Modulation Engineering of Electromagnetic Wave Absorption Performance of Layered Double Hydroxides Derived Hollow Metal Carbides Integrating Corrosion Protection.

Layered double hydroxides (LDHs) with unique layered structure and atomic composition are limited in the field of electromagnetic wave absorption (EMA) due to their poor electrical conductivity and lack of dielectric properties. In this study, the EMA performance and anticorrosion of hollow derived LDH composites are improved by temperature control and composition design using ZIF-8 as a sacrifice template. Diverse regulation modes result in different mechanisms for EMA. In the temperature control process, chemical reactions tune the composition of the products and construct a refined structure to optimize the LDHs conductivity loss. Additionally, the different phase interfaces generated by the control components optimize the impedance matching and enhance the interfacial polarization. The results show that the prepared NCZ (Ni3ZnC0.7/Co3ZnC@C) has a minimum reflection loss (RLmin ) of -58.92 dB with a thickness of 2.4 mm and a maximum effective absorption bandwidth (EABmax ) of 7.36 GHz with a thickness of 2.4 mm. Finally, due to its special structure and composition, the sample exhibits excellent anticorrosion properties. This work offers essential knowledge for designing engineering materials derived from metal organic framework (MOF) with cutting-edge components and nanostructures.

Multiphase Molybdenum Carbide Doped Carbon Hollow Sphere Engineering: The Superiority of Unique Double-Shell Structure in Microwave Absorption.

In order to achieve excellent electromagnetic wave (EMW) absorption properties, the microstructure design and component control of the absorber are critical. In this study, three different structures made of Mo2 C/C hollow spheres are prepared and their microwave absorption behavior is investigated. The Mo2 C/C double-shell hollow spheres consisting of an outer thin shell and an inner rough thick shell with multiple EMW loss mechanisms exhibit good microwave absorption properties. In order to further improve the microwave absorption properties, MoC1-x /C double-shell hollow spheres with different crystalline phases of molybdenum carbide are prepared to further optimize the EMW loss capability of the materials. Finally, MoC1-x /C double-shell hollow spheres with α-phase molybdenum carbide have the best microwave absorption properties. When the filling is 20 wt.%, the minimum reflection loss at 1.8 mm is -50.55 dB and the effective absorption bandwidth at 2 mm is 5.36 GHz, which is expected to be a microwave absorber with the characteristics of "thin, light, wide, and strong".

Anion Exchange of Metal Particles on Carbon-Based Skeletons for Promoting Dielectric Equilibrium and High-Efficiency Electromagnetic Wave Absorption.

The combination of carbon materials and magnetic elements is considered as an effective strategy to obtain high-performance electromagnetic wave (EMW) absorption materials. However, using nanoscale regulation to the optimization of composite material dielectric properties and enhanced magnetic loss properties is facing significant challenges. Here, the dielectric constant and magnetic loss capability of the carbon skeleton loaded with Cr compound particles are further tuned to enhance the EMW absorption performance. After 700 °C thermal resuscitation of the Cr3-polyvinyl pyrrolidone composite material, the chromium compound is represented as a needle-shaped structure of nanoparticles, which is fixed on the carbon skeleton derived from the polymer. The size-optimized CrN@PC composites are obtained after the substitution of more electronegative nitrogen elements using an anion-exchange strategy. The minimum reflection loss value of the composite is -105.9 dB at a CrN particle size of 5 nm, and the effective absorption bandwidth is 7.68 GHz (complete Ku-band coverage) at 3.0 mm. This work overcomes the limitations of impedance matching imbalance and magnetic loss deficiency in carbon-based materials through size tuning, and opens a new way to obtain carbon-based composites with ultra-high attenuation capability.

Self-Assembled MoS2 Cladding for Corrosion Resistant and Frequency-Modulated Electromagnetic Wave Absorption Materials from X-Band to Ku-Band.

Reasonable composition design and controllable structure are effective strategies for harmonic electromagnetic wave (EMW) adsorption of multi-component composites. On this basis, the hybrid MoS2 /CoS2 /VN multilayer structure with the triple heterogeneous interface is prepared by simple stirring hydrothermal, which can satisfy the synergistic interaction between different components and obtain excellent EMW absorption performance. Due to the presence of multiple heterogeneous interfaces, MoS2 /CoS2 /VN composites will produce strong interfacial polarization, while the defects in the sample will become the center of polarization, resulting in dipole polarization. Due to the excellent structural design of MoS2 /CoS2 /VN composite material, MoS2 /CoS2 /VN composite material not only has good conductive loss and polarization loss, but also can maintain excellent stability in simulated seawater, and enhance corrosion resistance. The MoS2 /CoS2 /VN composite with dual functions of corrosion resistant and microwave absorption achieves a minimum reflection loss (RL) of -50.48 dB and an effective absorption bandwidth of up to 5.76 GHz, covering both the X-band and Ku-band. Finally, this study provides a strong reference for the development of EMW absorption materials based on transition metal nitrides.

Multishelled Metal Oxide Hollow Spheres: Easy Synthesis and Formation Mechanism.

Uniform multishelled NiO, Co3 O4 , ZnO, and Au@NiO hollow spheres were synthesized (NiO and Co3 O4 hollow spheres for the first time) by a simple shell-by-shell self-assembly allowing for tuning of the the size, thickness and shell numbers by controlling the heat treatment, glucose/metal salt molar ratio, and hydrothermal reaction time. These findings further the development of synthetic methodologies for multishelled hollow structures and could open up new opportunities for deeper understanding of the mechanisms of shell-by-shell self-assembly. Moreover, the double-shelled NiO hollow sphere exhibits a higher photocatalytic activity for degradation of methyl orange than its morphological counterparts.

Event-triggered aperiodic intermittent control for linear time-varying systems.

This paper considers the aperiodic intermittent control (AIC) for linear time-varying systems (LTVSs), where the occurrence instants are determined by an event triggering mechanism based on Lyapunov functions. For LTVSs, most of the existing results are demanded that the feedback controls are exerted all the time. In fact, in many practical applications, the applied controls are unnecessary/impossible to be imposed all the time. Therefore, the event-triggered AIC is introduced in this paper for LTVSs, and the uniformly stability, globally asymptotic stability and finite-time stability are proposed for LTVSs with event-triggered AIC, respectively. In addition, by using the piecewise constant feedback control method, effective intermittent controllers are designed for LTVSs. Finally, we present two numerical examples to illustrate the efficacy of the derived results.

Optimal particle distribution induced interfacial polarization in hollow double-shell composites for electromagnetic waves absorption performance.

Tunable designs of polymorphic structured transition metal dichalcogenide (TMDC) demonstrate promising applications in the field of electromagnetic wave absorption (EMW). However, it remains a technical challenge for achieving a balanced relationship between well-matched impedance characteristics and dielectric losses. Therefore, the co-modification strategies of polydopamine coating and wet impregnation are chosen to construct CoS2 magnetic double-shell microspheres with phase component modulation to achieve the optimized performance. Dopamine hydrochloride forms a coating on the surface of CoS2 microspheres by self-polymerization and forms a double-shell structure during the pyrolysis process. Then the different metal is doped to generate heterogeneous components in the process of heat treatment. The results show that the cobalt doped double-shell microspheres have an ultra-high electromagnetic wave absorption absorption capacity with an effective absorption bandwidth of 5.04 GHz (1.98 mm) and a minimum reflection loss value of -48.90 dB. The double-shell layer structure and metal ion hybridization can improve the interfacial polarization and magnetic loss behavior, which provides an explicit inspiration for the development of transition metal dichalcogenide and even transition metal compounds with tunable absorption properties.

Simultaneous manipulation of polarization relaxation and conductivity toward self-repairing reduced graphene oxide based ternary hybrids for efficient electromagnetic wave absorption.

In consideration of the growing electromagnetic wave (EMW) pollution and interference, it is of crucial and imperative significance to develop high-efficiency EMW absorption materials. Herein, hierarchical hybrid network of MoS2@poly (3, 4-ethylenedioxythiophene) (PEDOT)/reduced graphene oxide (rGO) were successfully constructed and fabricated through the combination of oxidative polymerization and microwave-irradiated thermal reduction. The original defects in graphene oxide (GO) could be in situ repaired by introducing carbon source, and the rational regulation of polarization relaxation and conductivity of composites could be achieved. Profiting from the good impedance matching, ameliorated conductivity and enhanced dipole polarization as well as interfacial polarization by introducing GO/defect-recovered rGO and conductive PEDOT, both the MoS2@PEDOT/GO and MoS2@PEDOT/rGO composites exhibited outstanding EMW absorption performances. In details, the minimum reflection loss (RLmin) and effective absorption bandwidth (EAB) of MoS2@PEDOT/GO can reach -48.65 dB at 4.5 mm, and 6.48 GHz (11.52-18 GHz) at 2.2 mm, respectively. And the EAB of MoS2@PEDOT/rGO can reach 7.04 GHz (10.8-17.84 GHz) with an optimized RLmin of -32.41 dB at 2.1 mm under 20 wt% filler loading. Therefore, these composites can be regarded as competitive candidates for lightweight and high-efficient EMW absorbers.

Controlled formation of multiple core-shell structures in metal-organic frame materials for efficient microwave absorption.

The design of metal-organic frameworks (MOF) derived composites with multiple loss mechanisms and multi-scale micro/nano structures is an important research direction of microwave absorbing materials. Herein, multi-scale bayberry-like Ni-MOF@N-doped carbon composites (Ni-MOF@NC) are obtained by a MOF assisted strategy. By utilizing the special structure of MOF and regulating its composition, the effective improvement of Ni-MOF@NC's microwave absorption performance has been achieved. The nanostructure on the surface of core-shell Ni-MOF@NC can be regulated and N doping on carbon skeleton by adjusting the annealing temperature. The optimal reflection loss of Ni-MOF@NC is -69.6 dB at 3 mm, and the widest effective absorption bandwidth is 6.8 GHz. This excellent performance can be attributed to the strong interface polarization caused by multiple core-shell structures, the defect and dipole polarization caused by N doping, and the magnetic loss caused by Ni. Meanwhile, the coupling of magnetic and dielectric properties enhances the impedance matching of Ni-MOF@NC. The work proposes a particular idea of designing and synthesizing an applicable microwave absorption material that possesses excellent microwave absorption performance and promising application potential.

Construction of Self-Assembly Based Tunable Absorber: Lightweight, Hydrophobic and Self-Cleaning Properties.

Although multifunctional aerogels are expected to be used in applications such as portable electronic devices, it is still a great challenge to confer multifunctionality to aerogels while maintaining their inherent microstructure. Herein, a simple method is proposed to prepare multifunctional NiCo/C aerogels with excellent electromagnetic wave absorption properties, superhydrophobicity, and self-cleaning by water-induced NiCo-MOF self-assembly. Specifically, the impedance matching of the three-dimensional (3D) structure and the interfacial polarization provided by CoNi/C as well as the defect-induced dipole polarization are the primary contributors to the broadband absorption. As a result, the prepared NiCo/C aerogels have a broadband width of 6.22 GHz at 1.9 mm. Due to the presence of hydrophobic functional groups, CoNi/C aerogels improve the stability in humid environments and obtain hydrophobicity with large contact angles > 140°. This multifunctional aerogel has promising applications in electromagnetic wave absorption, resistance to water or humid environments.

Multiphase Interfacial Regulation Based on Hierarchical Porous Molybdenum Selenide to Build Anticorrosive and Multiband Tailorable Absorbers.

Electromagnetic wave (EMW) absorbing materials have an irreplaceable position in the field of military stealth as well as in the field of electromagnetic pollution control. And in order to cope with the complex electromagnetic environment, the design of multifunctional and multiband high efficiency EMW absorbers remains a tremendous challenge. In this work, we designed a three-dimensional porous structure via the salt melt synthesis strategy to optimize the impedance matching of the absorber. Also, through interfacial engineering, a molybdenum carbide transition layer was introduced between the molybdenum selenide nanoparticles and the three-dimensional porous carbon matrix to improve the absorption behavior of the absorber. The analysis indicates that the number and components of the heterogeneous interfaces have a significant impact on the EMW absorption performance of the absorber due to mechanisms such as interfacial polarization and conduction loss introduced by interfacial engineering. Wherein, the prepared MoSe2/MoC/PNC composites showed excellent EMW absorption performance in C, X, and Ku bands, especially exhibiting a reflection loss of - 59.09 dB and an effective absorption bandwidth of 6.96 GHz at 1.9 mm. The coordination between structure and components endows the absorber with strong absorption, broad bandwidth, thin thickness, and multi-frequency absorption characteristics. Remarkably, it can effectively reinforce the marine anticorrosion property of the epoxy resin coating on Q235 steel substrate. This study contributes to a deeper understanding of the relationship between interfacial engineering and the performance of EMW absorbers, and provides a reference for the design of multifunctional, multiband EMW absorption materials.

Integration of Multiple Heterointerfaces in a Hierarchical 0D@2D@1D Structure for Lightweight, Flexible, and Hydrophobic Multifunctional Electromagnetic Protective Fabrics.

The development of wearable multifunctional electromagnetic protective fabrics with multifunctional, low cost, and high efficiency remains a challenge. Here, inspired by the unique flower branch shape of "Thunberg's meadowsweet" in nature, a nanofibrous composite membrane with hierarchical structure was constructed. Integrating sophisticated 0D@2D@1D hierarchical structures with multiple heterointerfaces can fully unleash the multifunctional application potential of composite membrane. The targeted induction method was used to precisely regulate the formation site and morphology of the metal-organic framework precursor, and intelligently integrate multiple heterostructures to enhance dielectric polarization, which improves the impedance matching and loss mechanisms of the electromagnetic wave absorbing materials. Due to the synergistic enhancement of electrospinning-derived carbon nanofiber "stems", MOF-derived carbon nanosheet "petals" and transition metal selenide nano-particle "stamens", the CoxSey/NiSe@CNSs@CNFs (CNCC) composite membrane obtains a minimum reflection loss value (RLmin) of -68.40 dB at 2.6 mm and a maximum effective absorption bandwidth (EAB) of 8.88 GHz at a thin thickness of 2.0 mm with a filling amount of only 5 wt%. In addition, the multi-component and hierarchical heterostructure endow the fibrous membrane with excellent flexibility, water resistance, thermal management, and other multifunctional properties. This work provides unique perspectives for the precise design and rational application of multifunctional fabrics.

Impact mechanisms of aggregation state regulation strategies on the microwave absorption properties of flexible polyaniline.

In the field of electromagnetic (EM) wave absorption, intrinsic conductive polymers with conjugated long-chain structures, such as polyaniline (PANI) and polypyrrole (PPy), have gained widespread use due to their remarkable electrical conductivity and loss ability. However, current research in this area is limited to macroscopic descriptions of the absorption properties of these materials and the contribution of various components to the absorption effect. There has been insufficient exploration of the impact mechanisms of polymer aggregation states on the material's absorption performance and mechanism. To address this, a series of flexible PANI sponge absorbers with different molecular weights and aggregation states were prepared. By carefully controlling the crystallinity and other aggregation characteristics of PANI through the adjustment of its preparation conditions, we were able to influence its electrical conductivity and electromagnetic parameters, thereby achieving control over the material's absorption properties. The resulting PANI sponge absorbers exhibited an effective absorption bandwidth (EAB) that covered the entire X-band at a thickness of 3.2 mm. This study comprehensively explores the absorption mechanisms of conductive polymer absorbers, starting from the microstructure of PANI, and providing a more complete theoretical support for the research and promotion of polymer absorbers.

Staggered circular nanoporous graphene converts electromagnetic waves into electricity.

Harvesting largely ignored and wasted electromagnetic (EM) energy released by electronic devices and converting it into direct current (DC) electricity is an attractive strategy not only to reduce EM pollution but also address the ever-increasing energy crisis. Here we report the synthesis of nanoparticle-templated graphene with monodisperse and staggered circular nanopores enabling an EM-heat-DC conversion pathway. We experimentally and theoretically demonstrate that this staggered nanoporous structure alters graphene's electronic and phononic properties by synergistically manipulating its intralayer nanostructures and interlayer interactions. The staggered circular nanoporous graphene exhibits an anomalous combination of properties, which lead to an efficient absorption and conversion of EM waves into heat and in turn an output of DC electricity through the thermoelectric effect. Overall, our results advance the fundamental understanding of the structure-property relationships of ordered nanoporous graphene, providing an effective strategy to reduce EM pollution and generate electric energy.

Multicomponent Nanoparticles Synergistic One-Dimensional Nanofibers as Heterostructure Absorbers for Tunable and Efficient Microwave Absorption.

Application of novel radio technologies and equipment inevitably leads to electromagnetic pollution. One-dimensional polymer-based composite membrane structures have been shown to be an effective strategy to obtain high-performance microwave absorbers. Herein, we reported a one-dimensional N-doped carbon nanofibers material which encapsulated the hollow Co3SnC0.7 nanocubes in the fiber lumen by electrospinning. Space charge stacking formed between nanoparticles can be channeled by longitudinal fibrous structures. The dielectric constant of the fibers is highly related to the carbonization temperature, and the great impedance matching can be achieved by synergetic effect between Co3SnC0.7 and carbon network. At 800 °C, the necklace-like Co3SnC0.7/CNF with 5% low load achieves an excellent RL value of - 51.2 dB at 2.3 mm and the effective absorption bandwidth of 7.44 GHz with matching thickness of 2.5 mm. The multiple electromagnetic wave (EMW) reflections and interfacial polarization between the fibers and the fibers internal contribute a major effect to attenuating the EMW. These strategies for regulating electromagnetic performance can be expanded to other electromagnetic functional materials which facilitate the development of emerging absorbers.

Interconnected magnetic carbon@NixCo1-xFe2O4 nanospheres with core-shell structure: An efficient and thin electromagnetic wave absorber.

The applications of cobalt ferrite and nickel ferrite composite materials on electromagnetic (EM) wave absorption are the research hotspot currently. However, the systematical comparison study between these two ferrites composites have rarely been carried out. Thus, the EM wave absorption performance of interconnected carbon@NixCo1-xFe2O4 composites with core-shell structures were investigated comprehensively in this work. A series of magnetic nanospheres including NiFe2O4, cobalt-doped nickel ferrite, nickel-cobalt ferrite, nickel-doped cobalt ferrite and CoFe2O4 were synthesized firstly, and then uniformly encapsulation by carbon rendered the corresponding C@NixCo1-xFe2O4 composites nanospheres. Synthesis reactions involved for C@NixCo1-xFe2O4 formation were investigated in detail, and afterwards their magnetic behavior, EM wave absorption performance and absorbing mechanism were thoroughly explored and analyzed. Results show that when nickel is dominant element and cobalt is doping element (Ni0.75Co0.25Fe2O4), the composite nanosphere exhibits optimum EM wave absorption performance. When the sample thickness is just 1.9 mm, its RLmin value can reach -51 dB, and the corresponding EAB width is 3.3 GHz. The synthesized C@Ni0.75Co0.25Fe2O4 can be qualified as an efficient and thin electromagnetic wave absorber, which is mainly attributed to its special structure, fair electromagnetic matching and impedance matching.

The Investigation of the Effect of Filler Sizes in 3D-BN Skeletons on Thermal Conductivity of Epoxy-Based Composites.

Thermally conductive and electrically insulating materials have attracted much attention due to their applications in the field of microelectronics, but through-plane thermal conductivity of materials is still low at present. In this paper, a simple and environmentally friendly strategy is proposed to improve the through-plane thermal conductivity of epoxy composites using a 3D boron nitride (3D-BN) framework. In addition, the effect of filler sizes in 3D-BN skeletons on thermal conductivity was investigated. The epoxy composite with larger BN in lateral size showed a higher through-plane thermal conductivity of 2.01 W/m·K and maintained a low dielectric constant of 3.7 and a dielectric loss of 0.006 at 50 Hz, making it desirable for the application in microelectronic devices.

MOF-derived NiFe2S4/Porous carbon composites as electromagnetic wave absorber.

The preparation of strong absorption, thin thickness and wide band electromagnetic wave absorbers has always been the focus of research. In this paper, NiFe2S4/PC composites, an electromagnetic wave absorbing material with excellent performance, is prepared by introducing Ni-MOF, Fe and S elements into porous carbon framework. The material has a minimum reflection loss (RLmin) of -51.41 dB and the matching thickness is only 1.8 mm. In addition, the effective absorption bandwidth (EAB) is 4.08 GHz when the thickness is 1.9 mm. The rich interface and good impedance matching characteristics are the main reasons for the excellent absorbing performance of the material. The experimental results show that NiFe2S4/PC composites is a reasonable and effective electromagnetic wave absorption material.

One-dimensional Ni@Co/C@PPy composites for superior electromagnetic wave absorption.

The conductive networks for electron hopping and migration constructed by one-dimensional (1D) composite absorbers are highly desirable to improve the electromagnetic (EM) wave attenuation capacity. Herein, the Ni@Co/C@polypyrrole (PPy) composites integrating the advantages of component and microstructure were fabricated. The addition of Co/C and PPy effectively optimized the impedance matching and improved the EM attenuation. Under the comprehensive impacts of multiple reflections/scattering, conduction loss and interface polarization, the Ni@Co/C@PPy composites showed superior EM wave absorption with the reflection loss (RL) value of -48.76 dB and the effective absorption bandwidth (EAB) of 5.10 GHz at a corresponding thickness of 2.0 mm. The largest EAB could reach 5.54 GHz (7.24-12.78 GHz) at the thickness of 2.2 mm. This work provides a great reference for fabricating 1D novel EM wave absorption materials.

Spray drying induced engineering a hierarchical reduced graphene oxide supported heterogeneous Tin dioxide and Zinc oxide for Lithium-ion storage.

In this work, a hierarchical reduced graphene oxide (RGO) supportive matrix consisting of both larger two-dimensional RGO sheets and smaller three-dimensional RGO spheres was engineered with ZnO and SnO2 nanoparticles immobilized. The ZnO and SnO2 nanocrystals with controlled size were in sequence engineered on the surface of the RGO sheets during the deoxygenation of graphene oxide sample (GO), where the zinc-containing ZIF-8 sample and metal tin foil were used as precursors for ZnO and SnO2, respectively. After a spray drying treatment and calcination, the final ZnO@SnO2/RGO-H sample was obtained, which delivered an outstanding specific capacity of 982 mAh·g-1 under a high current density of 1000 mA·g-1 after 450 cycles. Benefitting from the unique hierarchical structure, the mechanical strength, ionic and electric conductivities of the ZnO@SnO2/RGO-H sample have been simultaneously promoted. The joint contributions from pseudocapacitive and battery behaviors in lithium-ion storage processes bring in both large specific capacity and good rate capability. The industrially mature spray drying method for synthesizing RGO based hierarchical products can be further developed for wider applications.