1.
Chem Commun (Camb)
; 60(15): 2094-2097, 2024 Feb 15.
Artículo
en Inglés
| MEDLINE
| ID: mdl-38294205
RESUMEN
Dynamic M/P invertible helicity was successfully induced at a SiO2 surface immobilized with a dynamic helical trinuclear cobalt complex, [LCo3(NHMe2)6](OTf)3, using chiral ((R) or (S))-1-phenylethylamine. Solid-state CD spectra and theoretical calculations suggested that the fixation of the M/P helical complex on the surface via coordination interactions was the key factor of the induced chirality at the surface.