Reconstruction Filters Improving the Spatial Resolution and Signal-to-Noise Ratio of Surface Plasmon Resonance Microscopy.

Benefitting from high sensitivity, real-time, and label-free imaging, surface plasmon resonance microscopy (SPRM) has become a powerful tool for dynamic detection of nanoparticles. However, the evanescent propagation of surface plasmon polaritons (SPPs) induces interference between scattered and launched SPPs, which deteriorates the spatial resolution and signal-to-noise ratio (SNR). Due to the simplicity and fast processing, image reconstruction based on deconvolution has shown the feasibility of improving the spatial resolution of SPRM imaging. Retrieving the particle scattering from SPRM interference imaging by filters is crucial for reconstruction. In this work, we illustrate the effect of filters extracting SPP scattering of nanoparticles with different sizes and shapes for reconstruction. The results indicate that the optimum filters are determined by the material of nanoparticles instead of particle sizes. The reconstruction of single Au and PS nanospheres as well as Ag nanowires with optimum filters is achieved. The reconstructed spatial resolution is improved to 254 nm, and the SNR is increased by 8.1 times. Our research improves the quality of SPRM imaging and provides a reliable method for fast detection of particles with diverse sizes and shapes.

Directional surface plasmon polariton scattering using single magnetic nanoparticles.

Directional surface plasmon polaritons (SPPs) are expected to promote the energy efficiency of plasmonic devices, via limiting the energy in a given spatial domain. The directional scattering of dielectric nanoparticles induced by the interference between electric and magnetic responses presents a potential candidate for directional SPPs. Magnetic nanoparticles can introduce permeability as an extra manipulation, whose directional scattered SPPs have not been investigated yet. In this work, we demonstrated the directional scattered SPPs by using single magnetic nanoparticles via simulation and experiment. By increasing the permeability and particle size, the high-order TEM modes are excited inside the particle and induce more forward directional SPPs. It indicated that the particle size manifests larger tuning range compared with the permeability. Experimentally, the maximum forward-to-backward (F-to-B) SPP scattering intensity ratio of 118.52:1 is visualized by using a single 1 µm Fe3O4 magnetic nanoparticle. The directional scattered SPPs of magnetic nanoparticles are hopeful to improve the efficiency of plasmonic devices and pave the way for plasmonic circuits on-chip.

Effects of nanoparticle sizes, shapes, and permittivity on plasmonic imaging.

Plasmonic imaging has exhibited superiority in label-free and fast detection to single nanoparticles due to its high sensitivity and high temporal resolution, which plays an important role in environmental monitoring and biomedical research. As containing plenty of information associated with particle features, plasmonic imaging has been used for identifying the particle sizes, shapes, and permittivity. Yet, the effects of the nanoparticle features on plasmonic imaging are not investigated, which hinders the in-depth understanding to plasmonic imaging and its applications in particle identification. In this work, we analyzed five types of nanoparticles, including polystyrene (PS), Au, silicon nanospheres as well as PS and Ag nanowires. We illustrated the effects of nanoparticle sizes, shapes, and permittivity on spatial resolution, imaging contrast, and interference fringes. We found that nanoparticle sizes and permittivity influenced the imaging contrast. Via introducing size parameter relevant to interference fringes, the connection between particle shape and reduction rate of size parameter is built, and the effects of particle shapes on the interference patterns are revealed. Our research provides a basis for improving the plasmonic imaging and presents guidance for applications on particle identification in nano-detection, biosensor, and environmental monitoring.

Locally excited surface plasmon resonance for refractive index sensing with high sensitivity and high resolution.

An angle-interrogated surface plasmon resonance (SPR) sensor based on a prism-coupled configuration has been extensively applied in biomedicine, environment monitoring, and food safety. Yet, the low sensitivity and low spatial resolution impede its further development. In this Letter, we investigated objective-coupled locally excited SPR for refractive index (RI) sensing with high sensitivity and high resolution. Through theoretical analysis, the SPR angle was retrieved from back focal plane imaging, which was highly correlated to the RI of the surrounding medium. Experimentally, a RI sensitivity of 77.41° refractive index unit (RIU)-1 was achieved with a detection range of 0.068 RIU when using glucose solutions for the demonstration. Furthermore, we acquired the spatial resolution of the configuration being 290 nm, and the RI measurement to a polydimethylsiloxane droplet with high spatial resolution was implemented. As a result, compared with the classical prism-coupled configuration, the locally excited SPR provides a method to achieve RI sensing with high sensitivity and high resolution.

Detecting the morphology of single graphene sheets by dual channel sampling plasmonic imaging.

Due to their excellent physical and chemical properties, graphene sheets are widely used in industry, which makes detection important to guarantee their performance. Atomic force microscopy, scanning electron microscopy, and Raman spectroscopy are the most common detection methods, which is either time-consuming or easily destructive. In this work, we presented a fast and nondestructive method to detect single graphene sheets by using plasmonic imaging. Dual channel sampling plasmonic imaging combining the image processing algorithm is used to improve the deterioration from propagation length of surface plasmon polaritons and reconstruct the complete morphology of single graphene sheets. The fast and nondestructive detection method paves the way to applications of graphene, and can be extended to the detections of two-dimensional materials, single biological molecule, viruses, and nanomaterials.

Detecting a single nanoparticle by imaging the localized enhancement and interference of surface plasmon polaritons: erratum.

In this erratum, the function ${\lambda _{{\rm SPP}}}$λSPP in the third page of Opt. Lett.44, 5707 (2019)OPLEDP0146-959210.1364/OL.44.005707 has been corrected.

Detecting a single nanoparticle by imaging the localized enhancement and interference of surface plasmon polaritons.

Label-free single-nanoparticle detection is crucial for the fast detection of nanoparticles and viruses in environmental monitoring and biological sciences. In this Letter, benefiting from the leakage radiation that transforms the near-field surface plasmon polariton (SPP) distribution along the interface to the far field, we demonstrated the plasmonic imaging of single polystyrene nanoparticles with a particle size down to 39 nm. The imaging is composed of the localized enhancement and interference of SPPs. The localized enhancement is the result of the accumulation of charges around the nanoparticle, and it is connected to the size and refractive index of nanoparticles. The interference is induced by the coupling between the incident SPPs and the scattered SPPs, verified by extracting the interference fringe periodicity to be half of the SPP wavelength. Our study provides an in-depth physical understanding of plasmonic imaging of single nanoparticles, which paves the way for a fast identification of nanomaterials.

Label-Free Imaging of Single Nanoparticles Using Total Internal Reflection-Based Leakage Radiation Microscopy.

Label-free, fast, and single nanoparticle detection is demanded for the in situ monitoring of nano-pollutants in the environment, which have potential toxic effects on human health. We present the label-free imaging of single nanoparticles by using total internal reflection (TIR)-based leakage radiation microscopy. We illustrate the imaging of both single polystyrene (PS) and Au nanospheres with diameters as low as 100 and 30 nm, respectively. As both far-field imaging and simulated near-field electric field intensity distribution at the interface showed the same characteristics, i.e., the localized enhancement and interference of TIR evanescent waves, we confirmed the leakage radiation, transforming the near-field distribution to far-field for fast imaging. The localized enhancement of single PS and Au nanospheres were compared. We also illustrate the TIR-based leakage radiation imaging of single polystyrene nanospheres with different incident polarizations. The TIR-based leakage radiation microscopy method is a competitive alternative for the fast, in situ, label-free imaging of nano-pollutants.