RESUMEN
In the present work, rock samples were collected from Paleolithic archaeological site of Attirampakkam, Tamil Nadu, India to assess the mineralogical composition using Fourier transform infrared-spectroscopic (FT-IR) technique and X-Ray Diffraction Spectrometry (XRD). The quartz, kaolinite, montmorillonite, calcite, orthoclase, microcline and illite minerals are identified in rock samples and crystallinity index of quartz (SiO2) is estimated for all the samples by comparing the ratio of intensity of the characteristic peak at 778 and 695 cm-1 using FT-IR spectrum. In rock samples, calculated crystallinity index of quartz is greater than the 1 from FT-IR spectrum and it shows that the distribution is disordered in nature. Additionally, some more minerals such as hematite and rutile are identified in rock samples by X-ray diffraction technique. This extensive study shows that archeological rock samples are wide variation in mineral composition.
RESUMEN
River sand samples have been collected from Ponnai river, Tamil Nadu, India for characterization of minerals and heavy metals by different spectroscopic techniques. Initially, the samples were subjected by Fourier Transform-Infra Red (FT-IR) spectroscopic technique and infra-red absorption bands values are observed in the range of 515-520, 695-700, 775-780 cm-1 which shows the presence of quartz in all the samples. Similarly, infra-red peaks were absorbed for feldspar, kaolinite, calcite, gibbsite and organic carbon and confirmed by X-Ray diffraction (XRD) technique. Additionally, zircon, aragonite, magnetite and kyanite minerals were identified in the samples using only the XRD method. The concentration of heavy metals such as Pb, Cr, Zn, Ni, Hg, As, Mn, Cu has been determined by flame atomic absorption spectrometry (FAAS). An average metal concentration measured in mg kg-1 were: Pb 0.12, As 0.15, Hg 0.13, Cu 2.80, Zn 10.15 Cr 12.70, Ni 2.86 and Mn 104.94 and hence found in the order of Mn > Cr > Zn > Ni > Cu > As > Hg > Pb. These average values do not exceed the world average value and hence potentially do not affect the quality of sand in the river. In addition to that, presences of heavy metals are confirmed by scanning electron microscope equipped with energy dispersive X-ray spectrometry (SEM/EDS) analysis. In order to understand the possible natural and anthropogenic sources of heavy metals, multivariate statistical techniques such as Pearson correlation, principal component and cluster analysis were performed. Results obtained from the statistical techniques were good agreement with each other.
RESUMEN
The major challenge in medical field is to diagnose disorder rather than a disease. In this paper, a neuro fuzzy based model is designed for identification or diagnosis of autism. The problematic areas are gathered from every individual and the related linguistic inputs are converted into fuzzy input values which are in turn given as input to feed forward multilayer neural network. The network is trained using back propagation training algorithm and tested for its performance with the expertise.
Asunto(s)
Algoritmos , Trastorno Autístico/diagnóstico , Lógica Difusa , Redes Neurales de la Computación , Inteligencia Artificial , Trastorno Autístico/psicología , Niño , Simulación por Computador , Diagnóstico Diferencial , Errores Diagnósticos/prevención & control , Técnicas y Procedimientos Diagnósticos/tendencias , Humanos , Valor Predictivo de las Pruebas , Conducta Social , Programas Informáticos , Diseño de Software , EnseñanzaRESUMEN
A 35 year old male developed multiple, non-tender metastatic nodules on the skin overlying an adenocarcinoma of the parotid gland. The patient was still alive 2 years after clinical diagnosis.