Rare earth elements sediment analysis tracing anthropogenic activities in the stratigraphic sequence of Alagankulam (India).

A methodological approach based on rare earth elements analysis was developed to observe human activities in the stratigraphic sequence of Alagankulam. The site was one of the main ancient ports in south-eastern India and one of the transoceanic connecting points between East and West during the Classical Period. The sampled sediments where collected from vertical profiles, areas with traces of firing activities and filled deposits. Major, minor and trace element concentrations were measured by the means of spectroscopic and spectrometric techniques. Data from multielemental analysis were then cross-referenced together with archaeological evidence to map the variability within the site and its association with the detected anthropic activities. The matching of the interpretation of the archaeological record and the analytical data has allowed a combined mapping of visible and invisible traces of human activities in the site, giving a deeper insight of the Alagankulam occupational history.

Study on ancient green materials and technology used in Udaipur palace, India: an input to abate climate changes in modern construction.

The characteristics and potential for carbon dioxide capture and storage of the fifteenth-century lime mortar samples from City Palace, Udaipur, India, were studied. Physiochemical analysis followed by XRD, FTIR, TGA-DSC, and FE-SEM was performed. The findings demonstrate that calcium-rich eminently hydraulic mortars were used with a binder/aggregate (B/Ag) ratio of about 1:2.8±0.42. Mineralogy identified load-bearing phases: aragonite, vaterite, and calcite with 45±5% clay minerals. Absorption and stretching bands detected by FTIR at 1631 cm-1 and 2954 cm-1 corroborate the inclusion of plant organics. All samples showed aragonite around 870 cm-1, which can be traced back to bonded CO2 and the subsequent carbonation throughout the age of the structure. TGA-DSC validated XRD and FE-SEM analysis exhibited 18.66±3.40% weight loss at >600 °C, indicating calcite decomposition and CO2 release with CO2/H2O ratio of 3.31 to 3.66. From the historic example, a debate has been sparked about using lime mortars in contemporary construction to mitigate the carbon footprint with inherent attributes.

Low Prevalence of Amalgam-Associated Lichenoid Lesions in the Oral Cavity: A Prospective Study.

INTRODUCTION: Amalgam has been the restoration of choice for years, but its popularity has declined due to concerns about aesthetics, mercury toxicity and lichenoid lesions associated with it. Lichenoid reaction is considered to be a delayed hypersensitivity type of reaction and it has been associated with dental materials in general and amalgam in particular. MATERIALS AND METHODOLOGY: Two thousand patients having at least one amalgam restoration were examined for signs of lichenoid lesions when visiting the OPD of Conservative Dentistry and Endodontics at the Nair Hospital Dental College in Mumbai, India. Indirect spatial correlation to the amalgam restoration and the same were recorded. Descriptive analysis was used. RESULTS: Three (0.15%) out of 2000 patients with amalgam-associated lichenoid lesions showed complete resolution of lesions after the replacement of the restorations. CONCLUSION: Amalgam associated lichenoid lesions have a low prevalence and should not be a contraindication to its use in routine restorative dental practice. Patch tests and biopsies have questionable diagnostic and prognostic value. Identification of the lesions should be made after the elimination of all other causative factors for the presenting symptoms. A close spatial association of the lesion to amalgam and the regression of symptoms after its removal should be considered as confirming the diagnosis.