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1.
J Phys Chem A ; 2024 Jun 27.
Artículo en Inglés | MEDLINE | ID: mdl-38935631

RESUMEN

The thermal decomposition of perfluorooctanoic acid (PFOA) under oxidative conditions was investigated using air (O2) and N2O as oxidants over temperatures ranging from 400 to 1000 °C in an α-alumina reactor. In the presence of air, PFOA was found to decompose into perfluorohept-1-ene (C7F14) and perfluoroheptanoyl fluoride (C7F14O) in addition to HF, CO, and CO2. At temperatures above 800 °C, both C7F14 and C7F14O were no longer detected. A comprehensive analysis of the reaction mechanisms through quantum chemical analysis and kinetic modeling in combination with experimental observations was utilized to identify key reaction pathways. Quantum chemical analysis led to the conclusion that oxygen atoms are crucial in decomposing perfluoroalk-1-enes, especially the stable perfluorohept-1-ene (C7F14). Under oxidative conditions, it was found that significant quantities of C2F6 and CF4 were formed. Further quantum chemical analysis suggests that the O atoms facilitate the formation of volatile fluorinated compounds (VFCs) such as tetrafluoromethane (CF4) and hexafluoroethane (C2F6), particularly at higher temperatures. By elucidating these key reactions, an improved understanding of the potential formation products of incomplete combustion (PICs) or products of incomplete destruction (PIDs) is made.

2.
Memory ; 25(3): 317-325, 2017 03.
Artículo en Inglés | MEDLINE | ID: mdl-27050770

RESUMEN

Studies of the memory-control framework have contrasted free-report and forced-report recall, with little regard to the order of these two tests. The present experiment sought to demonstrate that test order is crucial, and that this suggests a potential role for metacognitive monitoring on memory retrieval. Participants undertook tests of episodic and semantic memory in both free- and forced-report format, in one of the two potential response orders. This showed that free-report performance was more accurate if conducted prior to forced-report, rather than after it, with no cost to memory quantity. Additionally, there was a trend towards higher forced-report performance if it was preceded by an initial free-report test, a pattern revealed by a meta-analysis to be consistent with previous studies in the literature. These findings suggest a reciprocal relationship between metacognitive monitoring and early retrieval processes in memory that results in higher memory performance when monitoring is encouraged.


Asunto(s)
Memoria/fisiología , Metacognición/fisiología , Adolescente , Femenino , Humanos , Masculino , Recuerdo Mental/fisiología , Pruebas Neuropsicológicas , Adulto Joven
3.
Law Hum Behav ; 40(2): 147-58, 2016 Apr.
Artículo en Inglés | MEDLINE | ID: mdl-26595704

RESUMEN

When making a memorial judgment, respondents can regulate their accuracy by adjusting the precision, or grain size, of their responses. In many circumstances, coarse-grained responses are less informative, but more likely to be accurate, than fine-grained responses. This study describes a novel eyewitness identification procedure, the grain-size lineup, in which participants eliminated any number of individuals from the lineup, creating a choice set of variable size. A decision was considered to be fine-grained if no more than 1 individual was left in the choice set or coarse-grained if more than 1 individual was left in the choice set. Participants (N = 384) watched 2 high-quality or low-quality videotaped mock crimes and then completed 4 standard simultaneous lineups or 4 grain-size lineups (2 target-present and 2 target-absent). There was some evidence of strategic regulation of grain size, as the most difficult lineup was associated with a greater proportion of coarse-grained responses than the other lineups. However, the grain-size lineup did not outperform the standard simultaneous lineup. Fine-grained suspect identifications were no more diagnostic than suspect identifications from standard lineups, whereas coarse-grained suspect identifications carried little probative value. Participants were generally reluctant to provide coarse-grained responses, which may have hampered the utility of the procedure. For a grain-size approach to be useful, participants may need to be trained or instructed to use the coarse-grained option effectively.


Asunto(s)
Recuerdo Mental , Reconocimiento en Psicología , Grabación de Cinta de Video , Criminales , Femenino , Humanos , Masculino , Adulto Joven
4.
Br J Clin Psychol ; 53(2): 170-93, 2014 Jun.
Artículo en Inglés | MEDLINE | ID: mdl-24921070

RESUMEN

OBJECTIVES: Overgeneral autobiographical memory (OGM) refers to the impaired retrieval of specific events from autobiographical memory. This review examined OGM in children and adolescents to answer three main questions. First, do children demonstrate OGM? Second, how does the experience of OGM relate to childhood trauma and associated psychopathology? Third, is the CaR-FA-X model (Williams et al., 2007) able to explain OGM in child psychopathology once developmental issues have been considered? METHOD: Articles were identified in PsycINFO and PubMed searches using the terms overgeneral memory AND children, autobiographical memory specificity AND children, and autobiographical memory AND children. The authors reviewed 21 articles that examined OGM in young people aged 7­18 years. Effect sizes were calculated for each study. RESULTS: The review demonstrated consistent support for a relationship with trauma exposure and depression symptoms in childhood. Furthermore, OGM was found to predict depression symptoms. Limited support was provided for the efficacy of the CaR-FA-X model in young people. CONCLUSIONS: Future research will need to examine the influence of trauma characteristics on OGM development, along with the relationship of OGM to depression prognosis. Further investigation of the CaR-FA-X model is required and developmental aspects will need to be taken into account.


Asunto(s)
Memoria Episódica , Adolescente , Niño , Depresión/diagnóstico , Femenino , Humanos , Masculino , Pronóstico , Psicopatología , PubMed
5.
Autism ; 28(4): 1029-1044, 2024 Apr.
Artículo en Inglés | MEDLINE | ID: mdl-37606218

RESUMEN

LAY ABSTRACT: Most research about autism spectrum disorder (ASD) in females has looked at autistic features in people who have already received diagnoses. Because our understanding of ASD has been shaped by the difficulties of males, females may experience different difficulties and may not meet the criteria for diagnosis because of a skewed concept of ASD. We extracted detailed information from the assessment reports of 222 children who were either diagnosed with ASD (156 children) or not diagnosed despite many ASD traits (78 children). Females were less likely to have restricted interests, especially females who did not receive an ASD diagnosis. Females who did not receive an ASD diagnosis tended to show more ability in social and emotional reciprocity than what would qualify them for a diagnosis. We also found sex-/gender-specific profiles of body use and speech mannerisms. Many behaviours were more closely linked with an ASD diagnosis for males and others for females, suggesting that behaviours may be interpreted differently depending on the child's sex/gender. We discuss implications for assessing females for ASD in the context of this evidence.


Asunto(s)
Trastorno del Espectro Autista , Trastorno de Movimiento Estereotipado , Masculino , Niño , Humanos , Femenino , Trastorno del Espectro Autista/diagnóstico , Trastorno del Espectro Autista/psicología , Fenotipo , Habla
6.
Sci Total Environ ; 932: 172658, 2024 Jul 01.
Artículo en Inglés | MEDLINE | ID: mdl-38657813

RESUMEN

Per- and poly-fluoroalkyl substances (PFAS) are a class of synthetic chemicals known for their widespread presence and environmental persistence. Carbon-fluorine (C-F) bonds are major components among PFAS and among the strongest organic bonds, thus destroying PFAS may present significant challenge. Thermal treatment such as incineration is an effective and approved method for destroying many halogenated organic chemicals. Here, we present the results of existing studies and testing at combustion-based thermal treatment facilities and summarize what is known regarding PFAS destruction and mineralization at such units. Available results suggest the temperature and residence times reached by some thermal treatment systems are generally favorable to the destruction of PFAS, but the possibility for PFAS or fluorinated organic byproducts to escape destruction and adequate mineralization and be released into the air cannot be ruled out. Few studies have been conducted at full-scale operating facilities, and none to date have attempted to characterize possible fluorinated organic products of incomplete combustion (PICs). Further, the ability of existing air pollution control (APC) systems, designed primarily for particulate and acid gas control, to reduce PFAS air emissions has not been determined. These data gaps remain primarily due to the previous lack of available methods to characterize PFAS destruction and PIC concentrations in facility air emissions. However, newly developed stack testing methods offer an improved understanding of the extent to which thermal waste treatment technologies successfully destroy and mineralize PFAS in these waste streams.

7.
Behav Sci Law ; 31(5): 607-23, 2013.
Artículo en Inglés | MEDLINE | ID: mdl-24108576

RESUMEN

Conforming to erroneous memory reports of co-witnesses can have serious impacts on subsequent forensic investigation and court reports. One theoretical explanation proposed is that memory conformity arises due to informational influence; the co-witness desires to give accurate information and reports the co-witness's version because they perceive the co-witness as being more credible. We tested the idea that perceptions of credibility drive memory conformity. We manipulated credibility through expertise; specifically, by telling participants that the (confederate) co-witness had previously worked as either a policeman (high expertise) or an electrician (low expertise). After a discussion with the co-witness, we assessed cued-recall memory and perceptions of credibility about the co-witness and the self. We found that higher expertise led to greater memory conformity. Although higher expertise also led to higher credibility assessments of the co-witness, this was only for perceptions of the credibility as an eye-witness and memory confidence, neither of which predicted memory conformity. By contrast, memory accuracy of the co-witness relative to self-memory accuracy predicted memory conformity, but this was not affected by expertise. These results show support for an informational influence explanation but suggest that expertise perceptions operate differently from our explanation.


Asunto(s)
Testimonio de Experto , Memoria , Percepción Social , Adolescente , Adulto , Señales (Psicología) , Femenino , Humanos , Masculino , Recuerdo Mental , Encuestas y Cuestionarios
8.
Addiction ; 118(9): 1687-1698, 2023 09.
Artículo en Inglés | MEDLINE | ID: mdl-37070481

RESUMEN

BACKGROUND AND AIMS: The inclusion of gaming disorder (GD) in the International Classification of Diseases 11th Revision (ICD-11) has generated scholarly debate, including claims about its potential stigmatizing effects on the wider gaming population. The present study aimed to estimate the effect of addiction-based and non-addiction-based conceptualizations of problem gaming on stigma of gamers. DESIGN: This preregistered experiment involved a 2 (health information: addiction-related or non-addiction-related) × 3 (vignette: problem, regular or casual gamer) randomized, between-subjects design. SETTING: An international sample of participants was recruited via Prolific in June and July 2021. PARTICIPANTS: Participants were eligible (n = 1228) if they were aged 35 to 50 years, played video games for no more than 6 hours per week and did not endorse DSM-5 or ICD-11 criteria for GD. INTERVENTION AND COMPARATOR: Participants were provided with an explanation of problem gaming as related to either an addictive disorder (i.e. 'addiction' explanation) or personal choice and lifestyle factors (i.e. 'non-addiction' explanation). MEASUREMENTS: The Attribution Questionnaire (AQ) and Universal Stigma Scale (USS) assessed stigma toward each gamer vignette. Vignettes described a problem gamer (with features of GD); a regular gamer (frequent gaming; some life interference); and a casual gamer (infrequent gaming; no life interference). FINDINGS: Problem gamer vignettes (mean [M] = 113.3; 95% CI = 111.5-115.4) received higher AQ stigma ratings than regular (M = 94.0; 95% CI = 91.9-95.9) and casual gamers (M = 80.1; 95% CI = 78.2-82.1). Although significant, the effect of health information type on AQ stigma ratings was negligible (addiction group [M = 97.6; 95% CI = 95.9-99.1], non-addiction group [M = 94.1; 95% CI = 92.6-95.8]). However, the addiction information group scored lower on USS blame and responsibility than the non-addiction information group with at least a small effect (99.1% confidence). CONCLUSIONS: Framing of problem gaming as an addictive disorder or non-addictive activity appears to have a negligible effect on stigma of different gamers among middle-age adults with minimal gaming experience. The concept of 'gaming addiction' seems unlikely to be an important influence on public stigma of gaming.


Asunto(s)
Conducta Adictiva , Trastornos Disruptivos, del Control de Impulso y de la Conducta , Juegos de Video , Adulto , Persona de Mediana Edad , Humanos , Juicio , Estigma Social , Internet
9.
Psychol Sci ; 23(10): 1208-14, 2012 Oct 01.
Artículo en Inglés | MEDLINE | ID: mdl-22933457

RESUMEN

Eyewitness-identification tests often culminate in witnesses not picking the culprit or identifying innocent suspects. We tested a radical alternative to the traditional lineup procedure used in such tests. Rather than making a positive identification, witnesses made confidence judgments under a short deadline about whether each lineup member was the culprit. We compared this deadline procedure with the traditional sequential-lineup procedure in three experiments with retention intervals ranging from 5 min to 1 week. A classification algorithm that identified confidence criteria that optimally discriminated accurate from inaccurate decisions revealed that decision accuracy was 24% to 66% higher under the deadline procedure than under the traditional procedure. Confidence profiles across lineup stimuli were more informative than were identification decisions about the likelihood that an individual witness recognized the culprit or correctly recognized that the culprit was not present. Large differences between the maximum and the next-highest confidence value signaled very high accuracy. Future support for this procedure across varied conditions would highlight a viable alternative to the problematic lineup procedures that have traditionally been used by law enforcement.


Asunto(s)
Crimen/psicología , Toma de Decisiones/fisiología , Juicio/fisiología , Memoria/fisiología , Estrés Psicológico/psicología , Adolescente , Adulto , Intervalos de Confianza , Femenino , Humanos , Masculino , Recuerdo Mental/fisiología , Persona de Mediana Edad , Reconocimiento en Psicología/fisiología , Adulto Joven
10.
Law Hum Behav ; 36(1): 28-36, 2012 Feb.
Artículo en Inglés | MEDLINE | ID: mdl-22471383

RESUMEN

Improving eyewitness identification evidence remains a key priority for research. Basic laboratory research has consistently demonstrated that allowing participants to withhold answers about which they are unsure leads to improved accuracy. Surprisingly, this approach has not been the subject of comprehensive investigation in the eyewitness identification literature. In this article, we explored the utility of allowing uncertain witnesses to opt out of an identification decision, by providing an explicit don't know option. Further, we contrasted the rate of use of this explicit option with the frequency that participants spontaneously withheld a decision when asked to respond in their own words. Four hundred and twenty participants witnessed a mock crime video before being presented with a showup of the perpetrator or an innocent suspect. Participants were tested either immediately or after a 3-week delay, with one of the three report options: Participants either made their choice in their own words (spontaneous report), chose between identifying and rejecting the showup (forced-report), or chose between identification, rejection and don't know (free-report). Only 2.2% of witnesses spontaneously used a don't know response, compared to 19.3% who used it when the option was explicit. Compared with the forced-report decisions, free-report decisions were more accurate, more diagnostic of the suspect's guilt or innocence, and came at no cost to the number of correct decisions rendered. These data suggest that utilisation of an explicit don't know option may be of practical value.


Asunto(s)
Crimen/legislación & jurisprudencia , Memoria , Percepción Visual , Adolescente , Adulto , Australia , Femenino , Humanos , Masculino , Adulto Joven
11.
Law Hum Behav ; 36(5): 439-47, 2012 Oct.
Artículo en Inglés | MEDLINE | ID: mdl-22468758

RESUMEN

Wells ("The psychology of lineup identifications," Journal of Applied Social Psychology, 1984, 14, 89-103) proposed that a blank lineup (an initial lineup of known-to-be-innocent foils) can be used to screen eyewitnesses; witnesses who chose from a blank lineup (initial choosers) were more likely to make an error on a second lineup that contained a suspect than were witnesses who rejected a blank lineup (initial nonchoosers). Recent technological advances (e.g., computer-administered lineups) may overcome many of the practical difficulties cited as a barrier to the use of blank lineups. Our research extended knowledge about the blank lineup procedure by investigating the underlying causes of the difference in identification performance between initial choosers and initial nonchoosers. Studies 1a and 1b (total, N = 303) demonstrated that initial choosers were more likely to reject a second lineup than initial nonchoosers and witnesses who did not view a blank lineup, implying that cognitive biases (e.g., confirmation bias and commitment effects) influenced initial choosers' identification decisions. In Study 2 (N = 200), responses on a forced-choice identification test provided evidence that initial choosers have, on average, poorer memories for the culprit than do initial nonchoosers. We also investigated the usefulness of blank lineups for interpreting identification evidence. Diagnosticity ratios suggested that suspect identifications made by initial nonchoosers (cf. initial choosers) should have a greater impact on estimates of the likely guilt of the suspect. Furthermore, for initial nonchoosers, higher confidence in blank lineup rejections was associated with higher diagnosticity for subsequent suspect identifications. These results have implications for policy to guide the collection and interpretation of identification evidence.


Asunto(s)
Conducta de Elección , Juicio , Recuerdo Mental , Reconocimiento en Psicología , Adolescente , Adulto , Anciano , Cognición , Derecho Penal , Femenino , Humanos , Masculino , Persona de Mediana Edad , Grabación en Video , Adulto Joven
12.
J Autism Dev Disord ; 52(10): 4474-4489, 2022 Oct.
Artículo en Inglés | MEDLINE | ID: mdl-34669104

RESUMEN

Despite the importance of clinical judgement in autism spectrum disorder (ASD) assessment, little is currently known about challenges faced by diagnosticians when the client is female, any sex/gender biases during the assessment process, and how these issues affect diagnostic outcomes. Forty-seven ASD diagnosticians completed a questionnaire containing two hypothetical case studies (a 'male' and 'female' ASD presentation), with sex/gender randomly assigned within each. Diagnosticians reported greater ASD symptom severity when female sex/gender pseudonyms were allocated to the case studies, but their confidence in ASD diagnosis was similar regardless of condition. Diagnosticians identified a large number of challenges associated with assessing females for ASD. Many of these related to sex/gender differences in ASD presentation and limitations of diagnostic instruments.


Asunto(s)
Trastorno del Espectro Autista , Trastorno del Espectro Autista/diagnóstico , Femenino , Humanos , Factores Sexuales , Sexismo , Encuestas y Cuestionarios
13.
J Autism Dev Disord ; 52(9): 3958-3976, 2022 Sep.
Artículo en Inglés | MEDLINE | ID: mdl-34533659

RESUMEN

Growing evidence suggests that autistic females are more likely to be diagnostically overlooked than males, perhaps due to differences in ASD presentations (van Wijngaarden-Cremers in JAMA 44:627-635, 2014). To investigate specific behaviours in which differences lie, we analysed profiles of 777 children using the Childhood Autism Rating Scale (Scholper in JAMA 29:489-493, 2010) or Gilliam Autism Rating Scale (Gilliam, 2014). Males demonstrated greater difficulty in six CARS2-ST items and seven behaviours on the GARS-3, mostly reflecting restricted and repetitive behaviours. Across all instruments, the only area in which females showed greater difficulty was fear or nervousness (CARS2-ST). No meaningful differences emerged from the CARS2-HF analysis. Where males showed greater difficulty, females were more likely to present with developmentally typical behaviour.


Asunto(s)
Trastorno del Espectro Autista , Trastorno Autístico , Trastorno del Espectro Autista/diagnóstico , Niño , Femenino , Humanos , Masculino , Caracteres Sexuales , Factores Sexuales
14.
Front Psychiatry ; 13: 929657, 2022.
Artículo en Inglés | MEDLINE | ID: mdl-36090357

RESUMEN

Objectives: Associations between awareness of one's own aging and wellbeing have received increasing attention in the field of gerontology over the last decade. The current study examines how between-person differences and within-person fluctuations of awareness of age-related change (AARC) relate to daily negative affect and vitality. Of key interest was the extent to which fluctuations in AARC moderated reactivity to stressor exposure. We predicted that higher positive perceptions of aging (AARC-gains) would buffer the relationship between daily stressors and negative affect/vitality. Conversely, we expected that higher negative perceptions (AARC-losses) may exacerbate the relationship between daily stressors and the outcome variables. Methods: Data were collected from a community-based sample of 152 Australian adults aged 53-86 (M = 69.18, SD = 5.73). For 10 consecutive days, participants completed surveys on their smartphones measuring daily stressors, AARC, and affect (positive and negative). Bayesian hierarchical linear models were used to examine whether AARC-gains and AARC-losses moderated within-person associations of daily stressors and affect (i.e., stress reactivity). Results: At the between-person level, higher AARC-gains was associated with lower negative affect and higher vitality, whereas those reporting higher AARC-losses scored higher on negative affect and lower on vitality. Within-person variables revealed that on days when AARC-gains was higher and AARC-losses was lower, this corresponded with lower negative affect and higher vitality. There was no evidence in support of individual moderating effects of within-person AARC-losses or within-person AARC-gains on stress reactivity. A trend was evident in support of a three-way WP Stress severity × WP AARC-gains × WP AARC-losses interaction in the prediction of negative affect, indicating that on days when AARC-losses was higher, the association of stress severity with negative affect was weaker if AARC-gains was higher. Follow-up analyses modeling quadratic stress severity revealed a trend suggesting an interaction of within-person stress severity and within-person AARC-losses. Discussion: Results indicate that both individual differences and short-term fluctuations in AARC are associated with daily negative affect and vitality. The results provided qualified support for a possible protective role of AARC-gains in the context of stress reactivity.

15.
Sleep ; 44(9)2021 09 13.
Artículo en Inglés | MEDLINE | ID: mdl-33893807

RESUMEN

The high prevalence of chronic sleep restriction in adolescents underscores the importance of understanding how adolescent sleep is regulated under such conditions. One component of sleep regulation is a homeostatic process: if sleep is restricted, then sleep intensity increases. Our knowledge of this process is primarily informed by total sleep deprivation studies and has been incorporated in mathematical models of human sleep regulation. Several animal studies, however, suggest that adaptation occurs in chronic sleep restriction conditions, showing an attenuated or even decreased homeostatic response. We investigated the homeostatic response of adolescents to different sleep opportunities. Thirty-four participants were allocated to one of three groups with 5, 7.5, or 10 h of sleep opportunity per night for five nights. Each group underwent a protocol of nine nights designed to mimic a school week between two weekends: two baseline nights (10 h sleep opportunity), five condition nights (5, 7.5, or 10 h), and two recovery nights (10 h). Measures of sleep homeostasis (slow-wave activity and slow-wave energy) were calculated from frontal and central EEG derivations and compared to predictions derived from simulations of the homeostatic process of the two-process model of sleep regulation. Only minor differences were found between empirical data and model predictions, indicating that sleep homeostasis is preserved under chronic sleep restriction in adolescents. These findings improve our understanding of effects of repetitive short sleep in adolescents.


Asunto(s)
Privación de Sueño , Sueño , Adaptación Fisiológica , Adolescente , Electroencefalografía , Homeostasis , Humanos , Polisomnografía
16.
Law Hum Behav ; 34(4): 337-47, 2010 Aug.
Artículo en Inglés | MEDLINE | ID: mdl-19626432

RESUMEN

Recent research using a calibration approach indicates that eyewitness confidence assessments obtained immediately after a positive identification decision provide a useful guide as to the likely accuracy of the identification. This study extended research on the boundary conditions of the confidence-accuracy (CA) relationship by varying the retention interval between encoding and identification test. Participants (N = 1,063) viewed one of five different targets in a community setting and attempted an identification from an 8-person target-present or -absent lineup either immediately or several weeks later. Compared to the immediate condition, the delay condition produced greater overconfidence and lower diagnosticity. However, for choosers at both retention intervals there was a meaningful CA relationship and diagnosticity was much stronger at high than low confidence levels.


Asunto(s)
Recuerdo Mental , Adolescente , Adulto , Anciano , Anciano de 80 o más Años , Femenino , Humanos , Jurisprudencia , Masculino , Persona de Mediana Edad , Retención en Psicología , Factores de Tiempo , Adulto Joven
17.
J Anxiety Disord ; 76: 102324, 2020 12.
Artículo en Inglés | MEDLINE | ID: mdl-33137600

RESUMEN

Cognitive Processing Therapy (CPT) and Behavioural Activation Therapy (BA) were used to treat individuals with comorbid posttraumatic stress disorder (PTSD) and major depressive disorder (MDD). Fifty-two individuals (48 women, 4 men) were randomized to CPT alone (n = 18), CPT then BA for MDD (n = 17), or BA then CPT (n = 17). Presenting trauma was primarily interpersonal (87 %). Participants were assessed at pre-, posttreatment, and 6-month follow-up. PTSD and MDD symptoms were the main outcome of interest; trauma cognitions, rumination, and emotional numbing were secondary outcomes. All groups showed sizeable reductions in PTSD and depression (effect sizes at follow-up ranging between 1.02-2.54). A pattern of findings indicated CPT/BA showed better outcomes in terms of larger effect sizes and loss of diagnoses relative to CPT alone and BA/CPT. At follow-up greater numbers of the CPT/BA group were estimated to have achieved good end-state for remission of both PTSD and depression (49 %, CI95 [.26, .73]) relative to CPT alone (18 %, CI95 [.03, .38]) and BA/CPT (11 %, CI95 [.01, .29]). Although tempered by the modest sample size, the findings suggest that individuals with comorbid PTSD and MDD may benefit from having PTSD targeted first before remaining MDD symptoms are addressed.


Asunto(s)
Terapia Cognitivo-Conductual , Trastorno Depresivo Mayor , Psicoterapia de Grupo , Trastornos por Estrés Postraumático , Terapia Conductista , Comorbilidad , Trastorno Depresivo Mayor/epidemiología , Trastorno Depresivo Mayor/terapia , Femenino , Humanos , Masculino , Trastornos por Estrés Postraumático/epidemiología , Trastornos por Estrés Postraumático/terapia
18.
Am Psychol ; 75(1): 76-91, 2020 01.
Artículo en Inglés | MEDLINE | ID: mdl-30998024

RESUMEN

Problems associated with eyewitness identification decisions have long been highlighted by memory researchers (e.g., Loftus, 1979), with overwhelming evidence that witnesses can err, sometimes with disastrous consequences. Guided by the rationale that witnesses have access to potentially probative memorial information not captured by the traditional categorical lineup responses, an alternative procedure was examined in 6 experiments with adult (N = 1,669) and child (N = 273) witnesses. Instead of witnesses being asked to identify the offender from the lineup, they rated their confidence in the match between the offender and each lineup member and then variations in the maximum (max) confidence values assigned (i.e., the highest rated lineup members) were examined. Specifically, we evaluated how well max confidence values predicted suspect guilt or innocence. When suspects (guilty or innocent) in a lineup received the max confidence rating, the probability of guilt increased with the max. When the suspect received a rating lower than the max, they were generally more likely to be innocent. Max confidence patterns also predicted guilt where a traditional positive identification would have been unlikely: for example, when the max was low, when the witness gave the max to multiple lineup members, or when a filler received the max but the suspect also received a high rating. The data indicate that witnesses have access to probative memorial information often not captured by the traditional lineup responses when identifying someone or rejecting the lineup. Guidelines for the use and interpretation of this theoretically informed futuristic alternative to existing lineup procedures are provided. (PsycINFO Database Record (c) 2020 APA, all rights reserved).


Asunto(s)
Crimen , Derecho Penal , Recuerdo Mental , Adolescente , Adulto , Anciano , Niño , Femenino , Humanos , Masculino , Persona de Mediana Edad , Policia , Adulto Joven
19.
Environ Sci Process Impacts ; 22(10): 2084-2094, 2020 Oct 01.
Artículo en Inglés | MEDLINE | ID: mdl-32909592

RESUMEN

Chlorpyrifos (CPF) is a widely used pesticide; however, limited experimental work has been completed on its thermal decomposition. CPF is known to decompose into 3,5,6-trichloro-2-pyridinol (TCpyol) together with ethylene and HOPOS. Under oxidative conditions TCpyol can decompose into the dioxin-like 2,3,7,8-tetrachloro-[1,4]-dioxinodipyridine (TCDDPy). With CPF on the cusp of being banned in several jurisdictions worldwide, the question might arise as to how to safely eliminate large stockpiles of this pesticide. Thermal methods such as incineration or thermal desorption of pesticide-contaminated soils are often employed. To assess the safety of thermal methods, information about the toxicants arising from thermal treatment is essential. The present flow reactor study reports the products detected under inert and oxidative conditions from the decomposition of CPF representative of thermal treatments and of wildfires in CPF-contaminated vegetation. Ethylene and TCpyol are the initial products formed at temperatures between 550 and 650 °C, although the detection of HOPOS as a reaction product has proven to be elusive. During pyrolysis of CPF in an inert gas, the dominant sulfur-containing product detected from CPF is carbon disulfide. Quantum chemical analysis reveals that ethylene and HOPOS undergo a facile reaction to form thiirane (c-C2H4S) which subsequently undergoes ring opening reactions to form precursors of CS2. At elevated temperatures (>650 °C), TCpyol undergoes both decarbonylation and dehydroxylation reactions together with decomposition of its primary product, TCpyol. A substantial number of toxicants is observed, including HCN and several nitriles, including cyanogen. No CS2 is observed under oxidative conditions - sulfur dioxide is the fate of S in oxidation of CPF, and quantum chemical studies show that SO2 formation is initiated by the reaction between HOPOS and O2. The range of toxicants produced in thermal decomposition of CPF is summarised.


Asunto(s)
Cloropirifos , Dioxinas , Insecticidas , Plaguicidas , Dibenzodioxinas Policloradas , Estrés Oxidativo
20.
J Exp Psychol Gen ; 137(3): 528-47, 2008 Aug.
Artículo en Inglés | MEDLINE | ID: mdl-18729714

RESUMEN

Eyewitness identification decisions are vulnerable to various influences on witnesses' decision criteria that contribute to false identifications of innocent suspects and failures to choose perpetrators. An alternative procedure using confidence estimates to assess the degree of match between novel and previously viewed faces was investigated. Classification algorithms were applied to participants' confidence data to determine when a confidence value or pattern of confidence values indicated a positive response. Experiment 1 compared confidence group classification accuracy with a binary decision control group's accuracy on a standard old-new face recognition task and found superior accuracy for the confidence group for target-absent trials but not for target-present trials. Experiment 2 used a face mini-lineup task and found reduced target-present accuracy offset by large gains in target-absent accuracy. Using a standard lineup paradigm, Experiments 3 and 4 also found improved classification accuracy for target-absent lineups and, with a more sophisticated algorithm, for target-present lineups. This demonstrates the accessibility of evidence for recognition memory decisions and points to a more sensitive index of memory quality than is afforded by binary decisions.


Asunto(s)
Atención , Toma de Decisiones , Cara , Recuerdo Mental , Reconocimiento Visual de Modelos , Adolescente , Adulto , Conducta de Elección , Aprendizaje Discriminativo , Femenino , Humanos , Juicio , Masculino , Adulto Joven
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