Evolution of Thermoelectric Generators: From Application to Hybridization.

Considerable thermal energy is emitted into the environment from human activities and equipment operation in the course of daily production. Accordingly, the use of thermoelectric generators (TEGs) can attract wide interest, and it shows high potential in reducing energy waste and increasing energy recovery rates. Notably, TEGs have aroused rising attention and been significantly boosted over the past few years, as the energy crisis has worsened. The reason for their progress is that thermoelectric generators can be easily attached to the surface of a heat source, converting heat energy directly into electricity in a stable and continuous manner. In this review, applications in wearable devices, and everyday life are reviewed according to the type of structure of TEGs. Meanwhile, the latest progress of TEGs' hybridization with triboelectric nanogenerator (TENG), piezoelectric nanogenerator (PENG), and photovoltaic effect is introduced. Moreover, prospects and suggestions for subsequent research work are proposed. This review suggests that hybridization of energy harvesting, and flexible high-temperature thermoelectric generators are the future trends.

In-situ determination of spin polarization in a single-beam fiber-coupled spin-exchange-relaxation-free atomic magnetometer with differential detection.

The electronic spin polarization of alkali-metal-vapor atoms is a pivotal parameter for atomic magnetometers. Herein, a novel method is presented for determining the spin polarization with a miniaturized single-beam spin-exchange-relaxation-free (SERF) magnetometer on the basis of zero-field cross-over resonance. Two separate laser beams are utilized to heat the cell and interrogate the vapor atoms, respectively. Spin polarization can be extracted by measuring the resonance response signal of the magnetometer to the transverse magnetic field under different irradiances. Results of these experiments are consistent well with the theoretical predictions with the maximum deviation less than 4%. The proposed method has the integrated advantages of possessing a simple configuration and in-situ measurement. Furthermore, combined with a homemade optical differential detection system with a factor of approximately three of the power noise suppression, the developed single-beam SERF atomic magnetometer with a measuring sensitivity of 32 fT/Hz1/2 has been achieved. This demonstrated approach can help guide the development of chip-scale atomic magnetometers for bio-magnetic field imaging applications.

Efficient fluorescence coupling microlens integrated fiber magnetometer probe based on nitrogen vacancy centers.

The nitrogen vacancy (NV) centers in diamonds have gathered increasing interest as an emerging quantum sensing platform with high sensitivity and spatial resolution. Integration of micro-sized diamond and fiber is an essential method to build an NV center endoscope probe and enable NV center sensors for practical application. However, the low fluorescence collection efficiency of fibers due to their small numerical aperture (NA) has limited the sensitivity of the sensors. In this paper, a cone-shape microlens was fabricated using the photopolymerization process at the end of a multimode fiber to boost the laser excitation and fluorescence collection efficiency of NV centers. Experiments demonstrated that over 21 times fluorescence intensity enhancement and 12 times sensitivity improvement were achieved. This fiber-microlens magnetometer probe exhibited a 2.1-nT/Hz1/2 sensitivity over a bandwidth of 100 Hz with ∼80-µm diameter diamond. This research presented a robust and large NA diamond integrated fiber-microlens magnetometer probe, which can also be expanded to magnetic field scan and real-time monitoring.

Electro-optic high-speed optical beam shifting based on a lithium niobate tapered waveguide.

We propose an electro-optic on-chip beam shifting device based on gradient microstructured electrodes and an optical tapered waveguide fabricated using lithium niobate (LN). The distribution of refractive index variations of the optical waveguide can be electro-optically defined and tailored by the designed gradient microstructured electrodes, which directs the beam propagation and shifting. The length of the beam shifting device is 18 mm and the width of the waveguide is gradually increased from 8 µm to 80 µm. The functionality of the beam shifting device is experimentally demonstrated, and it is observed that it has an electro-optic tunability of 0.41 µm/V, and a high-speed response time of 19 ns (λ=1310 nm). This study can provide potential applications in optical switching and modulation, beam scanning and ranging, optical spatial communications, etc.

Compact Tri-FFPI sensor for measurement of ultrahigh temperature, vibration acceleration, and strain.

As a high-precision fiber optic sensor, a single optical fiber Fabry Pérot interferometer (FFPI) sensor is often used to measure parameters such as temperature or strain. However, the use of combined FFPIs to measure multiple parameters simultaneously has rarely been reported. In this paper, a compact Tri-FFPI sensor consisting of three series-connected FFPIs is proposed to measure high temperature, high acceleration, and large strain. The total length and diameter of the sensing part are only 2558.9 µm and 250 µm, respectively. One of the FFPIs, FFPI-1, contains a cantilever beam structure to measure vibration acceleration. FFPI-2 is used to measure temperature and the temperature compensation of the strain measurement. FFPI-3 is used to measure strain. To ensure that the sensor has high measurement sensitivity, two demodulation methods are used: the light intensity demodulation method for vibration acceleration and the wavelength demodulation method for temperature and strain. The sensor is capable of withstanding ultrahigh temperatures up to 1000°C.

Single beam Cs-Ne SERF atomic magnetometer with the laser power differential method.

We describe a single beam compact spin exchange relaxation free (SERF) magnetometer whose configuration is simple and compatible with the silicon-glass bonding micro-machining method. Due to the small size of the vapor cell utilized in a miniature atomic magnetometer, the wall relaxation could not be neglected. In this study we show that Ne buffer gas is more efficient than that of the other typically utilized gas species such as nitrogen and helium for wall relaxation reduction theoretically and experimentally. 3 Amagats (1 Amagat=2.69×1019/cm3) Ne gas is filled in the vapor cell and this is the first demonstration of a Cs-Ne SERF magnetometer. In order to reduce the laser amplitude noise and the large background detection offset, which is reported to be the main noise source of a single beam absorption SERF magnetometer, we developed a laser power differential method and a factor of approximately two improvement of the power noise suppression has been demonstrated. In order to reduce the power consumption of the magnetometer, the Cs based atomic magnetometer is studied. We did an optimization of the magnetometer and a sensitivity of 23fT/Hz1/2@100Hz has been achieved. This is the first demonstration of a single beam Cs based SERF magnetometer.

All electrospun fabrics based piezoelectric tactile sensor.

Tactile sensors have been widely used in the areas of health monitoring and intelligent human-machine interface. Flexible tactile sensors based on nanofiber mats made by electrospinning can meet the requirements of comfortability and breathability for wearing the body very well. Here, we developed a flexible and self-powered tactile sensor that was sandwich assembled by electrospun organic electrodes and a piezoelectric layer. The metal-free organic electrodes of thermal plastic polyurethane (PU) nanofibers decorated with multi-walled carbon nanotubes were fabricated by electrospinning followed by ultrasonication treatment. The electrospun polyvinylidene fluoride-trifluoroethylene (PVDF-TrFE) mat was utilized as the piezoelectric layer, and it was found that the piezoelectric performance of PVDF-TrFE nanofiber mat added with barium titanate (BaTiO3) nanoparticles was enhanced about 187% than that of the pure PVDF-TrFE nanofiber mat. For practical application, the as-prepared piezoelectric tactile sensor exhibited an approximative linear relationship between the external force and the electrical output. Then the array of fabricated sensors was attached to the fingertips of a glove to grab a cup of water for tactile sensing, and the mass of water can be directly estimated according to the outputs of the sensor array. Attributed to the integrated merits of good flexibility, enhanced piezoelectric performance, light weight, and efficient gas permeability, the developed tactile sensor could be widely used as wearable devices for robot execution end or prosthesis for tactile feedback.

Joint-peaks demodulation method based on multireflection peaks of a few-mode fiber Bragg grating for reducing sensing error.

A few-mode fiber Bragg grating (FM-FBG) inscribed in a few-mode fiber (FMF) can maintain multiple reflection peaks due to the stable multiple modes in FMF. This paper studies the sensing characteristics of multiple reflection peaks for a four-mode FBG (4M-FBG) and innovatively proposes a joint-peak demodulation method based on one FM-FBG to reduce measurement error in temperature or strain sensing. This joint-peak demodulation method, theoretically explained and experimentally verified, provides the possibility of generating miniature sensors with high measurement accuracy and stable measurement performance. The potential of 4M-FBG for simultaneous measurement of strain and temperature is studied in this paper. By measuring the changes of wavelength and intensity of the reflection peaks, temperature and strain can be measured effectively.

Adaptive high-precision demodulation method based on vector matching and cluster-competitive particle swarm optimization for multiplexed FPIs.

Multiplexed fiber optic Fabry-Perot interferometer (FPI) sensors are well known for their precision, simple construction, simpler wiring, and high sensing qualities. However, the limitations on existing demodulation methods degrade the measurement accuracy of multiplexed FPI sensors and necessitate large cavity length differences. In this paper, we propose an adaptive high-precision demodulation method based on vector matching and cluster-competitive particle swarm optimization (CCPSO), which transforms cavity length demodulation into searching for the global extreme. The proposed CCPSO, which uses agglomeration within clusters and competition between clusters simultaneously, enables the improvement of the global extreme search capabilities. The theoretical analysis and experimental results show that the proposed demodulation method decreases the lower limit of the needed cavity length differences to 22 µm, which is reduced by 76.9% compared with the fast Fourier transform-based method. An accuracy of 1.05 nm is achieved with a cavity length difference of 27.5 µm and a signal-to-noise ratio of 36.0 dB for the noise.

Design and Analysis of a Combined Strain-Vibration-Temperature Sensor with Two Fiber Bragg Gratings and a Trapezoidal Beam.

A combined sensor to simultaneously measure strain, vibration, and temperature has been developed. The sensor is composed of two Fiber Bragg gratings (FBGs) and a vibration gainer. One FBG is used to measure strain, while the other measures vibration and temperature. The gainer has a mass block which is used to increase its sensitivity to vibration. The main beam of the vibration gainer was designed as a trapezoid in order to reduce the strain gradient while sensing vibration. In addition, an interrogation method was used to eliminate interactions between measured parameters. Experiments were carried out to analyze the performance of the proposed sensor. For individual strain measurement in the range of 0-152 µÎµ, the sensitivity and nonlinearity error were 1.878 pm/µÎµ and 2.43% Full Scale (F.S.), respectively. For individual temperature measurement in the range of 50-210 °C, the sensitivity and nonlinearity error were 29.324 pm/°C and 1.88% F.S., respectively. The proposed sensor also demonstrated a sensitivity of 0.769 pm/m·s-2 and nonlinearity error of 1.83% F.S. for vibration measurement in the range of 10-55 m/s2. Finally, simultaneously measuring strain, temperature, and vibration resulted in nonlinearity errors of 4.23% F.S., 1.89% F.S., and 2.23% F.S., respectively.

Environmental Monitoring of Ancient Buildings Based on a Wireless Sensor Network.

Environmental monitoring plays an important role in the preventive protection of ancient buildings, although it is still in the prototype stage. In order to provide data support for the protection of ancient buildings, an environmental monitoring system with multi-sensor and multi-node for the interior and exterior of ancient buildings is designed and realized, based on ZigBee, TCP/IP, and intranet penetration technology. The new type of indoor node package box and outdoor package device are designed to meet the needs of different types of sensors. The monitoring platform is developed on the strength of the LabView so as to obtain real-time display, storage, and over-limit warning functions for local and remote monitoring data. It also proves that the monitoring system is stable and reliable by monitoring the actual ancient building with a brick (stone) structure.

Ordinary Optical Fiber Sensor for Ultra-High Temperature Measurement Based on Infrared Radiation.

An ordinary optical fiber ultra-high temperature sensor based on infrared radiation with the advantages of simple structure and compact is presented. The sensing system consists of a detection fiber and a common transmission fiber. The detector fiber is formed by annealing a piece of ordinary fiber at high temperature twice, which changes the properties of the fiber and breaks the temperature limit of ordinary fiber. The transmission fiber is a bending insensitive optical fiber. A static calibration system was set up to determine the performance of the sensor and three heating experiments were carried out. The temperature response sensitivities were 0.010 dBm/K, 0.009 dBm/K and 0.010 dBm/K, respectively, which indicate that the sensor has good repeatability. The sensor can withstand a high temperature of 1823 K for 58 h with an error of less than 1%. The main reason why the developed ordinary optical fiber sensor can work steadily for a long time at high temperature is the formation of ß-cristobalite, which is stable at high-temperature.

Modeling and Analysis of a Combined Stress-Vibration Fiber Bragg Grating Sensor.

A combined stress-vibration sensor was developed to measure stress and vibration simultaneously based on fiber Bragg grating (FBG) technology. The sensor is composed of two FBGs and a stainless steel plate with a special design. The two FBGs sense vibration and stress and the sensor can realize temperature compensation by itself. The stainless steel plate can significantly increase sensitivity of vibration measurement. Theoretical analysis and Finite Element Method (FEM) were used to analyze the sensor's working mechanism. As demonstrated with analysis, the obtained sensor has working range of 0-6000 Hz for vibration sensing and 0-100 MPa for stress sensing, respectively. The corresponding sensitivity for vibration is 0.46 pm/g and the resulted stress sensitivity is 5.94 pm/MPa, while the nonlinearity error for vibration and stress measurement is 0.77% and 1.02%, respectively. Compared to general FBGs, the vibration sensitivity of this sensor is 26.2 times higher. Therefore, the developed sensor can be used to concurrently detect vibration and stress. As this sensor has height of 1 mm and weight of 1.15 g, it is beneficial for minimization and integration.

High Temperature High Sensitivity Multipoint Sensing System Based on Three Cascade Mach⁻Zehnder Interferometers.

A temperature multipoint sensing system based on three cascade Mach⁻Zehnder interferometers (MZIs) is introduced. The MZIs with different lengths are fabricated based on waist-enlarged fiber bitapers. The fast Fourier transformation is applied to the overlapping transmission spectrum and the corresponding interference spectra can be obtained via the cascaded frequency spectrum based on the inverse Fourier transformation. By analyzing the drift of interference spectra, the temperature response sensitivities of 0.063 nm/°C, 0.071 nm/°C, and 0.059 nm/°C in different furnaces can be detected from room temperature up to 1000 °C, and the temperature response at different regions can be measured through the sensitivity matrix equation. These results demonstrate feasibility of multipoint measurement, which also support that the temperature sensing system provides new solution to the MZI cascade problem.

Range Analysis of Thermal Stress and Optimal Design for Tungsten-Rhenium Thin Film Thermocouples Based on Ceramic Substrates.

A thermal stress range analysis of tungsten-rhenium thin film thermocouples based on ceramic substrates is presented to analyze the falling off and breakage problems caused by the mismatch of the thermal stresses in thin film thermocouples (TFTCs) and substrate, and nano-indentation experiments are done to measure and calculate the film stress to compare with the simulation results. Optimal design and fabrication of tungsten-rhenium TFTCs based on ceramic substrates is reported. Static high temperature tests are carried out, which show the optimization design can effectively reduce the damage caused by the thermal stress mismatch.

Theoretical Analysis of a Magnetic Shielding System Combining Active and Passive Modes.

Considering the magnetic shielding requirements of both geomagnetic field and 50 Hz power-line frequency in the complex working conditions of the power grid, an electromagnetic shielding system combining active and passive modes is proposed in this article. A three-dimensional Helmholtz coil with a magnetic shielding barrel nested inside is established by the COMSOL simulation tool, and the magnetic shielding efficiency of the system is analyzed. Comparing different materials, the simulation results indicate that permalloy alloy exhibits better shielding performance than pure iron and nickel materials. Additionally, the overall shielding efficiency of the shielding barrel increases linearly with the number of multiple layers. Under the combined active and passive electromagnetic shielding conditions, the system achieves a shielding efficiency of SE = 113.98 dB, demonstrating excellent performance in shielding both AC and DC interference magnetic fields. This study provides theoretical guidance for the construction of magnetic shielding systems in electromagnetic interference environment.

An Intensity-Demodulated Fiber-Optic Magnetometer Based on Nanostructured Magnetic Fluid-Filled Fluidic Photonic Crystal Fibers.

An intensity-demodulated fiber-optic magnetometer is proposed and experimentally investigated, which is fabricated via fusion splicing a segment of photonic crystal fiber (PCF) between single-mode fibers (SMFs), with the cladding air holes of PCF filled with magnetic fluid. Using the magneto-optical properties of the magnetic fluid, the transmission spectrum is changed with an external magnetic field. Based on the intensity variations in the transmission spectrum, the magnetic field is detected, and a sensitivity of 0.238 dB/mT is obtained at 1550.03 nm with the length of PCF 5.5 cm. By converting light signals into electrical signals, a sensitivity of 0.003 V/mT is achieved. The fiber-optic magnetometer possesses the advantages of simple fabrication, compact/robust structure, and low cost.

Nanotoxicity of tungsten trioxide nanosheets containing oxygen vacancy to human umbilical vein endothelial cells.

Because of the excellent performance in photochemistry, WO3 is increasingly applied in the field of biology and medicine. However, little is known about the mechanism of WO3 cytotoxicity. In this work, WO3 nanosheets with oxygen vacancy are synthesized by solvothermal method, then characterized and added to culture medium of human umbilical vein endothelial cells (HUVECs) with different concentrations. We characterized and analyzed the morphology of nano-WO3 by transmission electron microscopy and calculated the specific data of oxygen vacancy by XPS. It is the first time the effect of WO3-x on cells that WO3-x can cause oxidative stress in HUVEC cells, resulting in DNA damage and thus promoting apoptosis. Transcriptome sequencing is performed on cells treated with low and high concentrations of WO3-x, and a series of key signals affecting cell proliferation and apoptosis are detected in differentially expressed genes, which indicates the research direction of nanotoxicity. The expression levels of key genes are also verified by quantitative PCR after cell treatment with different concentrations of WO3-x. This work fills the gap between the biocompatibility of nano WO3-x materials and molecular cytology and paves the way for investigating the mechanism and risks of oxygen vacancy in cancer therapy.

Advances in heart failure monitoring: Biosensors targeting molecular markers in peripheral bio-fluids.

Cardiovascular diseases (CVDs), especially chronic heart failure, threaten many patients' lives worldwide. Because of its slow course and complex causes, its clinical screening, diagnosis, and prognosis are essential challenges. Clinical biomarkers and biosensor technologies can rapidly screen and diagnose. Multiple types of biomarkers are employed for screening purposes, precise diagnosis, and treatment follow-up. This article provides an up-to-date overview of the biomarkers associated with the six main heart failure etiology pathways. Plasma natriuretic peptides (BNP and NT-proBNP) and cardiac troponins (cTnT, cTnl) are still analyzed as gold-standard markers for heart failure. Other complementary biomarkers include growth differentiation factor 15 (GDF-15), circulating Galactose Lectin 3 (Gal-3), soluble interleukin (sST2), C-reactive protein (CRP), and tumor necrosis factor-alpha (TNF-α). For these biomarkers, the electrochemical biosensors have exhibited sufficient sensitivity, detection limit, and specificity. This review systematically summarizes the latest molecular biomarkers and sensors for heart failure, which will provide comprehensive and cutting-edge authoritative scientific information for biomedical and electronic-sensing researchers in the field of heart failure, as well as patients. In addition, our proposed future outlook may provide new research ideas for researchers.

Flexible pressure sensors with ultrahigh stress tolerance enabled by periodic microslits.

Stress tolerance plays a vital role in ensuring the effectiveness of piezoresistive sensing films used in flexible pressure sensors. However, existing methods for enhancing stress tolerance employ dome-shaped, wrinkle-shaped, and pyramidal-shaped microstructures in intricate molding and demolding processes, which introduce significant fabrication challenges and limit the sensing performance. To address these shortcomings, this paper presents periodic microslits in a sensing film made of multiwalled carbon nanotubes and polydimethylsiloxane to realize ultrahigh stress tolerance with a theoretical maximum of 2.477 MPa and a sensitivity of 18.092 kPa-1. The periodic microslits permit extensive deformation under high pressure (e.g., 400 kPa) to widen the detection range. Moreover, the periodic microslits also enhance the sensitivity based on simultaneously exhibiting multiple synapses within the sensing interface and between the periodic sensing cells. The proposed solution is verified by experiments using sensors based on the microslit strategy for wind direction detection, robot movement sensing, and human health monitoring. In these experiments, vehicle load detection is achieved for ultrahigh pressure sensing under an ultrahigh pressure of over 400 kPa and a ratio of the contact area to the total area of 32.74%. The results indicate that the proposed microslit strategy can achieve ultrahigh stress tolerance while simplifying the fabrication complexity of preparing microstructure sensing films.