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J Phys Chem B ; 114(35): 11484-8, 2010 Sep 09.
Artículo en Inglés | MEDLINE | ID: mdl-20707362

RESUMEN

Fluorescence recovery after photobleaching was used to characterize the diffusion of fluorescently labeled phospholipids at the oil/water interface for oil viscosities that varied over four orders of magnitude. Measurements were performed over a range of surface concentrations corresponding to molecular areas of 40-130 A(2)/molecule. As expected, the interfacial diffusion coefficient increased with molecular area, saturating at an area of approximately 100 A(2)/molecule. At molecular areas below approximately 80 A(2)/molecule, macroscopic domains of a condensed monolayer phase were observed; the diffusion of these domains was characterized by direct tracking and trajectory analysis. For oils with viscosity

Asunto(s)
Aceites/química , Fosfolípidos/química , Agua/química , Difusión , Fotoblanqueo , Propiedades de Superficie , Viscosidad
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