding form of envy. In line with functional accounts of counterfactual thinking and envy, the results highlight cognitive processes that underlie functionally diverging pathways of envious responding. (PsycInfo Database Record (c) 2021 APA, all rights reserved).

Field insights into leaching and transformation of pesticides and fluorescent tracers in agricultural soil.

The frequent detection of residues from pesticides in various natural water types has raised public awareness. This study investigated the pesticide transformation in soil and their loss to shallow groundwater in a small agricultural catchment in Northern Germany. The pesticide Flufenacet and its transformation product Flufenacet ESA were examined in Luvisol and Colluvic Gleyosol under field conditions during two consecutive years. In the second year, a fluorescent tracer experiment applying Uranine and Sulforhodamine - B was carried out to gain additional insights into leaching and formation of transformation products in soil during and after a drought. We found preferential flow in response to low precipitation as an important transport pathway for Flufenacet in dry soil, as a Flufenacet concentration (1.57 µg L-1) was detected in shallow groundwater within 10 days after application. Leaching of Flufenacet to shallow groundwater by preferential flow posed greater risks during the dry than during the wet period. In contrast, Flufenacet ESA was detected in all groundwater samples. During the dry period, we detected no formation of TP510 (tracer transformation product) in the immediate topsoil. A fraction of both tracers remained there, suggesting also long-term residues of pesticides in the topsoil caused by limited living conditions for microorganisms under dry conditions. Newly formed transformation products of Uranine and Flufenacet were mainly trapped in upper soil if capillary flow was marginal. Formation of TP510 could be related to a soil water optimum and a soil temperature threshold. The occurrence of increased TP510 amounts in soil after drought was concurrent with the main peak of Flufenacet ESA in shallow groundwater. This suggested similar retention and transformation processes of fluorescent tracers and organic pesticides inside the soil. This study contributed to an extended understanding of the leaching and transformation of organic pollutants in agricultural soil under real field conditions.

Urban storm water infiltration systems are not reliable sinks for biocides: evidence from column experiments.

Groundwater quality in urban catchments is endangered by the input of biocides, such as those used in facade paints to suppress algae and fungal growth and washed off by heavy rainfall. Their retention in storm water infiltration systems (SIS) depends, in addition to their molecular properties, on chemical properties and structure of the integrated soil layer. These soil properties change over time and thus possibly also the relevance of preferential flow paths, e.g. due to ongoing biological activity. To investigate the mobility of biocides in SIS, we analyzed the breakthrough of differently adsorbing tracers (bromide, uranine, sulforhodamine B) and commonly used biocides (diuron, terbutryn, octhilinone) in laboratory column experiments of undisturbed soil cores of SIS, covering ages from 3 to 18 years. Despite similar soil texture and chemical soil properties, retention of tracers and biocides differed distinctly between SIS. Tracer and biocide breakthrough ranged from 54% and 5%, to 96% and 54%, respectively. We related the reduced solute retention to preferential transport in macropores as could be confirmed by brilliant blue staining. Our results suggest an increasing risk of groundwater pollution with increasing number of macropores related to biological activity and the age of SIS.

How hierarchy shapes our emotional lives: effects of power and status on emotional experience, expression, and responsiveness.

Hierarchy is a defining characteristic of social life that profoundly shapes human psychology. Here, we draw attention to the pervasive impact of social rank on emotional processes. We review the effects of rank (power and status) on emotional experience, expression, and responsiveness. Our review indicates that (1) lower-ranking individuals experience more negative emotions, whereas higher-ranking individuals experience more positive emotions; (2) lower-ranking individuals adapt their emotional expressions to the social context, whereas higher-ranking individuals express their feelings more freely; (3) lower-ranking individuals accurately perceive and respond to the emotional expressions of others, whereas higher-ranking individuals do so only when others' emotions are self-relevant. Finally, (4) power and status have very similar effects on emotional processes, suggesting opportunities for theoretical integration.

Accuracy and bias in the social perception of envy.

Research converges on the notion that when people feel envy, they disguise it toward others. This implies that a person's envy in a given situation cannot be accurately perceived by peers, as envy lacks a specific display that could be used as a perceptual cue. In contrast to this reasoning, research supports that envy contributes to the regulation of status hierarchies. If envy threatens status positions, people should be highly attentive to identify enviers. The combination of the two led us to expect that (a) state envy is difficult to accurately perceive in unacquainted persons and (b) dispositional enviers can be accurately identified by acquaintances. To investigate these hypotheses, we used actor-partner interdependence models to disentangle accuracy and bias in the perception of state and trait envy. In Study 1, 436 unacquainted dyad members competed against each other and rated their own and the partner's state envy. Perception bias was significantly positive, yet perception accuracy was nonsignificant. In Study 2, 502 acquainted dyad members rated their own and the partner's dispositional benign and malicious envy as well as trait authentic and hubristic pride. Accuracy coefficients were positive for dispositional benign and malicious envy and robust when controlling for trait authentic and hubristic pride. Moreover, accuracy for dispositional benign envy increased with the depth of the relationship. We conclude that enviers might be identifiable but only after extended contact and discuss how this contributes to research on the ambiguous experience of being envied. (PsycInfo Database Record (c) 2020 APA, all rights reserved).