Supramolecular complexation of C60 with branched polyethylene.

Fullerene C60 is a ubiquitous material for application in organic electronics and nanotechnology, due to its desirable optoelectronic properties including good molecular orbital alignment with electron-rich donor materials, as well as high and isotropic charge carrier mobility. However, C60 possesses two limitations that hinder its integration into large-scale devices: (1) poor solubility in common organic solvents leading to expensive device processing, and (2) poor optical absorbance in the visible portion of the spectrum. Covalent functionalization has long been the standard for introducing structural tunability into molecular design, but non-covalent interactions have emerged as an alternative strategy to tailor C60-based materials, offering a versatile and tuneable alternative to novel functional materials and applications. In this work, we report a straightforward non-covalent functionalization of C60 with a branched polyethylene (BPE), which occurs spontaneously in dilute chloroform solution under ambient conditions. A detailed characterization strategy, based on UV-vis spectroscopy and size-exclusion chromatography was performed to verify and investigate the structure of the C60+BPE complex. Among others, our work reveals that the supramolecular complex has an order of magnitude higher molecular weight than its C60 and BPE constituents and points towards oxidation as the driving force behind complexation. The C60+BPE complex also possesses significantly broadened optical absorbance compared to unfunctionalized C60, extending further into the visible portion of the spectrum. This non-covalent approach presents an inexpensive route to address the shortcomings of C60 for electronic applications, situating the C60+BPE complex as a promising candidate for further investigation in organic electronic devices.

Trends in Conjugated Chalcogenophenes: A Theoretical Study.

Heavy atom substitution in chalcogenophenes is a versatile strategy for tailoring and ultimately improving conjugated polymer properties. While thiophene monomers are commonly implemented in polymer designs, relatively little is known regarding the molecular properties of the heavier chalcogenophenes. Herein, we use density functional theory (DFT) calculations to examine how group 16 heteroatoms, including the radioactive polonium, affect polychalcogenophene properties including bond length, chain twisting, aromaticity, and optical properties. Heavier chalcogenophenes are more quinoidal in character and consequently have reduced band gaps and larger degrees of planarity. We consider both the neutral and radical cationic species. Upon p-type doping, bond length rearrangement is indicative of a more delocalized electronic structure, which combined with optical calculations is consistent with the polaron-model of charge storage on conjugated polymer chains. A better understanding of the properties of these materials at their molecular levels will inevitably be useful in material design as the polymer community continues to explore more main group containing polymers to tackle issues in electronic devices.

Isolation of Living Conjugated Polymer Chains.

Living polymerizations currently play a central role in polymer chemistry. However, one feature of these polymerizations is often overlooked, namely, the isolation of living polymer chains. Herein we report the isolation of living π-conjugated polymer chains, synthesized by catalyst-transfer polycondensation. Successful preservation of the nickel complex at polymer chain ends is evidenced by nuclear magnetic resonance spectroscopy, end group analysis, and chain extension experiments. When characterizing living chains by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry, we discovered a unique photoionization-photodissociation fragmentation process for polymers containing a nickel phosphine end group. Living chains are isolated for several types of conjugated polymers as well as discrete living oligomers. Additionally, we are able to recycle the catalysts from the isolated polymer chains. Catalyst recycling after π-conjugated polymerization has previously been impossible without chain isolation. This strategy not only exhibits general applicability to different monomers but also has far-reaching potential for other catalytic systems.

Evidence for the chain-growth synthesis of statistical π-conjugated donor-acceptor copolymers.

The synthesis of a series of dithienosilole-benzotriazole donor-acceptor statistical copolymers with various donor-acceptor ratios is reported, prepared by Kumada catalyst-transfer polymerization. Statistical copolymer structure is verified by (1) H NMR and optical absorption spectroscopy, and supported by density functional theory (DFT) calculations. The copolymers exhibit a single optical absorption band that lies between dithienosilole and benzotriazole homopolymers, which shifts with varying donor-acceptor content. A chain extension experiment using a partially consumed benzotriazole solution as a macroinitiator followed by addition of dithienosilole leads to the synthesis of a statistical dithienosilole-benzotriazole block copolymer from a pure benzotriazole block, demonstrating that both chain extension and simultaneous monomer incorporation are possible using this methodology.

Polyacetylene Revisited: A Computational Study of the Molecular Engineering of N-type Polyacetylene.

The development of stable and highly conductive polymers, particularly n-type materials, remains an outstanding challenge in organic electronics. N-doped polyacetylene has long been studied as a highly conductive organic n-type material but suffers from extremely poor stability. Herein, we use DFT to model a series of n-doped polyacetylene derivatives, which have been functionalized with a range of electron-withdrawing substituents, with the goal of identifying attractive candidates for synthesis. We analyze the predicted molecular orbital energies, polymer planarity, and delocalization of charge carriers along the polymer backbone. In so doing, we develop key insights about the ideal substituents for both stable and highly conductive polyacetylene derivatives. This work will inform the modern synthesis and development of new polyacetylene derivatives. Beyond this, the work identifies a variety of new materials that have not yet been synthesized and should be good candidates for emerging optoelectronic applications including soft thermoelectrics, bioelectronics, and flexible device technologies.

The role of halogens in the catalyst transfer polycondensation for π-conjugated polymers.

Catalyst transfer polycondensation is the only method to prepare π-conjugated polymers in a chain-growth manner, yet several aspects that underlie this polymerization are not fully understood. Here, we investigate the nickel-catalyzed polymerization mechanisms of a series of thiophene monomers bearing different halogen functionalities (Cl, Br, I). We have discovered the significant role that halogens and magnesium salts play in this polymerization. More specifically, the catalyst resting state changes depending on the type of halogenated monomer. For chlorinated monomers a mixture of Ni(ii)-dithienyl and dissociated Ni(phosphine) complexes are the resting states, which results in uncontrolled polymerization. For brominated monomers, a Ni(ii)-dithienyl complex is the resting state, which leads to controlled polymerization. For iodinated monomers, a Ni(ii)-thienyl iodide complex is the resting state, and notable inhibition by magnesium salt by-products is observed. The catalyst resting state changes to a Ni(ii)-dithienyl complex when a turbo Grignard reagent (i-PrMgCl·LiCl) is used. These findings are used to guide the design of a new monomer, 2-bromo-3-(2-ethylhexyl)-5-iodotellurophene, which enables the first controlled polymerization of a tellurophene monomer containing a sterically encumbered 2-ethylhexyl side chain. These insights are crucial for deepening the mechanistic understanding of Kumada cross coupling reactions and the controlled synthesis of π-conjugated polymers.

Controlled Synthesis of Fully π-Conjugated Donor-Acceptor Block Copolymers Using a Ni(II) Diimine Catalyst.

We use a Ni(II) diimine catalyst to prepare the first examples of the controlled synthesis of electron-rich/electron-deficient all-conjugated diblock copolymers. These catalysts are able to control polymerizations of both electron-rich and electron-deficient monomers, which we attribute to strong association to both monomer types. Block copolymers are prepared by controlled chain extension, and their structure is verified by gel permeation chromatography, 1H NMR, electrochemistry, calorimetry, and atomic force microscopy.