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1.
J Environ Manage ; 309: 114680, 2022 May 01.
Artículo en Inglés | MEDLINE | ID: mdl-35168132

RESUMEN

The shortage of water and energy are hindering the rapid development of the regional economy in recent years. Therefore, exploring the synergy of water and energy and managing the two resources comprehensively is conducive to the sustainable development of the economy. Based on the multi-regional input-output (MRIO) model, this study proposed a new assessment framework for investigating the water-energy (WE) relationship. We used this novel framework to identify the relationships in different sectors. The achieved results are as follows. First, water and energy are closely related in many sectors, including agriculture, extractive sector, petroleum, coking, and nuclear fuel processing sector, and other sectors. However, the construction sector, textile and clothing sector, and wood processing and furniture manufacturing sector showed low correlation (p > 0.05). Second, on the whole, the WE relationship has been improving. Among the eight regions, the relationship varies greatly, and the Southern coastal region has the best relationship (r = 0.78). Third, the spatial distribution of water and energy footprints shows high agreement. Although the virtual water and energy flows alleviated the energy pressure in Coastal areas, it has aggravated the water and energy shortages in Central areas. Therefore, identification of key sectors and construction of suitable policies may help alleviate the contradiction between water and energy shortages and drive regional economic development.


Asunto(s)
Abastecimiento de Agua , Agua , Agricultura , China , Recursos Hídricos
2.
Environ Monit Assess ; 191(3): 140, 2019 Feb 08.
Artículo en Inglés | MEDLINE | ID: mdl-30734102

RESUMEN

The Ningxia-Inner Mongolia reaches of the Yellow River suffer from bank erosion problems; in order to identify the bank erosion dynamics, Real Time Kinematic Global Positioning System (RTK GPS) was applied to monitor bank morphology at three sites: Taole Cropland (TC), Maobula Shrubland (MS), and Maobula Cropland (MC). The measured data were analyzed using the Geographical Information System (GIS) to quantify the volume and amount of bank erosion. To verify the feasibility of other means quantifying bank erosion including remote sensing image interpretation and Bank-Stability and Toe-Erosion Model (BSTEM) simulation, their results were compared with the directly monitored results by RTK GPS. Results show that the bank erosion moduli at the TC, MS, and MC sites are 12,762, 6681 and 44,142 t km-1 a-1 respectively based on RTK GPS measurements from 2011 to 2014, with the bank erosion amount varying between flood and non-flood seasons and among different years. The bank erosion quantified by remote sensing interpretation and BSTEM simulation agreed well with results from RTK GPS measurement. The main factors that influence bank erosion on the upper reaches of the Yellow River include land use in the bank area, bank height, and bank curvature. More rational land use along the Yellow River and stabilization of the river bank are required for this area. This study shows that RTK GPS monitoring is reliable and useful for bank erosion research, which has not yet been fully exploited. There is potential of applying remote sensing and model simulation to determine bank erosion of large rivers, while they should be combined and supported by field investigated data.


Asunto(s)
Monitoreo del Ambiente/métodos , Sistemas de Información Geográfica , Fenómenos Geológicos , Fenómenos Biomecánicos , China , Inundaciones/estadística & datos numéricos , Ríos , Movimientos del Agua
3.
Sensors (Basel) ; 18(12)2018 Dec 12.
Artículo en Inglés | MEDLINE | ID: mdl-30545150

RESUMEN

An integrated sensor system comprised of a terrestrial laser scanner (TLS), corner reflectors (CRs), and high precision linear rail is utilized to validate ground-based synthetic aperture radar (GB-SAR) interferometric micro-displacement measurements. A rail with positioning accuracy of 0.1 mm is deployed to ensure accurate and controllable deformation. The rail is equipped with a CR on a sliding platform for mobility. Three smaller CRs are installed nearby, each with a reflective sticker attached to the CR's vertex; the CRs present as high-amplitude points both in the GB-SAR images and the TLS point cloud to allow for accurate data matching. We analyze the GB-SAR zero-baseline repeated rail differential interferometry signal model to obtain 2D interferograms of the test site in time series, and then use TLS to obtain a 3D surface model. The model is matched with interferograms to produce more intuitive 3D products. The CR displacements can also be extracted via surface reconstruction algorithm. Finally, we compared the rail sensor measurement and TLS results to optimize coherent scatterer selection and filter the data. The proposed method yields accurate target displacement results via quantitative analysis of GB-SAR interferometry.

4.
ScientificWorldJournal ; 2014: 913852, 2014.
Artículo en Inglés | MEDLINE | ID: mdl-25250394

RESUMEN

Rapid land-use change in recent decades in China and its impact on terrestrial biodiversity have been widely studied, particularly at local and regional scales. However, the effect of land-use change on the diversity of soils that support the terrestrial biological system has rarely been studied. Here, we report the first effort to assess the impact of land-use change on soil diversity for the entire nation of China. Soil diversity and land-use effects were analyzed spatially in grids and provinces. The land-use effects on different soils were uneven. Anthropogenic soils occupied approximately 12% of the total soil area, which had already replaced the original natural soils. About 7.5% of the natural soil classes in China were in danger of substantial loss, due to the disturbance of agriculture and construction. More than 80% of the endangered soils were unprotected due to the overlook of soil diversity. The protection of soil diversity should be integrated into future conservation activities.


Asunto(s)
Biodiversidad , Conservación de los Recursos Naturales/métodos , Mapeo Geográfico , Suelo , Agricultura/métodos , Agricultura/normas , China , Suelo/normas
5.
Artículo en Inglés | MEDLINE | ID: mdl-38416619

RESUMEN

Conditional independence (CI) testing is an important problem, especially in causal discovery. Most testing methods assume that all variables are fully observable and then test the CI among the observed data. Such an assumption is often untenable beyond applications dealing with, e.g., psychological analysis about the mental health status and medical diagnosing (researchers need to consider the existence of latent variables in these scenarios); and typically adopted latent CI test schemes mainly suffer from robust or efficient issues. Accordingly, this article investigates the problem of testing CI between latent variables. To this end, we offer an auxiliary regression-based CI (AReCI) test by taking the measured variable as the surrogate variable of the latent variables to conduct the regression over the latent variables under the linear causal models, in which each latent variable has some certain measured variables. Specifically, given a pair of latent variables LX and LY , and a corresponding latent variable set LO , [Formula: see text] holds if and only if [Formula: see text] and [Formula: see text] are statistically independent, where A' and A'' are the two disjoint subset of the measured variable for the corresponding latent variables, A'{LO} ∩A''{LO} = ∅ , and ω1 is a parameter vector characterized from the cross covariance between A{LX} and A'{LO} , and ω2 is a parameter vector characterized from the cross covariance between A{LY} and A''{LO} . We theoretically show that the AReCI test is capable of addressing both Gaussian and non-Gaussian data. In addition, we find that the well-known partial correlation test can be seen as a special case of the AReCI test. Finally, we devise a causal discovery method by using the AReCI test as the CI test. The experimental results on synthetic and real-world data illustrate the effectiveness of our method.

6.
Water Res ; 254: 121356, 2024 May 01.
Artículo en Inglés | MEDLINE | ID: mdl-38430756

RESUMEN

Microplastics are found in continental and oceanic waters worldwide, but their spatial distribution shows an intricate pattern. Their driving factors remain difficult to identify and widely discussed due to insufficient and unstandardized monitoring data. Here, based on in situ experiments and hundreds of river samples from the Qinghai-Tibet Plateau, we formulate a model to standardize aquatic microplastic measurements. The model was applied to existing data on a global scale. These data are standardized to a 20 µm mesh size, resulting in a new spatial distribution of aquatic microplastic densities, with average concentrations of 554.93 ± 1352.42 items/m3 in Europe, 2558.90 ± 4799.62 in North America and 1741.94 ± 3225.09 in Asia. Excessive contaminations (microplastic concentration > 104 items/m3) are in the Yangtze River, the Charleston Harbor Estuary, the Bodega Bay and the Winyah Bay. We show that, based on these standardized concentrations, new driving factors could be used to predict the global or regional microplastic distribution in continental waters, such as the Human Development Index with a correlation of 75.86% on a global scale, the nighttime lights with a correlation of 37.26 ± 0.30% in Europe and 39.02 ± 0.54% in Asia, and the Mismanagement Plastic Waste with a correlation of 61.21 ± 19.86% in North America. Mapping standardized concentrations of aquatic microplastics enables a better comparison of contamination levels between regions and reveals more accurate hotspots to better adapt remediation efforts and future plastic pollution scenarios.


Asunto(s)
Microplásticos , Contaminantes Químicos del Agua , Humanos , Plásticos , Contaminantes Químicos del Agua/análisis , Monitoreo del Ambiente , Estándares de Referencia
7.
Zhejiang Da Xue Xue Bao Yi Xue Ban ; 42(4): 456-60, 2013 07.
Artículo en Zh | MEDLINE | ID: mdl-24022936

RESUMEN

OBJECTIVE: To analyze the characteristics of autopsies in medical dispute. METHODS: The data of 202 autopsy cases in medical disputes performed by the Department of Pathology of Jiangxi Medical College from January 2001 to December 2010 were retrospectively analyzed. RESULTS: The number of autopsy in medical disputes increased year by year. Neonatal, infant and 30 ≊ 60y were more common age groups in dispute; the gender ratio of male to female was 2:1 and more cases were from hospitals in rural areas. Most medical disputes came from in departments of pediatric, obstetrics and gynecology and general surgery. Death caused by cardiovascular diseases ranked at the first place. CONCLUSION: Autopsy is important in medical disputes to define the cause of death and to preserve evidence.


Asunto(s)
Autopsia/estadística & datos numéricos , Disentimientos y Disputas , Adolescente , Adulto , Anciano , Enfermedades Cardiovasculares/mortalidad , Causas de Muerte , Niño , Preescolar , Femenino , Departamentos de Hospitales/estadística & datos numéricos , Humanos , Lactante , Recién Nacido , Masculino , Mala Praxis , Persona de Mediana Edad , Estudios Retrospectivos , Razón de Masculinidad , Adulto Joven
8.
Artículo en Inglés | MEDLINE | ID: mdl-35055473

RESUMEN

Soil erosion is serious in China-the soil in plateau and mountain areas contain a large of rock fragments, and their content and distribution have an important influence on soil erosion. However, there are still no complete results for calculating soil erodibility factor (K) that have corrected rock fragments in China. In this paper, the data available on rock fragments in the soil profile (RFP); rock fragments on the surface of the soil (RFS); and environmental factors such as elevation, terrain relief, slope, vegetation coverage (characterised by normalised difference vegetation index, NDVI), land use, precipitation, temperature, and soil type were used to explore the effects of content of soil rock fragments on calculating of K in China. The correlation analysis, typical sampling area analysis, and redundancy analysis were applied to analyse the effects of content of soil rock fragments on calculating of K and its relationship with environment factors. The results showed that (1) The rock fragments in the soil profile (RFP) increased K. The rock fragments on the surface (RFS) of the soil reduced K. The effect of both RFP and RFS reduced K. (2) The effect of rock fragments on K was most affected by elevation, followed by terrain relief, NDVI, slope, soil type, temperature, and precipitation, but had little correlation with land use. (3) The result of redundancy analysis showed elevation to be the main predominant factor of the effect of rock fragments on K. This study fully considered the effect of rock fragments on calculating of K and carried out a quantitative analysis of the factors affecting the effect of rock fragments on K, so as to provide necessary scientific basis for estimating K and evaluating soil erosion status in China more accurately.


Asunto(s)
Monitoreo del Ambiente , Suelo , China , Conservación de los Recursos Naturales
9.
Sci Total Environ ; 849: 157882, 2022 Nov 25.
Artículo en Inglés | MEDLINE | ID: mdl-35944632

RESUMEN

Geochemical behaviors of trace metals in the sediment profiles are crucial for predicting the associated environmental risks in aquatic ecosystems. However, the comprehensive transport of trace metals under both equilibrium and dynamic conditions is still unclear under the changing hydrological regime. Here, the equilibrium partitioning behaviors and remobilization of five trace metals (Ni, Cu, Zn, As, and Pb) in sedimentary profiles within the tributaries of the Three Gorges Reservoir were explored by the partitioning coefficient (Kd), diffusive gradients in thin films (DGT), and DGT induced flux in sediments (DIFS) model. According to the Kd values, As posed the highest migration ability among the trace metals in the sediment profiles under equilibrium circumstances. Similarly, the dynamic processes of trace metals simulated by the DIFS model also suggested that As displayed the highest desorption rate despite having the lowest labile pool size. Moreover, all trace metals were classified as the "partially sustained" case, while the supply abilities of As and other trace metals were limited by the diffusion and the desorption kinetics, respectively. In addition, DGT-labile trace metals showed a diffusion trend from the sediment to the water column (except for Zn) at the sediment-water interface, indicating potential risks to water quality. Specifically, the equilibrium partitioning behaviors revealed the potential labile pool of trace metals in the solid phase, and the dynamic resupply process between the solid phase and porewater remained undetermined. In comparison, although DGT simulated the kinetic process of trace metals in the sediments, the labile pool of the trace metals could not be obtained. This study provided a holistic insight into the complementary trace metal behaviors under both equilibrium and dynamic conditions in the sediment and was beneficial to the water quality protection and internal pollution remediation in the aquatic environment.


Asunto(s)
Oligoelementos , Contaminantes Químicos del Agua , China , Ecosistema , Monitoreo del Ambiente , Sedimentos Geológicos , Plomo , Contaminantes Químicos del Agua/análisis
10.
Artículo en Inglés | MEDLINE | ID: mdl-36612520

RESUMEN

The existence of residences and roads is an important way in which human activity affects wind erosion in arid and semiarid environments. Studies assessing the impact of these elements on wind erosion have only focused on limited plots, and their threat of erosion to the surrounding environment has been ignored by many studies. This study was based on spatially overlayed analysis of independent wind erosion distribution simulated by the revised wind erosion equation (RWEQ) and remote-sensing-image-derived residence and road distribution data. Wind erosion at different distances from residences and roads was quantified at the landscape scale of a typical temperate grassland ecosystem, explicitly demonstrating the crucial impacts of both elements on wind erosion. The results showed that wind erosion weakened as the distance from residences and roads increased due to the priority pathways of human activities, and the wind erosion around the residence was more severe than around the road. Human activities in the buffer zones 0-200 m from the residences most frequently caused severe wind erosion, with a wind soil loss of 25 t ha-1 yr-1 and a wind soil loss of approximately 5.25 t ha-1 yr-1 for 0-60 m from the roads. The characteristics of wind erosion variation in the buffer zones were also affected by residence size and the environments in which the residences were located. The variation in wind erosion was closely related to the road levels. Human activities intensified wind erosion mainly by affecting the soil and vegetation around residences and roads. Ecological management should not be limited to residences and roads but should also protect the surrounding environments. The findings of this study are aimed towards a spatial perspective that can help implement rational and effective environmental management measures for the sustainability of wind-eroded ecosystems.


Asunto(s)
Ecosistema , Pradera , Humanos , Viento , Conservación de los Recursos Naturales/métodos , Monitoreo del Ambiente/métodos , Suelo
11.
Sci Total Environ ; 806(Pt 2): 150666, 2022 Feb 01.
Artículo en Inglés | MEDLINE | ID: mdl-34597542

RESUMEN

Water consumption, energy use, and carbon emission are three related key anthropogenic impacts on the natural environment. China is the largest carbon emitter and energy consumer, with the serious unevenly distributed water resources. Therefore, investigating the water-energy-carbon (WEC) nexus is important for China's environmental footprint reduction. This study explores the relation between water utilization, energy consumption, and carbon emission in China, based on a multiregional input-output (MRIO) analysis. The WEC nexus is discussed comprehensively in consideration of the utilization of water and energy and the emission of carbon, as well as the trade to and from and the consumption activities in different sectors and provinces. Results show that water, energy, and carbon present significant consistency in production and consumption processes. Sectors with higher consumption coefficients dominate the transfer of virtual WEC. Although virtual WEC mainly transfers from less developed regions to relatively developed regions, Category 1 (i.e., WEC all import) and category 2 (i.e., WEC disaccord) present opposite results to and category 3 (i.e., WEC all export) provinces in terms of W-E and W-C nexus. The net water and energy transfers are significantly positively correlated in category 1 provinces, whereas both sides are negatively correlated in category 2 and 3 provinces. This phenomenon also exists in the relationship between net water and carbon transfers. The virtual water, as well as energy and carbon export pressures are dispersed in these export provinces. Findings of this study are expected to assist the government in decreasing the environmental footprints and achieve sustainable development in China.


Asunto(s)
Carbono , Agua , Carbono/análisis , China , Recursos Hídricos
12.
Artículo en Inglés | MEDLINE | ID: mdl-35613067

RESUMEN

Learning causal structure among event types on multitype event sequences is an important but challenging task. Existing methods, such as the Multivariate Hawkes processes, mostly assumed that each sequence is independent and identically distributed. However, in many real-world applications, it is commonplace to encounter a topological network behind the event sequences such that an event is excited or inhibited not only by its history but also by its topological neighbors. Consequently, the failure in describing the topological dependency among the event sequences leads to the error detection of the causal structure. By considering the Hawkes processes from the view of temporal convolution, we propose a topological Hawkes process (THP) to draw a connection between the graph convolution in the topology domain and the temporal convolution in time domains. We further propose a causal structure learning method on THP in a likelihood framework. The proposed method is featured with the graph convolution-based likelihood function of THP and a sparse optimization scheme with an Expectation-Maximization of the likelihood function. Theoretical analysis and experiments on both synthetic and real-world data demonstrate the effectiveness of the proposed method.

13.
Ying Yong Sheng Tai Xue Bao ; 32(8): 2875-2885, 2021 Aug.
Artículo en Zh | MEDLINE | ID: mdl-34664461

RESUMEN

Biological soil crusts (BSCs), as a pioneer for vegetation restoration and crucial component of surface landscape, greatly affect land surface process. To explore the development of BSCs and its effects on soil water infiltration in karst region, we investigated the development of BSCs and analyzed the infiltration processes with different BSCs coverages (0, 28%, 40%, 70%, 97%) and rainfall intensities (42 and 132 mm·h-1) in simulating rainfall experiments on a typical karst slope. The results showed that there were significant differences in the development of BSCs for different land use types, whereas the spatial variation of BSCs development on the slope was not obvious under the same land use type. Compared to the bare plot, the presence of BSCs significantly increased surface roughness, the initial runoff generation time, and soil water infiltration. In the cases of light (42 mm·h-1) and intensive (132 mm·h-1) rainfall, the initial infiltration rate of BSCs covered plots were 1.7-1.9 times and 1.2-1.9 times as that of bare plot, while the average infiltration rate in BSCs covered plots were 2.5-3.0 times and 1.4-3.3 times as that of bare plot, respectively. The BSCs coverage was significantly positively correlated with the initial runoff production time. The critical values of facilitating infiltration of BSCs coverage were between 65% and 70% under the test rainfall intensities. For heavy rainfall events, the inhibiting effects of BSCs on surface runoff were weakened. Horton model was the most reliable one for describing the infiltration process on karst slope with BSCs, followed by Kostiakov model and Philip model. In conclusion, the spatial variability of BSCs development on the karst slope was higher. The presence of BSCs had a significant effect on soil permeability in karst region.


Asunto(s)
Suelo , Agua , Lluvia , Agua/análisis , Movimientos del Agua
14.
BMC Public Health ; 4: 23, 2004 Jun 18.
Artículo en Inglés | MEDLINE | ID: mdl-15202947

RESUMEN

BACKGROUND: Birth defects, which are the major cause of infant mortality and a leading cause of disability, refer to "Any anomaly, functional or structural, that presents in infancy or later in life and is caused by events preceding birth, whether inherited, or acquired (ICBDMS)". However, the risk factors associated with heredity and/or environment are very difficult to filter out accurately. This study selected an area with the highest ratio of neural-tube birth defect (NTBD) occurrences worldwide to identify the scale of environmental risk factors for birth defects using exploratory spatial data analysis methods. METHODS: By birth defect registers based on hospital records and investigation in villages, the number of birth defects cases within a four-year period was acquired and classified by organ system. The neural-tube birth defect ratio was calculated according to the number of births planned for each village in the study area, as the family planning policy is strictly adhered to in China. The Bayesian modeling method was used to estimate the ratio in order to remove the dependence of variance caused by different populations in each village. A recently developed statistical spatial method for detecting hotspots, Getis's 7, was used to detect the high-risk regions for neural-tube birth defects in the study area. RESULTS: After the Bayesian modeling method was used to calculate the ratio of neural-tube birth defects occurrences, Getis's statistics method was used in different distance scales. Two typical clustering phenomena were present in the study area. One was related to socioeconomic activities, and the other was related to soil type distributions. CONCLUSION: The fact that there were two typical hotspot clustering phenomena provides evidence that the risk for neural-tube birth defect exists on two different scales (a socioeconomic scale at 6.84 km and a soil type scale at 22.8 km) for the area studied. Although our study has limited spatial exploratory data for the analysis of the neural-tube birth defect occurrence ratio and for finding clues to risk factors, this result provides effective clues for further physical, chemical and even more molecular laboratory testing according to these two spatial scales.


Asunto(s)
Anomalías Congénitas/epidemiología , Anomalías Congénitas/etiología , Sistemas de Información Geográfica , Topografía Médica , Teorema de Bayes , China/epidemiología , Análisis por Conglomerados , Anomalías Congénitas/clasificación , Anomalías Congénitas/mortalidad , Femenino , Encuestas Epidemiológicas , Humanos , Recién Nacido , Masculino , Modelos Estadísticos , Defectos del Tubo Neural/epidemiología , Defectos del Tubo Neural/mortalidad , Proyectos de Investigación , Factores de Riesgo
15.
Spectrochim Acta A Mol Biomol Spectrosc ; 59(4): 729-31, 2003 Mar 01.
Artículo en Inglés | MEDLINE | ID: mdl-12609621

RESUMEN

The Tb(3+) and Eu(3+) doped amorphous zinc benzoate were prepared. Their infrared absorption, emission and excitation spectra were measured. The luminescence mechanisms of Tb(3+) and Eu(3+) in the amorphous substrate were discussed. The bonding modes of OCO group to Zn(2+) ion have two of symmetric and asymmetric bridging bidentate. The energy of the S(1) pi,pi* excited state of benzene ring can be transferred to Tb(3+) and Eu(3+) ion, and results in characteristic emission from the 5D(4)-->(7)F(j) of Tb(3+) and 5D(0)-->(7)F(j) of Eu(3+), respectively.


Asunto(s)
Benzoatos/química , Europio/análisis , Terbio/análisis , Zinc/química , Carbonatos/química , Relación Dosis-Respuesta a Droga , Europio/química , Iones , Luminiscencia , Espectrofotometría , Terbio/química , Difracción de Rayos X
16.
Spectrochim Acta A Mol Biomol Spectrosc ; 59(13): 2949-53, 2003 Nov.
Artículo en Inglés | MEDLINE | ID: mdl-14583271

RESUMEN

The zinc and europium alpha-thiophene carboxylate polymer with very strong red luminescence was prepared by rheological phase reaction method from zinc acetate, europium oxide and alpha-thiophenecarboxylic acid. Molecular weight, thermal analyses and X-ray diffraction pattern were measured. 1H NMR, 13C NMR, IR, XPS, UV, excitation and emission spectra were studied. The polymer with amorphous structure and 7.565x10(5) g/mol weight-average molecular exhibited excellent solubility in common organic solvents and better thermal stability under 270 degrees C in air. The quantum yield of the polymer in acetone was 0.6 relative to quinoline in 0.05 mol/l H(2)SO(4) solution. The energy of the pi,pi(*) excited state of C(4)H(3)SCO(2)(-) can be transferred to Eu(3+) ion resulting in emission from the 5D(0)-->(7)F(j) of Eu(3+) ion through the polymeric chains. Zn(2+) can effectively enhance the luminescence of Eu(3+) in alpha-thiophenecarboxylate polymer.


Asunto(s)
Europio/química , Tiofenos/química , Zinc/química , Luminiscencia , Espectroscopía de Resonancia Magnética , Polímeros , Espectrofotometría Infrarroja , Espectrofotometría Ultravioleta , Termodinámica , Difracción de Rayos X
17.
Guang Pu Xue Yu Guang Pu Fen Xi ; 23(2): 279-81, 2003 Apr.
Artículo en Zh | MEDLINE | ID: mdl-12961870

RESUMEN

The infrared spectra of Li-Mn-spinel were studied in this paper. As the structure of Li-Mn-spinel was classified as Fd3m space group, the lithium ions (Li(I)) occupy tetrahedral sites (8a sites) and manganese ions (Mn(IV) or Mn(III)) occupy octahedral sites (16d sites). The internal relationship between vibration modes and infrared activity was discussed based on the knowledge of group theory. The experimental IR spectra of Li-Mn-spinel were presented also. By theoretical analysis, we concluded that the bands at 618.6 and 501.5 cm-1 resulted from anti-symmetric stretching vibration of Mn(IV)-O and Mn (III)-O in Li-Mn-spinel crystal (Mn(IV)O6 and Mn(III)O6 octahedron), respectively, the weak band at 1,124 cm-1 resulted from anti-symmetric stretching vibration of Li-O in the spinel (LiO4 tetrahedron), and other possible bands at wave number lower than 400 cm-1 were not detected in the range from 400 to 4,000 cm-1. The reliability of conclusions was proved by IR spectra of both the Li-Mn-spinel and doped Li-Mn-spinel.


Asunto(s)
Compuestos de Litio/química , Litio/química , Manganeso/química , Cristalización , Electroquímica , Minerales/química , Compuestos Organometálicos/química , Oxidación-Reducción , Espectrofotometría Infrarroja , Vibración
18.
Guang Pu Xue Yu Guang Pu Fen Xi ; 24(2): 142-4, 2004 Feb.
Artículo en Zh | MEDLINE | ID: mdl-15769000

RESUMEN

Lanthanum salicylate and Tb3+ -doped lanthanum salicylate were synthesized with the rheological phase reaction method. Elemental analysis, IR, TG, DTA and powder X-ray diffraction were investigated to determine the composition, crystal structure and coordination manner between the COO- and ion La3+ of lanthanum salicylate. The emission and excitation spectra of Tb3+ -doped lanthanum salicylate were also discussed. Powder X-ray diffraction suggests that the compound has a layered monoclinic structure, and the lattice parameters are a = 21.6010 A, b = 13.8015 A , c = 3.8103 A, beta = 97.11 degrees, V = 1127.2 A3, Z = 2, rhocal = 1.621 g x cm(-3) and rhoexp = 1.653 g x cm(-3). The Tb3+ -doped lanthanum salicylate exhibits very strong green luminescence of Tb3+ under the excitation of UV light. And the transition from 5D4 to 7F5 is the strongest one.


Asunto(s)
Lantano/química , Ácido Salicílico/síntesis química , Terbio/química , Iterbio/química , Dióxido de Carbono/química , Luz , Luminiscencia , Mediciones Luminiscentes , Nanotecnología , Tamaño de la Partícula , Fotoquímica , Ácido Salicílico/química , Telurio , Óxido de Zinc
19.
Sci Total Environ ; 409(3): 447-51, 2011 Jan 01.
Artículo en Inglés | MEDLINE | ID: mdl-21106228

RESUMEN

The rate of birth defects in Shanxi Province is among the highest worldwide. In order to identify the impacts of geochemical and environmental factors on birth defect risk, samples of soil, water and food were collected from an area with an unusually high rate of birth defects (study area) and an area with a low rate of birth defects (control area) in Shanxi Province, China. Element contents were determined by ICP-OES, and the results were analyzed using a non-parametric test and stepwise regression. Differences in the level and distribution of 14 geochemical elements, namely arsenic (As), selenium (Se), molybdenum (Mo), zinc (Zn), strontium (Sr), iron (Fe), tin (Sn), magnesium (Mg), vanadium (V), calcium (Ca), copper (Cu), aluminum (Al), potassium (K) and sulfur (S) were thus compared between the study and control areas. The results reveal that the geochemical element contents in soil, water and food show a significant difference between the study area and control area, and suggest that the study area was characterized by higher S and lower Sr and Al contents. These findings, based on statistical analysis, may be useful in directing further epidemiological investigations identifying the leading causes of birth defects.


Asunto(s)
Anomalías Congénitas/epidemiología , Monitoreo del Ambiente , Fenómenos Geológicos , China/epidemiología , Contaminantes Ambientales/análisis , Contaminación Ambiental/estadística & datos numéricos , Monitoreo Epidemiológico , Humanos , Recién Nacido
20.
Ying Yong Sheng Tai Xue Bao ; 22(1): 99-104, 2011 Jan.
Artículo en Zh | MEDLINE | ID: mdl-21548295

RESUMEN

Field experiments were conducted in 2006-2008 to study the effects of no-tillage on the spatiotemporal dynamics of soil water content and related soil physical properties in spring corn fields in Beijing region during growth season. In study period, the water storage in 0-100 cm soil layer in tillage and no-tillage treatments had the same variation trend with time and precipitation, but the water storage at different time periods and under different precipitations was 2.7%-30.3% higher in no-tillage treatment than in tillage treatment. When the precipitation was relatively abundant, the increment of soil water storage was somewhat increased, but no-tillage was still worth to be popularized in the regions relatively deficit in precipitation. Under no-tillage, the average water storage in 0-100 cm soil layer during the three growth seasons in 2006-2008 was 3.4%-12.8% higher than that under conventional tillage, and the increment of the water storage in 0-20 cm and 80-100 cm soil layers under no-tillage was higher than that in intermediate layer, with the highest increment reached 22.2%. No-tillage improved soil water-holding capacity and water use efficiency via decreasing soil bulk density, increasing soil porosity, and promoting the formation of soil water-stable aggregates, and thereby, promoted crop yielding. After 3 years no-tillage, the soil water use efficiency and spring corn yield were increased by 13.3% and 16.4%, respectively, compared with those under conventional tillage.


Asunto(s)
Agricultura/métodos , Suelo/análisis , Agua/análisis , Zea mays/crecimiento & desarrollo , Biomasa , China , Porosidad , Lluvia , Estaciones del Año
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