1.
J Am Chem Soc
; 145(1): 37-40, 2023 01 11.
Artículo
en Inglés
| MEDLINE
| ID: mdl-36563100
RESUMEN
Herein, the first total synthesis of (+)-alterbrassicicene C (2) is described. Key features of the synthesis include an oxiranium mediated ether ring expansion, an oxa-Michael/retro-oxa-Michael cascade, and installation of a vinyl methoxy ether moiety via Stille coupling.