RESUMEN
In the age of mobile electronics and increased aerospace interest, multifunctional materials such as the polymer composites reported here are interesting alternatives to conventional materials, offering reduced cost and size of an electrical device packaging. We report a detailed study of an ecological and dual-functional polymer composite for electromagnetic interference (EMI) shielding and heat management applications. We studied a series of polylactic acid/graphene nanoplatelet composites with six graphene nanoplatelet loadings, up to 15 wt%, and three different flake lateral sizes (0.2, 5 and 25 µm). The multifunctionality of the composites is realized via high EMI shielding efficiency exceeding 40 dB per 1 mm thick sample and thermal conductivity of 1.72 W/mK at 15 wt% nanofiller loading. The EMI shielding efficiency measurements were conducted in the microwave range between 0.2 to 12 GHz, consisting of the highly relevant X-band (8-12 GHz). Additionally, we investigate the influence of the nanofiller lateral size on the studied physical properties to optimize the studied functionalities per given nanofiller loading.
RESUMEN
The majority of industry using high-speed communication systems is shifting towards higher frequencies, namely the terahertz range, to meet demands of more effective data transfer. Due to the rising number of devices working in terahertz range, effective shielding of electromagnetic interference (EMI) is required, and thus the need for novel shielding materials to reduce the electromagnetic pollution. Here, we show a study on optical and electrical properties of a series of ethylene co-butyl acrylate/carbon black (EBA/CB) composites with various CB loading. We investigate the transmittance, reflectance, shielding efficiency, absorption coefficient, refractive index and complex dielectric permittivity of the fabricated composites. Finally, we report a material that exhibits superior shielding efficiency (SE)-80 dB at 0.9 THz (14.44 vol% CB loading, 1 mm thick)-which is one of the highest SE values among non-metallic composite materials reported in the literature thus far. Importantly, 99% of the incoming radiation is absorbed by the material, significantly increasing its applicability. The absorption coefficient (α) reaches ~100 cm-1 for the samples with highest CB loading. The EBA/CB composites can be used as lightweight and flexible shielding packaging materials for electronics, as passive terahertz absorbers or as radiation shields for stealth applications.
RESUMEN
We report a surfactant-free exfoliation method of WS2 flakes combined with a vacuum filtration method to fabricate thin (<50 nm) WS2 films, that can be transferred on any arbitrary substrate. Films are composed of thin (<4 nm) single flakes, forming a large size uniform film, verified by AFM and SEM. Using statistical phonons investigation, we demonstrate structural quality and uniformity of the film sample and we provide first-order temperature coefficient χ, which shows linear dependence over 300-450 K temperature range. Electrical measurements show film sheet resistance RS = 48 MΩ/Υ and also reveal two energy band gaps related to the intrinsic architecture of the thin film. Finally, we show that optical transmission/absorption is rich above the bandgap exhibiting several excitonic resonances, and nearly feature-less below the bandgap.
RESUMEN
We performed scanning thermal microscopy measurements on single layers of chemical-vapor-deposited (CVD) graphene supported by different substrates, namely, SiO2, Al2O3, and PET using a double-scan technique to remove the contribution to the heat flux through the air and the cantilever. Then, by adopting a simple lumped-elements model, we developed a new method that allows determining, through a multistep numerical analysis, the equivalent thermal properties of thermally conductive coatings of nanometric thickness. In this specific case we found that our CVD graphene is "thermally equivalent", for heat injection perpendicular to the graphene planes, to a coating material of conductivity k eff = 2.5 ± 0.3 W/m K and thickness t eff = 3.5 ± 0.3 nm in perfect contact with the substrate. For the SiO2 substrate, we also measured stacks made of 2- and 4-CVD monolayers, and we found that the effective thermal conductivity increases with increasing number of layers and, with a technologically achievable number of layers, is expected to be comparable to that of 1 order of magnitude-thicker metallic thin films. This study provides a powerful method for characterizing the thermal properties of graphene in view of several thermal management applications.
RESUMEN
Increasing the requirements on telecommunications systems such as the need for higher data rates and connectivity via the Internet of things results in continuously increasing amounts of electromagnetic radiation in ever-higher telecommunications bands (up to terahertz). This can generate unwanted electromagnetic radiation that can affect the operation of electronic devices and human health. Here, we demonstrate that nonconductive and lightweight, graphene-based composites can shield more than 99.99% of the electromagnetic energy in the sub-THz range mainly via absorption. This contrasts with state-of-the-art electromagnetic radiation shielding materials that simply redirect the energy of the radiation from a protected area via conduction-based reflection mechanisms. This shifts the problem of electromagnetic pollution from one place to another. We have demonstrated that the proposed composites can be fabricated by industrial compatible methods and are characterized by specific shielding efficiency values that exceed 30 dB cm3 g-1, which is more than those for typical metals used today. Therefore these materials might help to solve the problem of electromagnetic environmental pollution.