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The Nd-doped LaMgAl11O19 single crystals were synthesized by the floating zone method, and the photoluminescence and scintillation properties were evaluated. Under X-ray irradiation, several sharp emission peaks due to the 4f-4f transitions of Nd3+ were observed at 900, 1060, and 1340 nm in the near-infrared range, and the decay curves show the typical decay time for Nd3+. The samples show good afterglow properties comparable with practical X-ray scintillators. The 1% and 3% Nd-doped LaMgAl11O19 samples show a good linearity in the dynamic range from 6-60,000 mGy/h.
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Scintillation materials and detectors that are used in many applications, such as medical imaging, security, oil-logging, high energy physics and non-destructive inspection, are reviewed. The fundamental physics understood today is explained, and common scintillators and scintillation detectors are introduced. The properties explained here are light yield, energy non-proportionality, emission wavelength, energy resolution, decay time, effective atomic number and timing resolution. For further understanding, the emission mechanisms of scintillator materials are also introduced. Furthermore, unresolved problems in scintillation phenomenon are considered, and my recent interpretations are discussed. These topics include positive hysteresis, the co-doping of non-luminescent ions, the introduction of an aimed impurity phase, the excitation density effect and the complementary relationship between scintillators and storage phosphors.
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Conteo por Cintilación/métodos , Sustancias Luminiscentes/química , Mediciones Luminiscentes , Ensayo de Materiales , Fenómenos Físicos , Conteo por Cintilación/instrumentación , SemiconductoresRESUMEN
We fabricated nanosized KMgF3 single crystals via a dry pulsed laser ablation process using femtosecond laser pulses. The sizes, shapes, and crystallographic properties of the crystals were evaluated by transmission electron microscopy (TEM). Almost all of the particles were spherical with diameters of less than 100 nm, and they were not highly agglomerated. Selected-area electron diffraction and high-resolution TEM analyses showed that the particles were single crystals. Particle diameter was controlled within a wide range by adjusting the Ar ambient gas pressure. Under low gas pressures (1 and 10 Pa), relatively small particles (primarily 10 nm or less) were observed with a high number density. With increasing pressure, the mean diameter increased and the number density drastically decreased. Vacuum-ultraviolet cathodoluminescence was observed at 140-230 nm with blue shift and broadening of spectrum.
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The organic liquid scintillators based on the emissive polymers are reported. A series of conjugated polymers containing organoboron complexes which show the luminescence in the near infrared (NIR) region were synthesized. The polymers showed good solubility in common organic solvents. From the comparison of the luminescent properties of the synthesized polymers between optical and radiation excitation, similar emission bands were detected. In addition, less significant degradation was observed. These data propose that the organoboron conjugated polymers are attractive platforms to work as an organic liquid scintillator with the emission in the NIR region.
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Boro/química , Técnicas de Química Analítica/instrumentación , Técnicas de Química Analítica/métodos , Compuestos Organometálicos/química , Polímeros/química , Espectroscopía Infrarroja Corta , Luminiscencia , Compuestos Organometálicos/síntesis química , Compuestos Organometálicos/farmacología , Polímeros/síntesis química , Polímeros/farmacología , SolubilidadRESUMEN
A vacuum ultraviolet (VUV) field emission lamp was developed by using a neodymium ion doped lutetium fluoride (Nd(3+) : LuF3) thin film as solid-state phosphor and carbon nanofiber field electron emitters. The thin film was synthesized by pulsed laser deposition and incorporated into the lamp. The cathodoluminescence spectra of the lamp showed multiple emission peaks at 180, 225, and 255 nm. These emission spectra were in good agreement with the spectra reported for the Nd(3+) : LuF3 crystal. Moreover, application of an acceleration voltage effectively increased the emission intensity. These results contribute to the performance enhancement of the lamp operating in the VUV region.
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Electrones , Lutecio/química , Neodimio/química , Humanos , Mediciones Luminiscentes , Rayos UltravioletaRESUMEN
Eulytite-type Ba3RE(PO4)3 (RE = Y, La, and Lu) single crystals were synthesized by the floating zone method, and their scintillation properties were investigated. The powder X-ray diffraction measurement revealed that the single phase of Ba3RE(PO4)3 samples were successfully synthesized. The samples exhibited a luminescence peak due to self-trapped exciton at around 400 nm under vacuum ultraviolet and X-ray irradiation. The X-ray-induced scintillation decay time constants of the samples were several microseconds at room temperature. In the 241Am α-ray irradiated pulse height spectra, all the samples showed a clear full energy peak, and the absolute light yields of the Ba3Y(PO4)3, Ba3La(PO4)3, and Ba3Lu(PO4)3 single crystals were estimated to be 960, 1160, and 1220 ph/5.5 MeV-α, with a typical error of ±10%, respectively. The scintillation light yields of the Ba3RE(PO4)3 have been quantitatively clarified for the first time.
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Undoped, 0.5, 1.0, and 2.0% Nd-doped Bi4Si3O12 (BSO) crystals were synthesized by the floating zone method. Regarding photoluminescence (PL) properties, all samples had emission peaks due to the 6p-6s transitions of Bi3+ ions. In addition, the Nd-doped samples had emission peaks due to the 4f-4f transitions of Nd3+ ions as well. The PL quantum yield of the 0.5, 1.0, and 2.0% Nd-doped samples in the near-infrared range were 67.9, 73.0, and 56.6%, respectively. Regarding X-ray-induced scintillation properties, all samples showed emission properties similar to PL. Afterglow levels at 20 ms after X-ray irradiation of the undoped, 0.5, 1.0, and 2.0% Nd-doped samples were 192.3, 205.9, 228.2, and 315.4 ppm, respectively. Dose rate response functions had good linearity from 0.006 to 60 Gy/h for the 1.0% Nd-doped BSO sample and from 0.03 to 60 Gy/h for the other samples.
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We synthesized the 0.1, 0.5, 1.0, and 1.5% Ce-doped mullite single crystals by the floating zone method and evaluated their photoluminescence (PL) and thermally stimulated luminescence (TSL) properties. The single-phase orthorhombic structure was confirmed in all the samples from powder X-ray diffraction patterns. The transmittance spectra of all the samples showed the absorption related to the 4f-5d transitions of Ce3+ ions and optical band gap of mullite. The Ce-doped mullite single crystals had the PL attributed to the 5d-4f transitions of Ce3+ ions. In TSL properties, TSL glow curves had the glow peaks at 250 and 370 °C, and TSL spectra heated at 250 and 370 °C had the peak at around 390 nm owing to the Ce3+ ions. TSL dose response functions showed linear response from 0.01 mGy to 10 Gy for the 1.0% Ce-doped mullite single crystal and from 0.1 mGy to 10 Gy for the 0.1, 0.5, and 1.5% Ce-doped ones. The 1.0% Ce-doped mullite single crystal could be used multiple times for dosimetry. In addition, the TSL intensity of the 1.0% Ce-doped mullite single crystal after 7 days from X-ray irradiation was about 82.4% from immediately one after X-ray irradiation.
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Recently, spark plasma sintering (SPS) has become an attractive method for the preparation of solid-state ceramics. As SPS is a pressure-assisted low-temperature process, it is important to examine the effects of temperature and pressure on the structural properties of the prepared samples. In the present study, we examined the correlation between the preparation conditions and the physical and structural properties of SiO2 glasses prepared by SPS. Compared with the conventional SiO2 glass, the SPS-SiO2 glasses exhibit a higher density and elastic modulus, but a lower-height first sharp diffraction peak of the X-ray total structure factor. Micro-Raman and micro-IR spectra suggest the formation of heterogeneous regions at the interface between the SiO2 powders and graphite die. Considering the defect formation observed in optical absorption spectra, reduction reaction mainly affects the densification of SPS-SiO2 glass. Hence, the reaction at the interface is important for tailoring the structure and physical properties of solid-state materials prepared by the SPS technique.
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Amorphous materials with non-periodic structures are commonly evaluated based on their chemical composition, which is not always the best parameter to evaluate physical properties, and an alternative parameter more suitable for performance evaluation must be considered. Herein, we quantified various structural and physical properties of Ce-doped strontium borate glasses and studied their correlations by principal component analysis. We found that the density-driven molar volume is suitable for the evaluation of structural data, while chemical composition is better for the evaluation of optical and luminescent data. Furthermore, the borate-rich glasses exhibited a stronger luminescence due to Ce3+, indicating a higher fraction of BO3/2 ring and larger cavity. Moreover, the internal quantum efficiency was found to originate from the local coordination states of the Ce3+ centres, independent of composition or molar volume. The comparison of numerical data of the matrix is useful not only for ensuring the homogenous doping of amorphous materials by activators, but also for determining the origin of physical properties.
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Scintillators emit visible luminescence when irradiated with X-rays. Given the unlimited tissue penetration of X-rays, the employment of scintillators could enable remote optogenetic control of neural functions at any depth of the brain. Here we show that a yellow-emitting inorganic scintillator, Ce-doped Gd3(Al,Ga)5O12 (Ce:GAGG), can effectively activate red-shifted excitatory and inhibitory opsins, ChRmine and GtACR1, respectively. Using injectable Ce:GAGG microparticles, we successfully activated and inhibited midbrain dopamine neurons in freely moving mice by X-ray irradiation, producing bidirectional modulation of place preference behavior. Ce:GAGG microparticles are non-cytotoxic and biocompatible, allowing for chronic implantation. Pulsed X-ray irradiation at a clinical dose level is sufficient to elicit behavioral changes without reducing the number of radiosensitive cells in the brain and bone marrow. Thus, scintillator-mediated optogenetics enables minimally invasive, wireless control of cellular functions at any tissue depth in living animals, expanding X-ray applications to functional studies of biology and medicine.
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Encéfalo/fisiología , Animales , Conducta Animal/fisiología , Conducta Animal/efectos de la radiación , Encéfalo/efectos de la radiación , Cerio , Femenino , Células HEK293 , Humanos , Luminiscencia , Masculino , Ratones , Ratones Endogámicos C57BL , Opsinas/metabolismo , Opsinas/efectos de la radiación , Optogenética/instrumentación , Conteo por Cintilación , Tecnología Inalámbrica/instrumentación , Rayos XRESUMEN
A glass phosphor is an attractive material for applications in radiation detections because of its high workability and availability with a wide range of chemical compositions. Recently, X-ray-induced luminescence of glasses containing various luminescent activators are actively investigated worldwide. In applications as phosphor, tailoring valence state of activators, which can take multiple valence states in glass, is very important. In this research, we studied effects of glass melting atmosphere on the valence state of copper-activator ion in alkaline aluminophosphate glasses and the radiation-induced luminescence characteristics. Optical absorption and X-ray absorption near edge structure spectra of Cu-doped glasses showed that the glass fused in Ar atmosphere contains higher concentration of Cu+ than those prepared in air. In addition, the presence of Cu+ enhances the photoluminescence (PL) quantum yield and PL kinetic constant. Furthermore, the increase of Cu+ concentration resulted an improvement of the X-ray-induced scintillation and thermally-stimulated luminescence intensity.
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Five photochromic terarylenes which show reversible photocyclisation and cycloreversion with relatively high quantum yields are presented. Some of these have been observed to undergo a highly efficient cycloreversion cascade process from their coloured, closed forms to their uncoloured open forms that leads to cycloreversion quantum yields significantly larger than unity. This cascade effect can been induced with both chemical and X-ray initiation; the limit of detection from X-ray initiation has been tested and is comparable to existing systems with detection observed at values as low as 0.3 mGy.
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The efficiency of X-ray-induced scintillation in glasses roughly depends on both the effective atomic number Zeff and the photoluminescence quantum efficiency Qeff of glass, which are useful tools for searching high-performance phosphors. Here, we demonstrate that the energy transfer from host to activators is also an important factor for attaining high scintillation efficiency in Ce-doped oxide glasses. The scintillation intensity of glasses with coexisting fractions of Ce3+ and Ce4+ species is found to be higher than that of a pure-Ce3+-containing glass with a lower Zeff value. Values of total attenuation of each sample indicate that there is a non-linear correlation between the scintillation intensity and the product of total attenuation and Qeff. The obtained results illustrate the difficulty in understanding the luminescence induced by ionizing radiation, including the energy absorption and subsequent energy transfer. Our findings may provide a new approach for synthesizing novel scintillators by tailoring the local structure.
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We investigated scintillation properties of organic-inorganic layered perovskite-type compounds under gamma-ray and X-ray irradiation. A crystal of the hybrid compounds with phenethyl amine (17 × 23 × 4 mm) was successfully fabricated by the poor-solvent diffusion method. The bulk sample showed superior scintillation properties with notably high light yield (14,000 photons per MeV) under gamma-rays and very fast decay time (11 ns). The light yield was about 1.4 time higher than that of common inorganic material (GSO:Ce) confirmed under 137Cs and 57Co gamma-rays. In fact, the scintillation light yield was the highest among the organic-inorganic hybrid scintillators. Moreover, it is suggested that the light yield of the crystal was proportional with the gamma-ray energy across 122-662 keV. In addition, the scintillation from the crystal had a lifetime of 11 ns which was much faster than that of GSO:Ce (48 ns) under X-ray irradiation. These results suggest that organic-inorganic layered perovskite-type compounds are promising scintillator for gamma-ray detection.
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Atomic distribution in phosphors for neutron detection has not been fully elucidated, although their ionization efficiency is strongly dependent on the state of the rare earth in the matrix. In this work, we examine optical properties of Eu-doped 80LiF-20CaF2 eutectics for neutron detector applications based on the Eu distribution. At low concentrations, aggregation of Eu cations is observed, whereas homogeneous atomic dispersion in the CaF2 layer, to substitute Ca(2+) ions, is observed in the eutectics at high concentrations. Eu LIII edge X-ray absorption fine structure (XAFS) analysis suggests that neutron responses do not depend on the amount of Eu(2+) ions. However, transparency, which depends on an ordered lamellar structure, is found to be important for a high light yield in neutron detection. The results confirm the effectiveness of the basic idea concerning the separation of radiation absorbers and activators in particle radiation scintillation and present potential for further improvement of novel bulk detectors.
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Although inorganic crystalline phosphors can exhibit high quantum efficiency, their use in phosphor films has been limited by a reliance on organic binders that have poor durability when exposed to high-power and/or high excitation energy light sources. To address this problem, Sn(2+)-doped transparent phosphate films measuring several micrometers in thickness have been successfully prepared through heat treatment and a subsequent single dip-coating process. The resulting monolithic inorganic amorphous film exhibited an internal quantum efficiency of over 60% and can potentially utilize transmitted light. Analysis of the film's emissivity revealed that its color can be tuned by changing the amount of Mn and Sn added to influence the energy transfer from Sn(2+) to Mn(2+). It is therefore concluded that amorphous films containing such emission centers can provide a novel and viable alternative to conventional amorphous films containing crystalline phosphors in light-emitting devices.
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We grew column-shaped Sr(3)NbGa(3)Si(2)O(14) (SNGS) and Sr(3)TaGa(3)Si(2)O(14) (STGS) langasite-type piezoelectric single crystals by the micro-pulling-down (µ-PD) method. 3-mm-diameter SNGS and STGS crystals were grown using a Pt-Rh crucible with a 3-mm-diameter columnar die. According to X-ray rocking curve measurements, the grown crystals had crystallinity equivalent to that of crystals grown by the Czochralski (Cz) method. The crystals were single-phase materials with langasite-type crystal structure. The lattice parameters of the grown crystals were almost consistent with those of crystals grown by the Cz method.
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We have grown shape-controlled langasite-type crystals by the micro-pulling-down (µ-PD) method. Columnar shaped La(3)Ta(0.5)Ga(5.5)O(14) (LTG), Ca(3)NbGa(3)Si(2)O(14) (CNGS), Ca(3)TaGa(3)Si(2)O(14) (CTGS), Sr(3)NbGa(3)Si(2)O(14) (SNGS), and Sr(3)Ta- Ga(3)Si(2)O(14) (STGS) crystals were grown using a Pt-Rh crucible with a 3-mm-diameter columnar die at the bottom. All grown crystals showed high transparency except for the peripheral area and diameter of approximately 3 mm. The chemical phases at the central parts of the grown crystals were identified as a single phase of langasite-type structure and their lattice parameters were almost the same as those of crystals grown by the Czochralski (Cz) method; however, some impurity phases were observed in the peripheral area. In X-ray rocking curve measurements, the grown crystals indicated equivalent crystallinity to the crystal grown by the Cz method. The piezoelectric constant d(11) of the CNGS crystal was 3.98 pC/N; this value is well correlated with those of previous reports.