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In this paper, the amplified spontaneous emission (ASE) suppression in a 1050â nm fiber laser with a pump-sharing oscillator-amplifier (PSOA) structure is studied theoretically and experimentally. A theoretical model of a fiber laser with a PSOA structure is established. The characteristics of the ASE for the PSOA structure and the pump-independent oscillator-amplifier (PIOA) structure are compared and analyzed. The experimental results show that the ASE can be effectively suppressed by utilizing the PSOA structure, which agree with the simulation results. A 1050â nm high-power narrow-linewidth fiber laser with PSOA structure is demonstrated, in which the gain fiber lengths of the oscillator and amplifier are 1.6 m and 9 m, respectively, to ensure the interconnection of pump power between the oscillator and amplifier. Finally, the maximum output power of 3.1â kW has been achieved, the linewidth is 0.22â nm at 3â dB, the beam quality M2â ≈â 1.33, and the optical signal-to-noise ratio (OSNR) is 45.5â dB.
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Antioxidants are healthy substances that are beneficial to the human body and exist mainly in natural and synthetic forms. Among many kinds of antioxidants, the natural antioxidants have great applications in many fields such as food chemistry, medical care, and clinical application. In recent years, many efforts have been made for the determination of natural antioxidants. Nano-electrochemical sensors combining electrochemistry and nanotechnology have been widely used in the determination of natural antioxidants due to their unique advantages. Therefore, a large number of nanomaterials such as metal oxide, carbon materials, and conducting polymer have attracted much attention in the field of electrochemical sensors due to their good catalytic effect and stable performance. This review mainly introduces the construction of electrochemical sensors based on different nanomaterials, such as metallic nanomaterials, metal oxide nanomaterials, carbon nanomaterials, metal-organic frameworks, polymer nanomaterials, and other nanocomposites, and their application to the detection of natural antioxidants, including ascorbic acid, phenolic acids, flavonoid, tryptophan, citric acid, and other natural antioxidants. In the end, the limitations of the existing nano-sensing technology, the latest development trend, and the application prospect for various natural antioxidant substances are summarized and analyzed. We expect that this review will be helpful to researchers engaged in electrochemical sensors.
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Antioxidantes , Nanocompuestos , Carbono/química , Técnicas Electroquímicas , Humanos , Óxidos , Polímeros/químicaRESUMEN
A three-dimensional g-C3N4/MWNTs/GO hybrid modified electrode was constructed as an electrochemical sensor for the simultaneous determination of ascorbic acid (AA), dopamine (DA) and uric acid (UA). Due to the high conductivity of MWCNTs and the strong synergy between g-C3N4 and GO, the combination of the three effectively improved the electrocatalytic activity of the modified electrode for the oxidation of AA, DA, and UA, and solved the problems such as overlapping anodic peaks. The electrochemical performance of the as-constructed sensor was investigated and optimized by cyclic voltammetry (CV) and differential pulse voltammetry (DPV). The linear response range of AA, DA, and UA in the optimal condition was 0.2-7.5 mM, 2-100 µM, and 4-200 µM, respectively. The detection limits (S/N = 3) of AA, DA, and UA were 96, 0.22, and 1.36 µM, respectively. The recoveries of AA, DA and UA in serum samples from three groups were 92.82-106.50%, and the relative standard deviations were less than 2%. The results show that the as-constructed g-C3N4/MWNTs/GO modified electrode has the advantages of simplicity, high sensitivity and good selectivity, and can simultaneously determine AA, DA, and UA.
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Grafito , Ácido Úrico , Ácido Ascórbico , Dopamina , Técnicas Electroquímicas/métodos , ElectrodosRESUMEN
Xanthomonas oryzae pv. oryzicola (Xoc), the causal agent of bacterial leaf streak, is one of the most severe seed-borne bacterial diseases of rice. However, the molecular mechanisms underlying Xoc in response to oxidative stress are still unknown. In this study, we performed a time-course RNA-seq analysis on the Xoc in response to H2O2, aiming to reveal its oxidative response network. Overall, our RNA sequence analysis of Xoc revealed a significant global gene expression profile when it was exposed to H2O2. There were 7, 177, and 246 genes that were differentially regulated at the early, middle, and late stages after exposure, respectively. Three genes (xoc_1643, xoc_1946, xoc_3249) showing significantly different expression levels had proven relationships with oxidative stress response and pathogenesis. Moreover, a hypothetical protein (XOC_2868) showed significantly differential expression, and the xoc_2868 mutants clearly displayed a greater H2O2 sensitivity and decreased pathogenicity than those of the wild-type. Gene localization and phylogeny analysis strongly suggests that this gene may have been horizontally transferred from a Burkholderiaceae ancestor. Our study not only provides a first glance of Xoc's global response against oxidative stress, but also reveals the impact of horizontal gene transfer in the evolutionary history of Xoc.