Rare earth elements (REE) in the urban wastewater of Cotonou (Benin, West Africa).

The rare earth element (REE) contamination of urban wastewater, which was collected from open sewers and the inlet of a wastewater treatment plant in Cotonou (Benin), was assessed. The drinking water distributed to the inhabitants of Cotonou and water samples from private wells were also analyzed. The sampling occurred between October and December 2016 and the samples were analyzed by ICP-MS. Although the only magnetic resonance imaging facility in Cotonou opened in November 2016, pollution by anthropogenic gadolinium (Gd), which is included in phase contrast agents, was observed: there was 30-620 times more Gd in wastewater samples than in drinking and well water samples. Europium was another REE presenting positive anomalies. It is hypothetized than the europium came from the leachates of solid waste piles in the street. In the absence of any wastewater treatment, the REEs found in the wastewater are spread to the aquatic environment. It would be interesting to monitor the wastewater REEs over the long term. So far, the aquifers used for water provision have not been polluted by the anthropogenic REEs.

Population mobility and urban wastewater dynamics.

Dynamic influent models, which have been proposed to test control strategies using virtual wastewater treatment plants, should be as realistic as possible. The number of inhabitants in the catchment at any given time and their ways of life are among the parameters affecting the quality of these models. Census data related to work and school commutes were used to evaluate the number of people present in a given urban area. Based on the example of a large urban catchment (Grand Nancy, France), the results show that a population increase of 30% could occur during working hours resulting from the imbalance between workers leaving and coming into the catchment. Combined with information related to the local way of life, variation in the population helps to explain changes in wastewater flow rate and pollution (carbon, nitrogen, phosphorus and heavy metals), which present several maxima reflecting daily activities, such as bladder voiding, meals, the use of washrooms, etc. However, no well-defined variation patterns for pH and conductivity, which are linked to the concentrations of anions and cations in the wastewater, were observed. Slight reductions (up to 10% on Sundays) in the flow and pollution load were observed on weekends as the commuter flow decreased. Census data proved to be efficient in helping to understand the daily pattern of urban wastewater characteristics.