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1.
Front Chem ; 8: 105, 2020.
Artículo en Inglés | MEDLINE | ID: mdl-32154218

RESUMEN

As one of the most promising fast energy storage devices, supercapacitor has been attracting intense attention for many emerging applications. However, how to enhance the electrochemical performance of electrode materials is still the main issue among various researches. In this paper, hierarchical porous carbons derived from Eleocharis dulcis has been prepared by chemical activation process with the aid of KOH at elevated temperature. Results show that the N, P co-doped porous carbon exhibits excellent electrochemical performance, it owns a specific capacitance of 340.2 F/g at 1 A/g, and obtains outstanding cycling stability of 96.9% of capacitance retention at 10 A/g after 5,000 cycles in a three-electrode system. Moreover, in the two-electrode system, the product still maintains a high specific capacitance of 227.2 F/g at 1 A/g, and achieves good electrochemical cycle stability (94.2% of capacitance retention at 10 A/g after 10,000 cycles); besides, its power/energy density are 3694.084 and 26.289 Wh/kg, respectively. Therefore, the combination of facile synthesis strategy and excellent electrochemical performance makes Eleocharis dulcis-based porous carbon as a promising electrode material for supercapacitor.

2.
Glob Chall ; 4(11): 2000002, 2020 Nov.
Artículo en Inglés | MEDLINE | ID: mdl-33163224

RESUMEN

Transition metal orthovanadates are emerging 2D materials for promising electrochemical energy storage applications. Facile hydrothermal method for nanocrystalline indium vanadate (InVO4) semiconducting materials' fabrication is economical because of its direct chemical synthesis. X-ray diffraction studies, field emission scanning electron microscope (SEM) images, transmission electron microscopy (TEM), and photoelectron X-ray spectrum are used to describe the semiconductor materials as synthesized. InVO4 microspheres have attracted a lot of attention in the energy and environmental sector. These microsphere-derived semiconductor materials are recognized to offer the advantages of their large surface area, tunable pore sizes, enhanced light absorption, efficient carrier (electron-hole) separation, superior electronic and optical behavior, and high durability. From the results of SEM and TEM, InVO4 shows a microsphere construction with a mixture of nanosized particles. Diffuse reflectance UV-visible measurements are used to determine the bandgap, and it is found to be 2.1 eV for InVO4. The electrochemical analysis reveals a superior performance of the pseudocapacitor with hydrothermally derived microspheres of InVO4. Alongside an improved pseudocapacity, developed after 4000 cycles, it has excellent cycling stability with a retention of ≈94% of its original specific capacitance efficiency.

3.
Nephrourol Mon ; 5(3): 843-6, 2013 Jul 01.
Artículo en Inglés | MEDLINE | ID: mdl-24282798

RESUMEN

Malignant peripheral nerve-sheath tumor (MPNST) is a high-grade malignant tumor of ecto-mesenchymal origin comprising approximately 10% of soft-tissue sarcomas. They tend to occur associated with neurofibromatosis or sporadically. Here we report a MPNST at an extremely rare location and behavior causing disappearance of the entire kidney. Patient evaluation included clinical, biochemical and radiological studies before treatment. Histological study revealed the rare diagnosis. Patient was asymptomatic at six-month follow-up after treatment.

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