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1.
Small ; 20(21): e2309112, 2024 May.
Artículo en Inglés | MEDLINE | ID: mdl-38150610

RESUMEN

A sulfur vacancy-rich, Sn-doped as well as carbon-coated MoS2 composite (Vs-SMS@C) is rationally synthesized via a simple hydrothermal method combined with ball-milling reduction, which enhances the sodium storage performance. Benefiting from the 3D fast Na+ transport network composed of the defective carbon coating, Mo─S─C bonds, enlarged interlayer spacing, S-vacancies, and lattice distortion in the composite, the Na+ storage kinetics is significantly accelerated. As expected, Vs-SMS@C releases an ultrahigh reversible capacity of 1089 mAh g-1 at 0.1 A g-1, higher than the theoretical capacity. It delivers a satisfactory capacity of 463 mAh g-1 at a high current density of 10 A g-1, which is the state-of-the-art rate capability compared to other MoS2 based sodium ion battery anodes to the knowledge. Moreover, a super long-term cycle stability is achieved by Vs-SMS@C, which keeps 91.6% of the initial capacity after 3000 cycles under the current density of 5 A g-1 in the voltage of 0.3-3.0 V. The sodium storage mechanism of Vs-SMS@C is investigated by employing electrochemical methods and ex situ techniques. The synergistic effect between S-vacancies and doped-Sn is evidenced by DFT calculations. This work opens new ideas for seeking excellent metal sulfide anodes.

2.
Int J Mol Sci ; 25(6)2024 Mar 18.
Artículo en Inglés | MEDLINE | ID: mdl-38542386

RESUMEN

The extracellular matrix (ECM) within the brain possesses a distinctive composition and functionality, influencing a spectrum of physiological and pathological states. Among its constituents, perineuronal nets (PNNs) are unique ECM structures that wrap around the cell body of many neurons and extend along their dendrites within the central nervous system (CNS). PNNs are pivotal regulators of plasticity in CNS, both during development and adulthood stages. Characterized by their condensed glycosaminoglycan-rich structures and heterogeneous molecular composition, PNNs not only offer neuroprotection but also participate in signal transduction, orchestrating neuronal activity and plasticity. Interfering with the PNNs in adult animals induces the reactivation of critical period plasticity, permitting modifications in neuronal connections and promoting the recovery of neuroplasticity following spinal cord damage. Interestingly, in the adult brain, PNN expression is dynamic, potentially modulating plasticity-associated states. Given their multifaceted roles, PNNs have emerged as regulators in the domains of learning, memory, addiction behaviors, and other neuropsychiatric disorders. In this review, we aimed to address how PNNs contribute to the memory processes in physiological and pathological conditions.


Asunto(s)
Encéfalo , Sistema Nervioso Central , Animales , Sistema Nervioso Central/fisiología , Encéfalo/metabolismo , Neuronas/metabolismo , Memoria/fisiología , Matriz Extracelular/metabolismo , Plasticidad Neuronal/fisiología
3.
Small ; 19(47): e2303963, 2023 Nov.
Artículo en Inglés | MEDLINE | ID: mdl-37488694

RESUMEN

Aqueous Zn-ion batteries (AZIBs) attract intensive attention owing to their environmental friendliness, cost-effectiveness, innate safety, and high specific capacity. However, the practical applications of AZIBs are hindered by several adverse phenomena, including corrosion, Zn dendrites, and hydrogen evolution. Herein, a Zn anode decorated with a 3D porous-structured Na3 V2 (PO4)3 (NVP@Zn) is obtained, where the NVP reconstruct the electrolyte/anode interface. The resulting NVP@Zn anode can provide a large quantity of fast and stable channels, facilitating enhanced Zn ion deposition kinetics and regulating the Zn ions transport process through the ion confinement effect. The NASICON-type NVP protective layer promote the desolvation process due to its nanopore structure, thus effectively avoiding side reactions. Theoretical calculations indicate that the NVP@Zn electrode has a higher Zn ion binding energy and a higher migration barrier, which demonstrates that NVP protective layer can enhance Zn ion deposition kinetics and prevent the unfettered 2D diffusion of Zn ions. Therefore, the results show that NVP@Zn/MnO2 full cell can maintain a high specific discharge capacity of 168 mAh g-1 and a high-capacity retention rate of 74.6% after cycling. The extraordinary results obtained with this strategy have confirmed the promising applications of NVP in high-performance AZIBs.

4.
Langmuir ; 2023 Jan 10.
Artículo en Inglés | MEDLINE | ID: mdl-36628490

RESUMEN

Facilitation of the photocarrier separation is a crucial strategy for developing highly efficient photocatalysts in eliminating environmental pollutants. Herein we have developed a new kind of Ag2MoO4/ZnWO4 (AMO/ZWO) composite photocatalysts with a Z-scheme mechanism by anchoring AMO nanoparticles onto ZWO nanorods. Multiple characterization methodologies and density functional theory (DFT) calculations were employed to study the performances of the AMO/ZWO heterojunctions as well as the underlying photocatalytic mechanism. Simulated-sunlight-driven photodegradation experiments for removing methylene blue (MB) demonstrates that the 8%AMO/ZWO heterojunction can photocatalytically remove 99.8% of MB within 60 min, and the reaction rate constant is obtained as 0.10199 min-1, which is enhanced by 6.8 (or 4.9) times when compared with that of pure ZWO (or AMO). On the base of the experimental results and DFT calculations, the enhanced photocatalytic mechanism of the AMO/ZWO heterojunctions was revealed to be the efficient separation of photocarriers via a Z-scheme transfer process. In addition, photodegradion of various organic pollutants over 8%AMO/ZWO was further compared and aimed at incorporating it into industrial application in pollutant removal.

5.
Phys Chem Chem Phys ; 25(12): 8583-8591, 2023 Mar 22.
Artículo en Inglés | MEDLINE | ID: mdl-36883940

RESUMEN

In order to improve the performance of optical fiber sensing and expand its application, a photonic crystal fiber (PCF) plasmonic sensor with a U-shaped channel based on surface plasmon resonance (SPR) is proposed. We have studied the general influence rules of structural parameters such as the radius of the air hole, the thickness of the gold film and the number of U-shaped channels using COMSOL based on the finite element method. The dispersion curves and loss spectrum of the surface plasmon polariton (SPP) mode and the Y-polarization (Y-pol) mode as well as the distribution of the electric field intensity (normE) under various conditions are studied using the coupled mode theory. The maximum refractive index (RI) sensitivity achieved in the RI range of 1.38-1.43 is 24.1 µm RIU-1, which corresponds to a full width at half maximum (FWHM) of 10.0 nm, a figure of merit (FOM) of 2410 RIU-1 and a resolution of 4.15 × 10-6 RIU. The results show that the proposed sensor combines the SPR effect, which is extremely sensitive to changes in the RI of the surrounding medium and realizes real-time detection of the external environment by analyzing the light signal modulated by the sensor. In addition, the detection range and sensitivity can be extended by adjusting the structural parameters. The proposed sensor has a simple structure with excellent sensing performance, which provides a new idea and implementation method for real-time detection, long-range measurement, complex environment monitoring and highly integrated sensing, and has a strong potential practical value.

6.
Phys Chem Chem Phys ; 25(29): 19596-19605, 2023 Jul 26.
Artículo en Inglés | MEDLINE | ID: mdl-37435700

RESUMEN

To further reduce the fabrication difficulty of optical fiber sensors and improve the sensing performance, this study introduced the surface plasmon resonance (SPR) effect into optical fiber sensing technology and designed an eccentric-core photonic crystal fiber (EC-PCF). We investigated the characteristics of the two fundamental modes in the fiber core and the surface plasmon polariton (SPP) modes on the surface of the gold film. We also investigated the influence of the structural parameters, such as gold film coating area and thickness, air hole diameter, and eccentricity, on the confinement loss and achieved a refractive index (RI) sensitivity of 31.25 µm RIU-1 in the RI range of 1.29-1.43, corresponding to a figure of merit (FOM) of 521.6 per RIU. When the resolution of the optical spectrum analyzer was 0.1 nm, the EC-PCF could achieve a refractive index resolution of 3.2 × 10-6 RIU. Moreover, we performed tests with two typical sensing types, one in which the sensor was directly in contact with adulterated gasoline to achieve kerosene-concentration detection, and another in which the sensor was coated with a layer of polydimethylsiloxane (PDMS), whose RI is sensitive to the temperature field, to achieve temperature sensing. The EC-PCF demonstrated excellent sensing performance and offers obvious manufacturing advantages, providing a new and easily fabricated structural design idea for optical fiber sensing.

7.
Phys Chem Chem Phys ; 25(12): 8489-8496, 2023 Mar 22.
Artículo en Inglés | MEDLINE | ID: mdl-36883439

RESUMEN

With the development of science and technology, intermediate infrared technology has gained more and more attention in recent years. In the research described in this paper, a tunable broadband absorber based on a Dirac semimetal with a layered resonant structure was designed, which could achieve high absorption (more than 0.9) of about 8.7 THz in the frequency range of 18-28 THz. It was confirmed that the high absorption of the absorber comes from the strong resonance absorption between the layers, and the resonance of the localised surface plasmon. The absorber has a gold substrate, which is composed of three layers of Dirac semimetal and three layers of optical crystal plates. In addition, the resonance frequency of the absorber can be changed by adjusting the Fermi energy of the Dirac semimetal. The absorber also shows excellent characteristics such as tunability, absorption stability at different polarisation waves and incident angles, and has a high application value for use in radar countermeasures, biotechnology and other fields.

8.
J Opt Soc Am A Opt Image Sci Vis ; 40(1): 35-44, 2023 Jan 01.
Artículo en Inglés | MEDLINE | ID: mdl-36607073

RESUMEN

Surface plasmon resonance (SPR) is widely used in photonic crystal fiber sensors. In this work, a photonic crystal fiber sensor based on HE1,1 mode excited SPR is designed and analyzed by the finite element method. The maximum wavelength sensitivity, optimal resolution, and amplitude sensitivity of the optical fiber sensor are 24,600 nm/RIU, 4.07×10-6RIU, and 1164.13RIU-1, respectively, for the refractive index range between 1.29 and 1.39. The sensor has excellent properties and wide application prospects in bimolecular and biochemical sensing, environmental monitoring, food safety, and other fields.


Asunto(s)
Óptica y Fotónica , Resonancia por Plasmón de Superficie , Refractometría , Fibras Ópticas , Fotones
9.
Angew Chem Int Ed Engl ; 62(45): e202311196, 2023 Nov 06.
Artículo en Inglés | MEDLINE | ID: mdl-37721394

RESUMEN

Alanine is widely employed for synthesizing polymers, pharmaceuticals, and agrochemicals. Electrocatalytic coupling of biomass molecules and waste nitrate is attractive for the nitrate removal and alanine production under ambient conditions. However, the reaction efficiency is relatively low due to the activation of the stable substrates, and the coupling of two reactive intermediates remains challenging. Herein, we realize the integrated tandem electrochemical-chemical-electochemical synthesis of alanine from the biomass-derived pyruvic acid (PA) and waste nitrate (NO3 - ) catalyzed by PdCu nano-bead-wires (PdCu NBWs). The overall reaction pathway is demonstrated as a multiple-step catalytic cascade process via coupling the reactive intermediates NH2 OH and PA on the catalyst surface. Interestingly, in this integrated tandem electrochemical-chemical-electrochemical catalytic cascade process, Cu facilitates the electrochemical reduction of nitrate to NH2 OH intermediates, which chemically couple with PA to form the pyruvic oxime, and Pd promotes the electrochemical reduction of pyruvic oxime to the desirable alanine. This work provides a green strategy to convert waste NO3 - to wealth and enriches the substrate scope of renewable biomass feedstocks to produce high-value amino acids.

10.
Phys Chem Chem Phys ; 24(14): 8279-8295, 2022 Apr 06.
Artículo en Inglés | MEDLINE | ID: mdl-35319037

RESUMEN

In this study, we have adopted a one-step hydrothermal route to synthesize an interesting type of Bi2O2CO3 hierarchical nanotubes self-assembled from ordered nanosheets. The effects of reaction time on the morphological and structural evolution, light absorption properties, photoelectrochemical performance, and photocatalytic performance of the prepared hierarchical nanotubes were investigated. Among the products synthesized at different reaction times, the 3-hour-derived Bi2O2CO3 hierarchical nanotubes were identified to possess the highest photocatalytic performance. To promote the photocatalytic application of the as-synthesized Bi2O2CO3 hierarchical nanotubes, their performance was systematically evaluated via the photodegradation of various organic pollutants (e.g., methyl orange (MO), rhodamine B (RhB), methylene blue (MB), ciprofloxacin (CIP), sulfamethoxazole (SMX) and tetracycline hydrochloride (TC)) and the photoreduction of Cr(VI) under simulated-sunlight irradiation. Furthermore, their photocatalytic performance was also evaluated by purifying simulated industrial wastewater (i.e., a MO/RhB/MB mixed solution) at different pH values and containing different inorganic anions. Based on the experimental data and density functional theory (DFT) calculations, the involved photocatalytic mechanism was discussed.

11.
Phys Chem Chem Phys ; 24(8): 4871-4880, 2022 Feb 23.
Artículo en Inglés | MEDLINE | ID: mdl-35136890

RESUMEN

In this work, we demonstrate that the performance of c-Si/ZnO heterojunction ultrathin-film solar cells (SCs) is enhanced by an integrated structure of c-Si trapezoidal pyramids on the top of a c-Si active layer and Al pyramids in the active layer on the Al back electrode. The top c-Si trapezoidal pyramid (TTP) increases the absorption of short wavelengths by lengthening the propagation distance of incident light and coupling the incident light into photonic modes in the active layer. The bottom Al pyramid (BP) improves the overall optical absorption performance especially for the long wavelength band by forming the surface plasmon resonance (SPR) mode in the active layer. As a result, the average absorption in the entire wavelength range (300-1400 nm) reaches 93.16%. The optimized short-circuit current density (Jsc) and photoelectric conversion efficiency (PCE) of ultra-thin film c-Si/ZnO SCs are 41.94 mA cm-2 and 18.97%, respectively. Moreover, the effect of different illumination angles on the optical absorption of the SCs was explored. The SCs have good absorption when the incident angles are in the range from 0 degrees to 60 degrees. Furthermore, the underlying mechanism for the enhancement of photon absorption in the SCs was discussed through careful analysis of the electric field intensity profile at different wavelengths. It was found that the electric field tends to concentrate around the bottom pyramids and top trapezoidal pyramids even for the long-wave band, which results in an excellent light-trapping performance.

12.
Phys Chem Chem Phys ; 24(4): 2527-2533, 2022 Jan 26.
Artículo en Inglés | MEDLINE | ID: mdl-35023523

RESUMEN

Terahertz functional devices have been instrumental in the development of terahertz technology. Moreover, the advent of metamaterials has greatly contributed to the advancement of terahertz devices. However, most of today's metamaterials in the terahertz band exhibit poor performance and are mono-functional. This greatly limits the scalability and application potential of the devices. To achieve diversification and tunability of device functionality, we propose a combination of metamaterial structures and vanadium dioxide film. A metamaterial absorber based on the thermotropic phase change material VO2 has been designed. Flexible switching of absorption performance (complete reflection and ultra-broadband perfect absorption) can be achieved through temperature adjustment. Moreover, the perfectly absorbed bandwidth is a staggering 3.3 THz. The thermal tuning of spectral absorbance has a maximal range of 0.01 to 0.999. The shift in absorption properties is explained by the phase change process of vanadium oxide (MIT). The electric field intensity on the absorber surface at different temperatures was monitored and analysed as a way to correlate the VO2 film phase transition process. The impedance matching theory is applied to explain the high level of absorption generated by the absorber. Finally, the effects of the structural parameters on the performance of the absorber are analysed. This work will have many applications in the terahertz field and offers a wide range of ideas for the design of terahertz-enabled devices.

13.
Phys Chem Chem Phys ; 24(15): 8846-8853, 2022 Apr 13.
Artículo en Inglés | MEDLINE | ID: mdl-35356962

RESUMEN

We present a novel, structurally simple, multifunctional broadband absorber. It consists of a patterned vanadium dioxide film and a metal plate spaced by a dielectric layer. Temperature control allows flexible adjustment of the absorption intensity from 0 to 0.999. The modulation mechanism of the absorber stems from the thermogenic phase change properties of the vanadium dioxide material. The absorber achieves total reflection properties in the terahertz band when the vanadium dioxide is in the insulated state. When the vanadium dioxide is in its metallic state, the absorber achieves near-perfect absorption in the ultra-broadband range of 3.7 THz-9.7 THz. Impedance matching theory and the analysis of electric field are also used to illustrate the mechanism of operation. Compared to previous reports, our structure utilizes just a single cell structure (3 layers only), and it is easy to process and manufacture. The absorption rate and operating bandwidth of the absorber are also optimised. In addition, the absorber is not only insensitive to polarization, but also very tolerant to the angle of incidence. Such a design would have great potential in wide-ranging applications, including photochemical energy harvesting, stealth devices, thermal emitters, etc.

14.
Phys Chem Chem Phys ; 24(35): 21233-21241, 2022 Sep 14.
Artículo en Inglés | MEDLINE | ID: mdl-36040374

RESUMEN

In this paper, a dual-parameter sensor based on surface plasmon resonance (SPR)-photonic crystal fiber (PCF) is proposed, which can be applied in detecting the magnetic field and temperature. In this sensor, two elliptical channels are designed on both sides of the fiber core. The left channel (Ch 1) is coated with gold film and filled with magnetic fluid (MF) to achieve a response to the magnetic field and temperature using SPR. The right channel (Ch 2) is coated with gold film as well as Ta2O5 film to improve the SPR sensing performance. Finally, Ch 2 is filled with polydimethylsiloxane (PDMS) to achieve a response to the temperature. The mode characteristics, structural parameters and sensing performance are investigated by the finite element method. The results show that when the magnetic field is in the range of 50-130 Oe, the magnetic field sensitivities of Ch 1 and Ch 2 are 65 pm Oe-1 and 0 pm Oe-1, respectively. When the temperature is in the range of 17.5-27.5 °C, the temperature sensitivities of Ch 1 and Ch 2 are 520 pm °C-1 and 2360 pm °C-1, respectively. By establishing and demodulating a sensing matrix, the sensor can not only measure the temperature and magnetic field simultaneously but also solve the temperature cross-sensitivity problem. In addition, when the temperature exceeds a certain value, the proposed sensor is expected to achieve dual-parameter sensing without a matrix. The proposed dual-parameter SPR-PCF sensor has a unique structure and excellent sensing performance, which are important for the simultaneous sensing of multiple basic physical parameters.

15.
Bioelectromagnetics ; 43(2): 106-118, 2022 Feb.
Artículo en Inglés | MEDLINE | ID: mdl-35066900

RESUMEN

Numerous studies have shown that radiofrequency electromagnetic radiation (RF-EMR) may negatively affect human health. We detected the effect of 3500 MHz RF-EMR on anxiety-like behavior and the auditory cortex (ACx) in guinea pigs. Forty male guinea pigs were randomly divided into four groups and exposed to a continuous wave of 3500 MHz RF-EMF at an average specific absorption rate (SAR) of 0, 2, 4, or 10 W/kg for 72 h. After exposure, malondialdehyde (MDA) levels, antioxidant enzyme activity, anxiety-like behavior, hearing thresholds, cell ultrastructure, and apoptosis were detected. Our results revealed that hearing thresholds and basic indexes of animal behavior did not change significantly after exposure (P > 0.05). However, the MDA levels of ACx were increased (P < 0.05), and catalase (CAT), superoxide dismutase (SOD), and glutathione peroxidase (GSH-px) activities were decreased (P < 0.05) in the exposure groups compared to the sham group. Ultrastructural changes of ACx, including swollen mitochondria and layered myelin sheaths, were observed. Cytochrome-c relocalization, caspase-9, and cleaved caspase-3 activation were detected in the exposure groups. In conclusion, these results suggest that oxidative stress is an important mechanism underlying the biological effects of RF-EMR, which can induce ultrastructural damage to the ACx and cell apoptosis through a mitochondria-dependent mechanism. Moreover, oxidative stress, apoptosis induction and ultrastructural damage increase in a SAR-dependent manner. However, RF-EMR does not increase hearing thresholds or induce anxiety. Bioelectromagnetics. 43:106-118, 2022. © 2021 Bioelectromagnetics Society.


Asunto(s)
Corteza Auditiva , Teléfono Celular , Animales , Antioxidantes/metabolismo , Ansiedad/etiología , Corteza Auditiva/metabolismo , Campos Electromagnéticos/efectos adversos , Radiación Electromagnética , Cobayas , Masculino , Estrés Oxidativo
16.
Sensors (Basel) ; 22(17)2022 Aug 28.
Artículo en Inglés | MEDLINE | ID: mdl-36080942

RESUMEN

The paper proposes an ultra-narrow band graphene refractive index sensor, consisting of a patterned graphene layer on the top, a dielectric layer of SiO2 in the middle, and a bottom Au layer. The absorption sensor achieves the absorption efficiency of 99.41% and 99.22% at 5.664 THz and 8.062 THz, with the absorption bandwidths 0.0171 THz and 0.0152 THz, respectively. Compared with noble metal absorbers, our graphene absorber can achieve tunability by adjusting the Fermi level and relaxation time of the graphene layer with the geometry of the absorber unchanged, which greatly saves the manufacturing cost. The results show that the sensor has the properties of polarization-independence and large-angle insensitivity due to the symmetric structure. In addition, the practical application of testing the content of hemoglobin biomolecules was conducted, the frequency of first resonance mode shows a shift of 0.017 THz, and the second resonance mode has a shift of 0.016 THz, demonstrating the good frequency sensitivity of our sensor. The S (sensitivities) of the sensor were calculated at 875 GHz/RIU and 775 GHz/RIU, and quality factors FOM (Figure of Merit) are 26.51 and 18.90, respectively; and the minimum limit of detection is 0.04. By comparing with previous similar sensors, our sensor has better sensing performance, which can be applied to photon detection in the terahertz band, biochemical sensing, and other fields.


Asunto(s)
Grafito , Refractometría , Metales , Refracción Ocular , Dióxido de Silicio
17.
Phys Chem Chem Phys ; 23(31): 17041-17048, 2021 Aug 12.
Artículo en Inglés | MEDLINE | ID: mdl-34342321

RESUMEN

Solar energy absorption is a very important field in photonics. The successful development of an efficient, wide-band solar absorber is an extremely powerful driver in this field. We propose an ultra-wideband (UWB) solar energy absorber composed of a Ti ring and SiO2-Si3N4-Ti thin films. In the range of 300-4000 nm, the wide band has an absorption efficiency of more than 90% and can reach 3683 nm, and it has four absorption peaks with a high absorptivity. Moreover, the weighted average absorption efficiency of the solar absorber under AM 1.5 is maintained above 97.03%, which indicates it has great potential for use in the field of solar energy absorption. Moreover, we proved that the polarization is insensitive by analyzing the absorption characteristics at arbitrary polarization angles. For both the transverse electric (TE) and transverse magnetic (TM) modes, the UWB absorption is maintained at more than 90% in the wide incidence angle range of 60°. The UWB solar energy absorber has great potential for use in a variety of applications, such as converting solar light and heat into electricity for public use and reducing the side effects of coal-fired power generation. It can also be used in information detection and infrared thermal imaging owing to its UWB characteristics.

18.
Phys Chem Chem Phys ; 23(47): 26864-26873, 2021 Dec 08.
Artículo en Inglés | MEDLINE | ID: mdl-34821236

RESUMEN

A four-band terahertz tunable narrow-band perfect absorber based on a bulk Dirac semi-metallic (BDS) metamaterial with a microstructure is designed. The three-layer structure of this absorber from top to bottom is the Dirac semi-metallic layer, the dielectric layer and the metal reflector layer. Based on the Finite Element Method (FEM), we use the simulation software CST STUDIO SUITE to simulate the absorption characteristics of the designed absorber. The simulation results show that the absorption rate of the absorber is over 93% at frequencies of 1.22, 1.822, 2.148 and 2.476 THz, and three of them have achieved a perfect absorption rate of more than 95%. We use the localized surface plasmon resonance (LSPR), impedance matching and other theories to analyze its physical mechanism in detail. The influence of the geometric structure parameters of the absorber and the incident angle of electromagnetic waves on the absorption performance has also been studied in detail. Due to the rotational symmetry of the structure, the designed absorber has excellent polarization insensitivity. In addition, the maximum adjustable range of absorption frequency is 0.051 THz, which can be achieved by changing the Fermi energy of BDS. We also define the refractive index sensitivity (S), which is 39.1, 75.4, 119.1 and 122.0 GHz RIU-1 for the four absorption modes when the refractive index varies in the range of 1 to 1.9. This high-performance absorber has a very good development prospect in the frontier fields of bio-chemical sensing and special environmental detection.

19.
Angew Chem Int Ed Engl ; 60(51): 26718-26724, 2021 Dec 13.
Artículo en Inglés | MEDLINE | ID: mdl-34580969

RESUMEN

The uncontrollable dendrite growth of Li metal anode leads to poor cycle stability and safety concerns, hindering its utilization in high energy density batteries. Herein, a phenoxy radical Spiro-O8 is proposed as an artificial protection film for Li metal anode owing to its excellent film-forming capability and remarkable ionic conductivity. A spontaneous redox reaction between the Spiro-O8 and Li metal results in the formation of a uniform and highly ionic conductive organic film in the bottom. Meanwhile, the phenoxy radicals on surface of Spiro-O8 facilitate the decomposition of Li salt upon exposed to the ether electrolyte and lead the formation of LiF film on the top. Arising from the synergistic effects of inner high ionic conductive film and outer rigid film, stable Li plating/stripping can be realized at a high current density (4000 cycles at 10 mA cm-2 ) and a high areal capacity of 5 mAh cm-2 for 550 h with an ultrahigh Li utilization rate of 54.6 %. As a proof of concept, this work shows a facile strategy to rationally fabricate dual-layered interfaces for Li metal anodes.

20.
Mol Cell Probes ; 30(1): 1-5, 2016 Feb.
Artículo en Inglés | MEDLINE | ID: mdl-26746358

RESUMEN

A genome-wide association study has shown a number of chicken (Gallus gallus) single nucleotide polymorphism (SNP) markers to be significantly associated with abdominal fat content in Northeast Agricultural University (NEAU) broiler lines selected divergently for abdominal fat content (NEAUHLF). The six significant SNPs are located in the kinase insert domain receptor (KDR), tumor suppressor candidate 3 (TUSC3), phosphoribosyl pyrophosphate amidotransferase (PPAT), exocyst complex component 1 (EXOC1), v-myb myeloblastosis viral oncogene homolog (avian)-like 2 (MYBL2) and KIAA1211 (undefined) genes. In this study, the expression levels of these genes were investigated in both abdominal fat and liver tissues using 32 14th generation chickens from the NEAUHLF. The levels of expression of KDR in abdominal fat and KDR and TUSC3 in liver differed significantly between the two lines. The expression level of KDR in the abdominal fat was significantly correlated with the abdominal fat weight (AFW) and abdominal fat percentage (AFP). The expression levels of KDR, TUSC3 and PPAT in liver were significantly correlated with AFW and AFP, indicating that the six genes, especially KDR and TUSC3, could be associated with fat traits in domestic chickens. This study could provide insight into the mechanisms underlying the formation of abdominal fat in chickens.


Asunto(s)
Grasa Abdominal/metabolismo , Proteínas Aviares/genética , Pollos/genética , Perfilación de la Expresión Génica/veterinaria , Estudios de Asociación Genética/métodos , Estudios de Asociación Genética/veterinaria , Animales , Mapeo Cromosómico/veterinaria , Perfilación de la Expresión Génica/métodos , Frecuencia de los Genes , Genética de Población/métodos , Genotipo , Desequilibrio de Ligamiento , Tamaño de los Órganos/genética , Fenotipo , Polimorfismo de Nucleótido Simple
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