Fabrication of a MXene-based shape-memory hydrogel and its application in the wound repair of skin.

Wound dressings can generally complete hemostasis and provide temporary protection after skin damage. Herein, a MXene-based hydrogel was prepared from MXene, gelatin, poly(ethylene glycol)diacrylate (PEGDA) and N,N'-methylenebis(acrylamide) (HEAA) to prepare wound-dressing hydrogels for skin repair. HEAA and PEGDA crosslink polymerization formed the first layer of the network. Hydrogen bonds between MXene, PHEAA, and gelatin formed the second layer of the network. To make the hydrogel more suitable for skin repair, the mechanical properties of the hybrid hydrogel were adjusted. The MXene-based hydrogel could recover its original shape in 16 s upon immersion in water or for a few minutes under light irradiation. The obtained hydrogel showed good photothermal properties upon light irradiation (808 nm, 1 W cm-2) for 20 s, and its temperature on the surface could reach 86.4 °C. Due to its good photothermal properties, this MXene-based hydrogel was suitable for skin repair.

Recent Advances in the Synthesis of MXene Quantum Dots.

Quantum dots (QDs) with ultrahigh surface-to-volume ratio, abundant edge active sites, forceful quantum confinement and other remarkable physio-chemical properties, have garnered considerable research interest. MXene QDs, as an emerging member of them, have also attracted wide attention in the last six years, and shown great achievements in many fields. This critical review systematically summarizes the various methods for synthesizing MXene QDs. The characteristics and corresponding applications of various MXene QDs are also presented. The advantages and disadvantages of various synthetic methods, and the limitations of corresponding MXene QDs are compared and highlighted. Finally, the challenges and perspectives of synthesizing MXene QDs are proposed. We hope this review will enlighten researchers to the fabrication of more advancing and promising MXene-based QDs with proprietary properties in diverse applications.

Structurally colored aramid fabric construction and its application as a recyclable photonic catalyst.

Structural colors can be used in fabric coloring due to their bright color and non-fading properties. However, it is still a challenge to construct structural color on high crystallinity, smooth surfaced and yellow colored aramid fabrics. Herein, for the first time, photonic crystals (PCs) with structural color were constructed on aramid fabrics by introducing dopamine to modify aramid fabrics and synthesizing monodisperse high refractive index zinc sulfide nanoparticles (ZnS). The influence of the PC coatings on the structural color, mechanical properties, and thermal stability of the structurally colored aramid fabrics or fibers was further investigated. Moreover, due to the excellent catalytic properties of ZnS and the slow photon effects of PCs, the structurally colored fabrics showed good photocatalytic properties, which will be beneficial in reusing the catalysts, which is crucial to their application in the coloring of fabrics but also facilitates the recycling of waste PC coated aramid fabrics.

Protocol for the Chinese Real-World Evidence for Acute Spinal Cord Injury (ChiRES) study: a prospective, observational, multicentre cohort study of acute spinal cord injury.

INTRODUCTION: Spinal cord injury (SCI) is a catastrophic event with devastating physical, social and occupational consequences for patients and their families. The number of patients with acute SCI in China continues to grow rapidly, but there have been no large prospective cohort studies of patients with acute SCI. This proposed study aims to establish a multicentre, extensive sample cohort of clinical data and biological samples of patients in China, which would aid the systematisation and standardisation of clinical research and treatment of acute SCI, thus reducing the heavy burden of acute SCI on patients and society. METHODS AND ANALYSIS: The Chinese Real-World Evidence for Acute Spinal Cord Injury (ChiRES) study is an observational, multicentre cohort study of patients with acute SCI admitted to the Qilu Hospital of Shandong University and other participating centres with prospective collection of their clinical data and biological samples. We aim to recruit 2097 patients in this study. Demographics, disease history, emergency intervention information, motor and sensory examinations, surgical information, medication information and rehabilitation evaluation will be recorded. This will facilitate the development of a prediction model for complications and prognosis of patients with acute SCI and an evaluation of the current management of acute SCI. Among these variables, detailed information on surgical treatment will also be used to assess procedures for acute SCI treatment. Outcome measurements, including the International Standard for Neurological Classification of Spinal Cord Injury examinations, the occurrence of complications and death, will be performed repeatedly during follow-up. We will analyse imaging data and blood samples to develop SCI imaging markers and biomarkers. ETHICS AND DISSEMINATION: This study protocol has been approved by the Medical Ethics Committee of the Qilu Hospital of Shandong University and all other participating centres. The findings will be disseminated in peer-reviewed journals and academic conferences.

Construction of Wash-Resistant Photonic Crystal-Coated Fabrics based on Hydrogen Bonds and a Dynamically Cross-Linking Double-Network Structure.

Structural coloration as the most possible way to realize the ecofriendly dying process for textiles or fabrics has attracted significant attention in the past decades. However, photonic crystals (PCs) are a typical example of materials with structural color usually located on the surface of the fabrics or textiles, which make them not stable when rubbed, bent, or washed due to the weak interaction between the PC coatings and fabrics. Here, double networks were constructed between the PC coatings and the fabrics for the first time via a hydrogen bond by introducing tannic acid (TA) and dynamic cross-linking with 2-formylphenylboronic acid to increase the wash resistance of the structural colored fabrics. On modifying the monodispersed SiO2 nanoparticles, poly(dimethylsiloxane), and the fabrics, the interaction between the PC coatings and the fabrics increased by the formation of double networks. The structural color, wash, and rub resistance of the PC-coated fabrics were systematically studied. The obtained fabrics with the TA content at 0.030% (SiDT30) showed the best wash and rub resistance. The construction of double networks not only improved the wash and rub resistance of PCs but also retained the bright structural color of the PC coatings, facilitating the practical application of structural coloration in the textile industry.

Pressure Drop Performance of Porous Composites Based on Cotton Cellulose Nanofiber and Aramid Nanofiber for Cigarette Filter Rod.

Porous composites have been widely used in the adsorption and catalysis field due to their special structure, abundant sites, and light weight. In this work, an environmentally friendly porous composite was successfully prepared via a facile freeze-drying method, in which cotton cellulose nanofiber (CCNF) was adopted as the main framework to construct the connected flue structure, and aramid nanofiber (ANF) was used as a reinforcer to enhance its thermal property. As-prepared porous materials retained a regulated inter-connected hole structure and controllable porosity after ice template evolution and possessed improved resistance to thermal collapse with the introduction of a small amount of aramid nanofiber, as evaluated and verified by FTIR, SEM, and TGA measurements. With the increased addition of cotton cellulose nanofiber and aramid nanofiber, the porous composites exhibited decreased porosity and increased pressure drop performance. For the CCNF/ANF-5 sample, the pressure drop was 1867 Pa with a porosity of 7.46 cm3/g, which best met the required pressure drop value of 1870 Pa. As-prepared porous composite with adjustable interior structure and enhanced thermal property could be a promising candidate in the tobacco field.

Traumatic spinal injury-related hospitalizations in the United States, 2016-2019: a retrospective study.

BACKGROUND: Traumatic spinal injury (TSI) is associated with significant fatality and social burden; however, the epidemiology and treatment of patients with TSI in the US remain unclear. MATERIALS AND METHODS: An adult population was selected from the National Inpatient Sample database from 2016 to 2019. TSI incidence was calculated and TSI-related hospitalizations were divided into operative and nonoperative groups according to the treatments received. TSIs were classified as fracture, dislocation, internal organ injury, nerve root injury, or sprain injuries based on their nature. The annual percentage change (APC) was calculated to identify trends. In-hospital deaths were utilized to evaluate the prognosis of different TSIs. RESULTS: Overall, 95 047 adult patients were hospitalized with TSI in the US from 2016 to 2019, with an incidence rate of 48.4 per 100 000 persons in 2019 (95% CI: 46.2-50.6). The total incidence increased with an APC of 1.5% (95% CI: 0.1-3%) from 2016 to 2019. Operative TSI treatment was more common than nonoperative (32.8 vs. 3.8; 95% CI: 32.3-33.2 vs. 3.6-4%). The number of operations increased from 37 555 (95% CI: 34 674-40 436) to 40 460 (95% CI: 37 372-43 548); however, the operative rate only increased for internal organ injury (i.e. spinal cord injury [SCI])-related hospitalizations (APC, 3.6%; 95% CI: 2.8-4.4%). In-hospital mortality was highest among SCI-related hospitalizations, recorded at 3.9% (95% CI: 2.9-5%) and 28% (95% CI: 17.9-38.2%) in the operative and nonoperative groups, respectively. CONCLUSIONS: The estimated incidence of TSI in US adults increased from 2016 to 2019. The number of operations increased; however, the proportion of operations performed on TSI-related hospitalizations did not significantly change. In 2019, SCI was the highest associated mortality TSI, regardless of operative or nonoperative treatment.

Iron partially occupying sulfur vacancies in WS2 boosts electrochemical nitrogen fixation at low potentials.

Metallic Fe nanoparticles partially occupy the sulfur vacancies at edge sites of WS2 leading to 4-fold higher NRR performance due to the boosted p-d hybridization between Fe and N atoms.

Ionic-exchange immobilization of ultra-low loading palladium on a rGO electro-catalyst for high activity formic acid oxidation.

A formic acid oxidation electro-catalyst with ultra-low palladium (Pd) loading was prepared via an ionic exchange method by utilizing the acidic functional groups on graphene oxide (GO). After simultaneous reduction of exchanged Pd2+ and residual functional groups on the GO surface, an ionic exchange reduced Pd catalyst supported on reduced GO (IE-Pd/rGO) was obtained. Three times improved formic acid oxidation mass activity compared with that of the conventional synthesized Pd/C catalyst was exhibited for the IE-Pd/rGO catalyst. More importantly, formic acid oxidation stability on the IE-Pd/rGO catalyst was remarkably improved due to synergistic effect of the strong immobilization of Pd nanoparticles and the effect of in situ doped N on the rGO support.