Phase Engineered Composite Phase Change Materials for Thermal Energy Manipulation.

Phase change materials (PCMs) present a dual thermal management functionality through intrinsic thermal energy storage (TES) capabilities while maintaining a constant temperature. However, the practical application of PCMs encounters challenges, primarily stemming from their low thermal conductivity and shape-stability issues. Despite significant progress in the development of solid-solid PCMs, which offer superior shape-stability compared to their solid-liquid counterparts, they compromise TES capacity. Herein, a universal phase engineering strategy is introduced to address these challenges. The approach involves compositing solid-liquid PCM with a particulate-based conductive matrix followed by surface reaction to form a solid-solid PCM shell, resulting in a core-shell composite with enhanced thermal conductivity, high thermal storage capacity, and optimal shape-stability. The core-shell structure designed in this manner not only encapsulates the energy-rich solid-liquid PCM core but also significantly enhances TES capacity by up to 52% compared to solid-solid PCM counterparts. The phase-engineered high-performance PCMs exhibit excellent thermal management capabilities by reducing battery cell temperature by 15 °C and demonstrating durable solar-thermal-electric power generation under cloudy or no sunshine conditions. This proposed strategy holds promise for extending to other functional PCMs, offering a compelling avenue for the development of high-performance PCMs for thermal energy applications.

MXene-Integrated Solid-Solid Phase Change Composites for Accelerating Solar-Thermal Energy Storage and Electric Conversion.

The high thermal storage density of phase change materials (PCMs) has attracted considerable attention in solar energy applications. However, the practicality of PCMs is often limited by the problems of leakage, poor solar-thermal conversion capability, and low thermal conductivity, resulting in low-efficiency solar energy storage. In this work, a new system of MXene-integrated solid-solid PCMs is presented as a promising solution for a solar-thermal energy storage and electric conversion system with high efficiency and energy density. The composite system's performance is enhanced by the intrinsic photo-thermal behavior of MXene and the heterogeneous phase transformation properties of PCM molecular chains. The optimal composites system has an impressive solar thermal energy storage efficiency of up to 94.5%, with an improved energy storage capacity of 149.5 J g-1 , even at a low MXene doping level of 5 wt.%. Additionally, the composite structure shows improved thermal conductivity and high thermal cycling stability. Furthermore, a proof-of-concept solar-thermal-electric conversion device is designed based on the optimized M-SSPCMs and commercial thermoelectric generators, which exhibit excellent energy conversion efficiency. The results of this study highlight the potential of the developed PCM composites in high-efficiency solar energy utilization for advanced photo-thermal systems.

High-Efficiency Thermal-Shock Resistance Enabled by Radiative Cooling and Latent Heat Storage.

Radiative cooling technology is well known for its subambient temperature cooling performance under sunlight radiation. However, the intrinsic maximum cooling power of radiative cooling limits the performance when the objects meet the thermal shock. Here, a dual-function strategy composed of radiative cooling and latent heat storage simultaneously enabling the efficient subambient cooling and high-efficiency thermal-shock resistance performance is proposed. The electrospinning and absorption-pressing methods are used to assemble the dual-function cooler. The high sunlight reflectivity and high mid-infrared emissivity of radiative film allow excellent subambient temperature of 5.1 °C. When subjected the thermal shock, the dual-function cooler demonstrates a pinning effect of huge temperature drop of 39 °C and stable low-temperature level by isothermal heat absorption compared with the traditional radiative cooler. The molten phase change materials provide the heat-time transfer effect by converting thermal-shock heat to the delayed preservation. This strategy paves a powerful way to protect the objects from thermal accumulation and high-temperature damage, expanding the applications of radiative cooling and latent heat storage technologies.

Emerging Solid-to-Solid Phase-Change Materials for Thermal-Energy Harvesting, Storage, and Utilization.

Phase-change materials (PCMs) offer tremendous potential to store thermal energy during reversible phase transitions for state-of-the-art applications. The practicality of these materials is adversely restricted by volume expansion, phase segregation, and leakage problems associated with conventional solid-liquid PCMs. Solid-solid PCMs, as promising alternatives to solid-liquid PCMs, are gaining much attention toward practical thermal-energy storage (TES) owing to their inimitable advantages such as solid-state processing, negligible volume change during phase transition, no contamination, and long cyclic life. Herein, the aim is to provide a holistic analysis of solid-solid PCMs suitable for thermal-energy harvesting, storage, and utilization. The developing strategies of solid-solid PCMs are presented and then the structure-property relationship is discussed, followed by potential applications. Finally, an outlook discussion with momentous challenges and future directions is presented. Hopefully, this review will provide a guideline to the scientific community to develop high-performance solid-solid PCMs for advanced TES applications.

Phase-change materials reinforced intelligent paint for efficient daytime radiative cooling.

Passive cooling of buildings has become increasingly important for green and low-carbon development, especially in the near decade where daytime radiative cooling technology (DRCT) has drawn attention with big breakthroughs. However, irresistibly importing heat from sunlight and surroundings results in notable temperature rise, thus limiting the cooling effect. Here, we report a radiative paint with latent heat storage capacity to store imported heat by coupling randomly-distributed phase-change materials (PCMs) based microcapsules with acrylic resin to enhance cooling performance. The bifunctional paint shows good performance in selected-suitable phase transition temperature, high enthalpy, high reflectivity in the sunlight region and strong emissivity in the atmospheric window region. The temperature measurements demonstrate that the paint possesses enhanced cooling performance of temperature drop and time buffering effect compared with the pure radiative cooling paint. This work offers the potential to broaden the applications of PCMs and DRCT for energy saving and environment protection.