Comprehensive Evaluation of Polyaniline-Doped Lignosulfonate in Adsorbing Dye and Heavy Metal Ions.

Lignosulfonate/polyaniline (LS/PANI) nanocomposite adsorbent materials were prepared by the chemical polymerization of lignosulfonate with an aniline monomer as a dopant and structure-directing agent, and the adsorption behavior of dyes as well as heavy metal ions was investigated. LS/PANI composites were used as dye adsorbents for the removal of different cationic dyes (malachite green, methylene blue, and crystal violet). The adsorption behavior of LS/PANI composites as dye adsorbents for malachite green was investigated by examining the effects of the adsorbent dosage, solution pH, initial concentration of dye, adsorption time, and temperature on the adsorption properties of this dye. The following conclusions were obtained. The optimum adsorption conditions for the removal of malachite green dye when LS/PANI composites were used as malachite green dye adsorbents were as follows: an adsorbent dosage of 20 mg, an initial concentration of the dye of 250 mg/L, an adsorption time of 300 min, and a temperature of 358 K. The LS/PANI composite adsorbed malachite green dye in accordance with the Langmuir adsorption model and pseudo-second-order kinetic model, which belongs to chemisorption-based monomolecular adsorption, and the equilibrium adsorption amount was 245.75 mg/g. In particular, the adsorption of heavy metal ion Pb2+ was investigated, and the removal performance was also favorable for Pb2+.

Recent advances in lignin antioxidant: Antioxidant mechanism, evaluation methods, influence factors and various applications.

Lignin, a by-product of processing lignocellulosic materials, has a polyphenolic structure and can be used as an antioxidant directly or synergistically with synthetic types of antioxidants, leading to different applications. Its antioxidant mechanism is mainly related to the production of ROS, but the details need to be further investigated. The antioxidant property of lignin is mainly related to the content of phenolic hydroxyl group, but methoxy, purity will also have an effect on it. In addition, different methods to detect the antioxidant properties of lignin have different advantages and disadvantages. In this paper, the antioxidant mechanism of lignin, the methods to determine the antioxidant activity and the progress of its application in various fields are reviewed. In addition, the current research on the antioxidant properties of lignin and the hot directions are provided, and an outlook on the research into the antioxidant properties of lignin is provided to broaden its potential application areas.

Antibacterial mechanism of lignin and lignin-based antimicrobial materials in different fields.

The control of microbial infection transmission often relies on the utilization of synthetic and metal-based antimicrobial agents. However, their non-biodegradability and inadequate disposal practices lead to significant environmental contamination. To address this concern, the quest for natural alternatives has gained paramount importance. Lignin, a widely available renewable aromatic compound, emerges as a promising candidate owing to its inherent phenolic moiety, which lends itself well to acting as a natural antimicrobial agent either independently or in combination with other agents. This article provides a comprehensive account of the structure and primary classes of lignin. Additionally, it elucidates the antimicrobial mechanism of lignin, the factors influencing its efficacy, and the methods employed for its detection. Moreover, it describes the progress made in developing the antimicrobial capacity of lignin in different areas. In conclusion, this paper not only outlines the current state of research on the antimicrobial function of lignin, but also identifies challenges and future possibilities for enhancing its antimicrobial properties. This work holds great significance in the ongoing endeavor to contribute to high-impact research on natural alternatives for controlling infections and fostering environmentally conscious practices.

Preparation and Adsorption Properties of Lignin/Cellulose Hydrogel.

With the development of global industry, industrial wastewater pollution has caused serious environmental problems, and the demand for green and sustainable adsorbents is increasingly strong in the society. In this article, lignin/cellulose hydrogel materials were prepared using sodium lignosulfonate and cellulose as raw materials and 0.1% acetic acid solution as a solvent. The results showed that the optimal adsorption conditions for Congo red were as follows: an adsorption time of 4 h, a pH value of 6, and an adsorption temperature of 45 °C. The adsorption process was in line with the Langmuir isothermal model and a quasi-second-order kinetic model, which belonged to single molecular layer adsorption, and the maximum adsorption capacity was 294.0 mg/g. The optimal adsorption conditions for Malachite green were as follows: an adsorption time of 4 h, a pH value of 4, and an adsorption temperature of 60 °C. The adsorption process was consistent with the Freundlich isothermal model and a pseudo-second-order kinetic model, which belonged to the chemisorption-dominated multimolecular layer adsorption with the maximum adsorption capacity of 129.8 mg/g.

[The performance and applications of lignin based hydrogels: a review].

Lignin is the only natural aromatic polymer and the second most abundant lignocellulosic resource in nature after cellulose, and its derived high-value products can be used in a variety of fields. An efficient, highly value-added and high-quality production of lignin is critical for lignocellulose biorefinery, but the complex and variable structure of lignin macromolecules, poor activity of reactions, and redundant functional groups make it difficult to prepare polymeric materials with stable properties. With the increasing research on lignin modification, the application of lignin composite hydrogels has also received great attention. In this paper, the preparation of lignin composite hydrogels based on the basic structural composition and reaction properties of lignin was briefly outlined. The current applications of lignin composite hydrogels, including biosensors, controlled release materials, environmentally responsive materials, adsorbent materials, electrode materials, and other materials, were summarized. Moreover, future perspectives of lignin-based composite hydrogels were prospected.

Review on the preparation of fuels and chemicals based on lignin.

Lignin is by far the most abundant natural renewable aromatic polymer in nature, and its reserves are second only to cellulose. In addition to the rich carbon content, the structure of lignin contains functional groups such as benzene rings, methoxyl groups, and phenolic hydroxyl groups. Lignin degradation has become one of the high value, high quality and high efficiency methods to convert lignin, which is of great significance to alleviating the current energy shortage and environmental crisis. This article introduces the hydrolysis methods of lignin in acidic, alkaline, ionic liquids and supercritical fluids, reviews the heating rate, the source of lignin species and the effects of heating rate on the pyrolysis of lignin, and briefly describes the metal catalysis, oxidation methods such as electrochemical degradation and photocatalytic oxidation, and degradation reduction methods using hydrogen and hydrogen supply reagents. The lignin degradation methods for the preparation of fuels and chemicals are systematically summarized. The advantages and disadvantages of different methods, the selectivity under different conditions and the degradation efficiency of different catalytic combination systems are compared. In this paper, a new approach to improve the degradation efficiency is envisioned in order to contribute to the efficient utilization and high value conversion of lignin.

Comparison of the Degradation Performance of Seven Different Choline Chloride-Based DES Systems on Alkaline Lignin.

Lignin is a natural polymer second only to cellulose in natural reserves, whose structure is an aromatic macromolecule composed of benzene propane monomers connected by chemical bonds such as carbon-carbon bonds and ether bonds. Degradation is one of the ways to achieve the high-value conversion of lignin, among which the heating degradation of lignin by deep eutectic solvent (DES) can be an excellent green degradation method. In this study, choline chloride (CC) was used as the hydrogen bond acceptor, and urea (UR), ethylene glycol (GC), glycerol (GE), acetic acid (AA), formic and acetic mixed acid (MA), oxalic acid (OX), and p-toluenesulfonic acid (TA) were used as hydrogen bond donors to degrade lignin. NMR hydrogen spectroscopy was used for the simple and rapid determination of phenolic hydroxyl groups in lignin. FT-IR spectroscopy was used to characterize the changes of functional groups of lignin during DES treatment. GPC observed the molecular weight of lignin after degradation and found a significant increase in the homogeneity (1.6-2.0) and a significant decrease in the molecular weight Mw (2478-4330) of the regenerated lignin. It was found that acidic DES was more effective in depolymerizing alkaline lignin, especially for the toluene-choline chloride. Seven DES solutions were recovered, and it was found that the recovery of DES still reached more than 80% at the first recovery.