RESUMEN
The 193-nm photolysis of CH2CHCN illustrates the capability of chirped-pulse Fourier transform millimeter-wave spectroscopy to characterize transition states. We investigate the HCN, HNC photofragments in highly excited vibrational states using both frequency and intensity information. Measured relative intensities of J = 1-0 rotational transition lines yield vibrational-level population distributions (VPD). These VPDs encode the properties of the parent molecule transition state at which the fragment molecule was born. A Poisson distribution formalism, based on the generalized Franck-Condon principle, is proposed as a framework for extracting information about the transition-state structure from the observed VPD. We employ the isotopologue CH2CDCN to disentangle the unimolecular 3-center DCN elimination mechanism from other pathways to HCN. Our experimental results reveal a previously unknown transition state that we tentatively associate with the HCN eliminated via a secondary, bimolecular reaction.
RESUMEN
A Chirped-Pulse millimeter-Wave (CPmmW) spectrometer is applied to the study of chemical reaction products that result from pyrolysis in a Chen nozzle heated to 1000-1800 K. Millimeter-wave rotational spectroscopy unambiguously determines, for each polar reaction product, the species, the conformers, relative concentrations, conversion percentage from precursor to each product, and, in some cases, vibrational state population distributions. A chirped-pulse spectrometer can, within the frequency range of a single chirp, sample spectral regions of up to â¼10 GHz and simultaneously detect many reaction products. Here we introduce a modification to the CPmmW technique in which multiple chirps of different spectral content are applied to a molecular beam pulse that contains the pyrolysis reaction products. This technique allows for controlled allocation of its sensitivity to specific molecular transitions and effectively doubles the bandwidth of the spectrometer. As an example, the pyrolysis reaction of ethyl nitrite, CH3CH2ONO, is studied, and CH3CHO, H2CO, and HNO products are simultaneously observed and quantified, exploiting the multi-chirp CPmmW technique. Rotational and vibrational temperatures of some product molecules are determined. Subsequent to supersonic expansion from the heated nozzle, acetaldehyde molecules display a rotational temperature of 4 ± 1 K. Vibrational temperatures are found to be controlled by the collisional cooling in the expansion, and to be both species- and vibrational mode-dependent. Rotational transitions of vibrationally excited formaldehyde in levels ν4, 2ν4, 3ν4, ν2, ν3, and ν6 are observed and effective vibrational temperatures for modes 2, 3, 4, and 6 are determined and discussed.
RESUMEN
We present here the analysis of experimental Stark effect measurements made using photofragment quantum beat spectroscopy on the |4,0(-)>, |5,0(-)>, |8,0(+)> and |4,0(-)>|2> vibrational states of H(2)O [ Callegari , A. ; et al. Science 2002 , 297 , 993.]. To link the measured Stark coefficients with the dipole surface, we analyze our results using a coupled anharmonic oscillator model, which takes into account the local-mode nature of higly excited OH stretching vibrations in water, and the tunneling between the two equivalent bonds. The large inertial frame tilt associated with the local-mode bond stretching results in a complex interaction between rotational-, vibrational-, and tunneling-motion, all of which become deeply entangled in the Stark coefficients. A perturbational approach makes it possible to analyze the problem at increasingly higher levels of approximation and to disentangle the different contributions, according to the different time scales involved. This simple model reproduces most experimental values to within a few percent, even for these highly vibrationally excited levels, and gives valuable insight into the complex rotational and vibrational motions that link the dipole moment surface with the Stark coefficients.
RESUMEN
An apparatus is presented to perform magnetic resonance measurements in a beam of doped helium nanodroplets. This type of experiment faces the same difficulties as traditional molecular beam electric/magnetic resonance experiments, namely, an optically thin sample. Like many of these traditional experiments, it uses lasers to prepare the states of interest and to detect them after manipulation with a microwave field. Unlike these traditional experiments, Zeeman substates cannot be resolved by the laser transition because of the droplet-induced line broadening. A magnetic dichroism scheme is used instead, exploiting the favorable selection rules for the absorption of circularly polarized light. ESR spectra are shown for K atoms captured on the surface of He nanodroplets. The extension of the method to other atoms and molecules, and to NMR spectroscopy, is discussed.
RESUMEN
Chirped-Pulse millimetre-Wave (CPmmW) rotational spectroscopy provides a new class of information about photolysis transition state(s). Measured intensities in rotational spectra determine species-isomer-vibrational populations, provided that the rotational populations can be thermalized. The formation and detection of S(0) vinylidene is discussed in the limits of low and high initial rotational excitation. CPmmW spectra of 193 nm photolysis of vinyl cyanide (acrylonitrile) contain J = 0-1 transitions in more than 20 vibrational levels of HCN and HNC, but no transitions in vinylidene or highly excited local-bender vibrational levels of acetylene. Reasons for the non-observation of the vinylidene co-product of HCN are discussed.
RESUMEN
We report here the measurements of rovibrational levels in the electronic ground state of water molecule at the previously inaccessible energies above 26,000 cm(-1). The use of laser double-resonance overtone excitation extends this limit to 34,200 cm(-1), which corresponds to 83% of the water dissociation energy. We use experimental data to generate a semiempirical potential energy surface that now allows prediction of water levels with sub-cm(-1) accuracy at any energy up to the new limit.
Asunto(s)
Química Física/métodos , Agua/química , Algoritmos , Electrónica , Modelos Estadísticos , Modelos Teóricos , Fotones , Reproducibilidad de los Resultados , TermodinámicaRESUMEN
We report here a measurement of electric dipole moments in highly vibrationally excited HDO molecules. We use photofragment yield detected quantum beat spectroscopy to determine electric field induced splittings of the J=1 rotational levels of HDO excited with 4, 5, and 8 quanta of vibration in the OH stretching mode. The splittings allow us to deduce mua and mub, the projections of dipole moment onto the molecular rotation inertial axes. We compare the measured HDO dipole moment components with the results of quantitative calculations based on Morse oscillator wave functions and an ab initio dipole moment surface. The vibrational dependence of the dipole moment components reflect both structural and electronic changes in HDO upon vibrational excitation; principally the vibrational dependence of the O-H bond length and bond angle, and the resulting change in orientation of the principal inertial coordinate system. The dipole moment data also provide a sensitive test of theoretical dipole moment and potential energy surfaces, particularly for molecular configurations far from equilibrium.
RESUMEN
The intensity of water absorption in the region of the solar spectrum plays a dominant role in atmospheric energy balance and hence strongly influences climate. Significant controversy exists over how to model this absorption accurately. We report dipole moment measurements of highly vibrationally excited water, which provide stringent tests of intensities determined by other means. Our measurements and accompanying calculations suggest that the best currently available potential and dipole surfaces do not accurately model intensities in the optical spectrum of water.