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The vast majority of commodity plastics do not degrade and therefore they permanently pollute the environment. At present, less than 20% of post-consumer plastic waste in developed countries is recycled, predominately for energy recovery or repurposing as lower-value materials by mechanical recycling. Chemical recycling offers an opportunity to revert plastics back to monomers for repolymerization to virgin materials without altering the properties of the material or the economic value of the polymer. For plastic waste that is either cost prohibitive or infeasible to mechanically or chemically recycle, the nascent field of chemical upcycling promises to use chemical or engineering approaches to place plastic waste at the beginning of a new value chain. Here state-of-the-art methods are highlighted for upcycling plastic waste into value-added performance materials, fine chemicals and specialty polymers. By identifying common conceptual approaches, we critically discuss how the advantages and challenges of each approach contribute to the goal of realizing a sustainable plastics economy.
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Many pledges and laws are setting recycling targets without clearly defining quality of recycling. Striving to close this gap, this study presents an operational framework to quantify quality of recycling. The framework comprises three dimensions: the Virgin Displacement Potential (VDP); In-Use Stocks Lifetime (IUSL); and Environmental Impact (EI). The VDP indicates to what extent a secondary material can be used as a substitute for virgin material; the IUSL indicates how much of a certain material is still functional in society over a given time frame, and the EI is a measure of the environmental impact of a recycling process. The three dimensions are aggregated by plotting them in a distance-to-target graph. Two example calculations are included on poly(ethylene terephthalate) (PET) and glass. The results indicate that the recycling of bottle and container glass collected via a deposit-refund system has the lowest distance-to-target, at 1.05, and, thus, the highest quality of recycling. For PET bottles, the highest quality of recycling is achieved in closed-loop mechanical recycling of bottles (distance to optimal quality of 0.96). Furthermore, sensitivity analysis indicates that certain parameters, e.g., the collection rate for PET bottles, can reduce the distance-to-target to 0.75 when all bottles are collected for recycling.
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ReciclajeRESUMEN
Anthocyanins and pyranoanthocyanins are flavonoids that are present in various food products (e.g., fruit, vegetables, wine, etc.). The large chemical diversity amongst these molecules leads to compound-specific properties such as color and stability towards external conditions. These properties are also attractive for food and non-food applications. The photophysical experimental characterization is not easy as this generally demands advanced analytical techniques along with optimized separation procedures. Molecular modeling can provide insights into the fundamental understanding of the photophysical properties of these compounds in a uniform way for a broad set of compounds. However, the current literature is quite fragmented on this topic. Herein, a large set of 140 naturally derived anthocyanins was evaluated in a systematic way with three functionals (B3LYP, PBE0, and CAM-B3LYP). The accuracy of these functionals was determined with experimental literature λmax,vis values. In addition to λmax,vis values, time-dependent (TD)-DFT calculations also provided oscillator strengths, molar absorption coefficients, and orbital energies, which define whether specific natural anthocyanin-based compounds can be deployed in food and non-food applications such as food additives/colorants, textile dyeing, analytical standards, and dye-sensitized solar cells (DSSCs).
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Microplastics are ubiquitous pollutants within the marine environment, predominantly (>90%) accumulating in sediments worldwide. Despite the increasing global concern regarding these anthropogenic pollutants, research into the remediation of microplastics is lacking. Here, we examine those characteristics of microplastics that are essential to adequately evaluate potential remediation techniques such as sedimentation and (air) flotation techniques. We analyzed the sinking behavior of typical microplastics originating from real plastic waste samples and identified the best-available drag model to quantitatively describe their sinking behavior. Particle shape is confirmed to be an important parameter strongly affecting the sinking behavior of microplastics. Various common shape descriptors were experimentally evaluated on their ability to appropriately characterize frequently occurring particle shapes of typical microplastics such as spheres, films, and fibers. This study is the first in this field to include film particles in its experimental design, which were found to make up a considerable fraction of marine pollution and are shown to significantly affect the evaluation of shape-dependent drag models. Circularity χ and sphericity Φ are found to be appropriate shape descriptors in this context. We also investigated the effect of biofouling on the polarity of marine plastics and estimated its potential contribution to the settling motion of initially floating microplastics based on density-modification. It is found that biofouling alters the polarity of plastics significantly; this is from (near) hydrophobic (i.e., water contact angles from 70 to 100°) to strong hydrophilic (i.e., water contact angles from 30 to 40°) surfaces, rendering them more difficult to separate from sediment based on polarity as a primary separation factor. Thus, besides providing a better understanding of the fate and behavior of typical marine microplastics, these findings serve as a fundamental stepping-stone to the development of the first large-scale sediment remediation technique for microplastics to address the global microplastic accumulation issue.
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Incrustaciones Biológicas , Contaminantes Químicos del Agua , Monitoreo del Ambiente , Contaminación Ambiental , Sedimentos Geológicos , Microplásticos , Plásticos , Contaminantes Químicos del Agua/análisisRESUMEN
Plastic packaging typically consists of a mixture of polymers and contains a whole range of components, such as paper, organic residue, halogens, and metals, which pose problems during recycling. Nevertheless, until today, limited detailed data are available on the full polymer composition of plastic packaging waste taking into account the separable packaging parts present in a certain waste stream, nor on their quantitative levels of (elemental) impurities. This paper therefore presents an unprecedented in-depth analysis of the polymer and elemental composition, including C, H, N, S, O, metals, and halogens, of commonly generated plastic packaging waste streams in European sorting facilities. Various analytical techniques are applied, including Fourier transform infrared (FTIR) spectroscopy, differential scanning calorimetry (DSC), polarized optical microscopy, ion chromatography, and inductively coupled plasma optical emission spectrometry (ICP-OES), on more than 100 different plastic packaging products, which are all separated into their different packaging subcomponents (e.g., a bottle into the bottle itself, the cap, and the label). Our results show that certain waste streams consist of mixtures of up to nine different polymers and contain various elements of the periodic table, in particular metals such as Ca, Al, Na, Zn, and Fe and halogens like Cl and F, occurring in concentrations between 1 and 3000 ppm. As discussed in the paper, both polymer and elemental impurities impede in many cases closed-loop recycling and require advanced pretreatment steps, increasing the overall recycling cost.
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Plásticos , Residuos , Polímeros , Embalaje de Productos , ReciclajeRESUMEN
The production and consumption of plastics, although inevitable in our modern life, are predominantly unsustainable and inefficient. Hence, the concept of a circular economy for plastics has been proposed as a sustainable approach to thrive both economy and our modern life. To implement a circular economy for plastics, an understanding of both individuals' and organizations' behaviors is needed since psychological effects often undermine technical solutions. We particularly focus on organizations' behaviors since commercial plastic waste has not been thoroughly investigated compared to household plastic waste. Using the Theory of Planned Behavior (TPB) and Partial Least Squares Structural Equation Modeling (PLS-SEM), we assess the determinants of intentions and behaviors of 637 organizations in Belgium towards a circular economy for plastics. Our PLS-SEM analysis support that attitudes, subjective norms, and perceived behavioral control of decision makers positively influence organizations' intentions to implement best practices of plastic recycling. Furthermore, organizations' intentions, perceived behavioral control, pressures, and enablers positively, whereas barriers negatively, influence organizations' behaviors. Our study shows that most organizations have positive intentions, yet they seem to be failing in implementing best practices of plastic recycling due to some critical barriers. To overcome this intention-behavior gap and to attain a circular economy for plastics, our study suggests some measures.
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Circular Economy (CE) is a growing topic, especially in the European Union, that promotes the responsible and cyclical use of resources possibly contributing to sustainable development. CE is an umbrella concept incorporating different meanings. Despite the unclear concept, CE is turned into defined action plans supported by specific indicators. To understand what indicators used in CE measure specifically, we propose a classification framework to categorise indicators according to reasoning on what (CE strategies) and how (measurement scope). Despite different types, CE strategies can be grouped according to their attempt to preserve functions, products, components, materials, or embodied energy; additionally, indicators can measure the linear economy as a reference scenario. The measurement scope shows how indicators account for technological cycles with or without a Life Cycle Thinking (LCT) approach; or their effects on environmental, social, or economic dimensions. To illustrate the classification framework, we selected quantitative micro scale indicators from literature and macro scale indicators from the European Union 'CE monitoring framework'. The framework illustration shows that most of the indicators focus on the preservation of materials, with strategies such as recycling. However, micro scale indicators can also focus on other CE strategies considering LCT approach, while the European indicators mostly account for materials often without taking LCT into account. Furthermore, none of the available indicators can assess the preservation of functions instead of products, with strategies such as sharing platforms, schemes for product redundancy, or multifunctionality. Finally, the framework illustration suggests that a set of indicators should be used to assess CE instead of a single indicator.
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The rising demand for feed and food has put an increasing pressure on agriculture, with agricultural intensification as a direct response. Notwithstanding the higher crop productivity, intensive agriculture management entails many adverse environmental impacts. Worldwide, soil organic carbon (SOC) decline is hereby considered as a main danger which affects soil fertility and productivity. The life cycle perspective helps to get a holistic overview when evaluating the environmental sustainability of agricultural systems, though the impact of farm management on soil quality aspects is often not integrated. In this paper, we introduce an indicator called Agricultural Biomass Productivity Benefit of SOC management (ABB_SOC), which, relying on natural resource consumption, enables to estimate the net effect of the efforts made to attain a better soil quality. Hereby the focus is put on SOC. First, we introduce a framework to describe the SOC trend due to farm management decisions. The extent to which remediation measures are required are used as a measure for the induced SOC losses. Next, ABB_SOC values are calculated as the balance between the natural resource consumption of the inputs (including remediation efforts) and the desired output of arable crop production systems. The models RothC and EU-Rotate_N are used to simulate the SOC evolution due to farm management and the response of the biomass productivity, respectively. The developed indicator is applied on several rotation systems in Flanders, comparing different remediation strategies. The indicator could be used as a base for a method to account for soil quality in life cycle analysis.
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Carbono/análisis , Productos Agrícolas , Recursos Naturales , Agricultura , Biomasa , Suelo/químicaRESUMEN
The effects of a pharmaceutical treatment have until now been evaluated by the field of Health Economics on the patient health benefits, expressed in Quality-Adjusted Life Years (QALYs) versus the monetary costs. However, there is also a Human Health burden associated with this process, resulting from emissions that originate from the pharmaceutical production processes, Use Phase and End of Life (EoL) disposal of the medicine. This Human Health burden is evaluated by the research field of Life Cycle Assessment (LCA) and expressed in Disability-Adjusted Life Years (DALYs), a metric similar to the QALY. The need for a new framework presents itself in which both the positive and negative health effects of a pharmaceutical treatment are integrated into a net Human Health effect. To do so, this article reviews the methodologies of both Health Economics and the area of protection Human Health of the LCA methodology and proposes a conceptual framework on which to base an integration of both health effects. Methodological issues such as the inclusion of future costs and benefits, discounting and age weighting are discussed. It is suggested to use the structure of an LCA as a backbone to cover all methodological challenges involved in the integration. The possibility of monetizing both Human Health benefits and burdens is explored. The suggested approach covers the main methodological aspects that should be considered in an integrated assessment of the health effects of a pharmaceutical treatment.
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Quimioterapia , Análisis Costo-Beneficio , Quimioterapia/economía , Ambiente , HumanosRESUMEN
The pharmaceutical and fine chemical industries are eager to strive toward innovative products and technologies. This study first derives hotspots in resource consumption of 2839 Basic Operations in 40 Active Pharmaceutical Ingredient synthesis steps through Exergetic Life Cycle Assessment (ELCA). Second, since companies are increasingly obliged to quantify the environmental sustainability of their products, two alternative ways of simplifying (E)LCA are discussed. The usage of averaged product group values (R(2) = 3.40 × 10(-30)) is compared with multiple linear regression models (R(2) = 8.66 × 10(-01)) in order to estimate resource consumption of synthesis steps. An optimal set of predictor variables is postulated to balance model complexity and embedded information with usability and capability of merging models with existing Enterprise Resource Planning (ERP) data systems. The amount of organic solvents used, molar efficiency, and duration of a synthesis step were shown to be the most significant predictor variables. Including additional predictor variables did not contribute to the predictive power and eventually weakens the model interpretation. Ideally, an organization should be able to derive its environmental impact from readily available ERP data, linking supply chains back to the cradle of resource extraction, excluding the need for an approximation with product group averages.
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Ambiente , Preparaciones Farmacéuticas , Industria Farmacéutica , Modelos TeóricosRESUMEN
This perspective combines various expertise to develop and analyse the concept of technology cascade for recycling waste plastics with the goal of displacing as much fossil crude oil as possible. It thereby presents archetype recycling technologies with their strengths and weaknesses. It then combines them in various cascades to process a representative plastic mix, and determines how much (fossil) naphtha could be displaced and at which energy consumption. The cascades rely on a limited number of parameters that are fully reported in supplementary information and that were used in a simple and transparent spreadsheet model. The calculated results bust several common myths in plastic recycling, e. g. by prioritizing here recycled volume over recycling efficiency, and prioritizing circular industry over circular products . It unravels the energy cost of solvent-based recycling processes, shows the key role of gasification and the possibility to displace up to 70 % of the fossil feedstock with recycled carbon, a recycling rate that compares well with that aluminium, steel or paper. It suggests that deeper naphtha displacement would require exorbitant amount of energy. It therefore argues for the need to complement recycling with the use of renewable carbon, e. g. based on biomass, to fully defossilise the plastic industry.
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Although multiple methods have been reported in the literature for the chemical recycling of poly(ethylene terephthalate) (PET), large-scale depolymerization is not yet widely employed. The main reasons for the limited adoption of chemical recycling of PET are the harsh conditions required and the lack of selectivity. In this study, the organocatalytic glycolysis of PET mediated by organic bases at low temperatures is studied, and routes to avoid the deactivation of the catalyst are explored. It is shown that the formation of terephthalic acid by uncontrolled hydrolysis leads to issues which can be resolved using potassium tert-butoxide as a cocatalyst. Finally, complex PET waste obtained from a mechanical recycling plant was depolymerized under optimized conditions, obtaining bis(2-hydroxyethyl) terephthalate yields >90% in less than 15 min at only 100 °C. These results open the way to efficient recycling of PET-enriched waste streams under milder conditions.
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Deodorization and, in a broader sense, the removal of volatile organic compounds (VOCs) from plastic waste have become increasingly important in the field of plastic recycling, and various new decontamination techniques have been developed. Both in research and industrial practice, the selection of VOCs has been random or unsubstantiated, making it difficult to compare studies and assess decontamination processes objectively. Thus, this study proposes the use of Statistical Molecular Design (SMD) and Quantitative Structure - Activity Relationship (QSAR) as chemometric tools for the selection of representative VOCs, based on physicochemical properties. Various algorithms are used for SMD; hence, several frequently used D-Optimal Onion Design (DOOD) and Space-Filling (SF) algorithms were assessed. Hereby, it was validated that DOOD, by dividing the layers based on the equal-distance approach without so-called 'Adjacent Layer Bias', results in the most representative selection of VOCs. QSAR models that describe VOC removal by water-based washing of plastic waste as a function of molecular weight, polarizability, dipole moment and Hansen Solubility Parameters Distance were successfully established. An adjusted-R2 value of 0.77 ± 0.09 and a mean absolute error of 24.5 ± 4 % was obtained. Consequently, by measuring a representative selection of VOCs compiled using SMD, the removal of other unanalyzed VOCs was predicted on the basis of the QSAR. Another advantage of the proposed chemometric selection procedure is its flexibility. SMD allows to extend or modify the considered dataset according to the available analytical techniques, and to adjust the considered physicochemical properties according to the intended process.
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Compuestos Orgánicos Volátiles , Relación Estructura-Actividad Cuantitativa , QuimiometríaRESUMEN
Solvent-based recycling of plastic waste is a promising approach for cleaning polymer chains without breaking them. However, the time required to actually dissolve the polymer in a lab environment can take hours. Different factors play a role in polymer dissolution, including temperature, turbulence, and solvent properties. This work provides insights into bottlenecks and opportunities to increase the dissolution rate of polystyrene in solvents. The paper starts with a broad solvent screening in which the dissolution times are compared. Based on the experimental results, a multiple regression model is constructed, which shows that within several solvent properties, the viscosity of the solvent is the major contributor to the dissolution time, followed by the hydrogen, polar, and dispersion bonding (solubility) parameters. These results also indicate that cyclohexene, 2-pentanone, ethylbenzene, and methyl ethyl ketone are solvents that allow fast dissolution. Next, the dissolution kinetics of polystyrene in cyclohexene in a lab-scale reactor and a baffled reactor are investigated. The effects of temperature, particle size, impeller speed, and impeller type were studied. The results show that increased turbulence in a baffled reactor can decrease the dissolution time from 40 to 7 min compared to a lab-scale reactor, indicating the importance of a proper reactor design. The application of a first-order kinetic model confirms that dissolution in a baffled reactor is at least 5-fold faster than that in a lab-scale reactor. Finally, the dissolution kinetics of a real waste sample reveal that, in optimized conditions, full dissolution occurs after 5 min.
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Biomass contains different macroconstituents (polysaccharides, lipids, and proteins) with nutritional and functional properties. However, after harvest or processing, stabilization of biomass is necessary to preserve the macroconstituents from degradation by microbial growth and enzymatic reactions. Because these stabilization methods affect the structure of the biomass, extraction of valuable macroconstituents can be impacted. Literature, in general, focuses on either stabilization or extraction, but systematic information on the interlinkage between these processes has rarely been reported. This review summarizes recent research on physical, biological, and chemical stabilization methods on macroconstituent extraction yields and functionalities. Often, freeze drying as a stabilization method resulted in a good extraction yield and functionality, independent of the macroconstituent. Less documented treatments, such as microwave drying, infrared drying, and ultrasound stabilization, result in better yields compared to conventional physical treatments. Biological and chemical treatments were rarely performed but could be promising as stabilization methods before performing an extraction step.
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Desecación , Tecnología , Biomasa , LiofilizaciónRESUMEN
In evaluating environmental sustainability with methodologies like life cycle assessment (LCA), recycling is usually credited for avoiding impacts from virgin material production. Consequently, the LCA results are influenced by the manner in which the substitutability of virgin by recycled materials is estimated. This study reviews how the scientific community assesses the technical substitutability of recycled materials in LCA. Accordingly, 49 peer-reviewed papers were in-depth analysed, considering aspects such as materials studied, type of substitution, recycled material (rMaterial) application, and life cycle stages (LCSs) where substitution was evaluated. The results show that 49% of the papers investigated material substitutability through technical and economic aspects. 51% of the articles did not consider the final application of the rMaterial. Plastics were the most studied material, and mass was the most used property to quantify technical substitutability. Certain materials were more analysed in specific LCSs (e.g., metals in the natural resource extraction stage). As 51% of the papers developed a new approach for substitutability calculation, this shows that substitutability is still a concept in development. It was noticed in 33% of the papers that substitutability values were taken from external sources, and in some cases were used without considering whether they were representative for a specific case. Aspects such as harmonization, transparency, and consideration of the application of recycled materials, therefore, require more attention in substitutability evaluation. Based on the results, a step-wise framework to measure technical substitutability at different LCSs was developed to guide researchers in including substitutability in LCA studies.
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Volatile organic compounds (VOCs), including odors, are still a key issue in plastic recycling, especially in case of flexible packaging. Therefore, this study presents a detailed qualitative and quantitative VOC analysis by applying gas chromatography on 17 categories of flexible plastic packaging that are manually sorted from bales of post-consumer flexible packaging (e.g., beverage shrink wrap, packaging for frozen food, packaging for dairy products, etc.). A total of 203 VOCs are identified on packaging used for food products, while only 142 VOCs are identified on packaging used for non-food products. Especially, more oxygenated compounds (e.g., fatty acids, esters, aldehydes) are identified on food packaging. With more than 65 VOCs, the highest number of VOCs is identified on packaging used for chilled convenience food and ready meals. The total concentration of 21 selected VOCs was also higher on packaging used for food products (totally 9187 µg/kg plastic) compared to packaging used for non-food packaging (totally 3741 µg/kg plastic). Hence, advanced sorting of household plastic packaging waste, e.g., via tracer-based sorting or watermarking, could open the door towards sorting on other properties than polymer type, such as mono- versus multi-material packaging, food versus non-food packaging or even their VOC profile, which might allow for tailoring washing procedures. Potential scenarios showed that sorting the categories with the lowest VOC load, which corresponds to half of the total mass of flexible packaging, could result in a VOC reduction of 56%. By producing less contaminated plastic film fractions and by tailoring washing processes recycled plastics can ultimately be used in a broader market segment.
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Plásticos , Compuestos Orgánicos Volátiles , Plásticos/química , Polímeros , Embalaje de Productos , Embalaje de Alimentos , ReciclajeRESUMEN
Due to the complexity and diversity of polyolefinic plastic waste streams and the inherent non-selective nature of the pyrolysis chemistry, the chemical decomposition of plastic waste is still not fully understood. Accurate data of feedstock and products that also consider impurities is, in this context, quite scarce. Therefore this work focuses on the thermochemical recycling via pyrolysis of different virgin and contaminated waste-derived polyolefin feedstocks (i.e., low-density polyethylene (LDPE), polypropylene (PP) as main components), along with an investigation of the decomposition mechanisms based on the detailed composition of the pyrolysis oils. Crucial in this work is the detailed chemical analysis of the resulting pyrolysis oils by comprehensive two-dimensional gas chromatography (GC × GC) and ICP-OES, among others. Different feedstocks were pyrolyzed at a temperature range of 430-490 °C and at pressures between 0.1 and 2 bar in a continuous pilot-scale pyrolysis unit. At the lowest pressure, the pyrolysis oil yield of the studied polyolefins reached up to 95 wt%. The pyrolysis oil consists of primarily α-olefins (37-42 %) and n-paraffins (32-35 %) for LDPE pyrolysis, while isoolefins (mostly C9 and C15) and diolefins accounted for 84-91 % of the PP-based pyrolysis oils. The post-consumer waste feedstocks led to significantly less pyrolysis oil yields and more char formation compared to their virgin equivalents. It was found that plastic aging, polyvinyl chloride (PVC) (3 wt%), and metal contamination were the main causes of char formation during the pyrolysis of polyolefin waste (4.9 wt%).
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Polietileno , Pirólisis , Polietileno/química , Temperatura , Plásticos/química , Polipropilenos/química , AceitesRESUMEN
Plastic packaging is usually heavily printed with inks to provide functional benefits. However, the presence of inks strongly impedes the closed-loop recycling of plastic films. Various media have already been studied for the deinking of plastic films, but there is little scientific insight into the effectiveness of different deinking techniques. Therefore, this study aims to obtain a systematic understanding by measuring the liquefaction and maximum solubility of 14 chemically different polymer resins in seven different media typically used in plastic deinking, such as acetone, ethyl acetate, sodium hydroxide solution, cetyltrimethylammonium bromide solution, formic acid, sulfuric acid, and N,N-dimethylcyclohexylamine. Our findings show that acid-based media are able to remove a broader range of polymer resins. Organic solvents are particularly effective against acrylics and related polymer resins. The deinking efficiency tests on pure resins are also confirmed by deinking four printed plastic films containing different classes of polymer resins. A basic cost and environmental impact analysis is given to evaluate scale-up potential of the deinking medium.
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Quality of recycling is a concept used by many authors in the scientific literature and the EU legislator. However, a clear definition of what is intended for quality of recycling and a framework for operationalising it is lacking. Most studies, while proposing indicators reflecting quality, leave the concept of quality largely undefined. Such lack of clarity is an obstacle to the conception of robust policies addressing recycling and circular economy. In this article, we review the available studies investigating on recycling quality, synthetize the approaches available and conclude suggesting a way forward for research to operationalise the definition to support circular economy policy measures and monitoring. Essentially, quality is not an on/off criterion. The definition of quality of recycling should consider that quality depends on technical characteristics of the recyclate, which determine if it is adequate (thus functional) for a certain end application or not. Furthermore, it should consider that the recyclate can be used in different end applications over different markets and that can be adequate for substitution of primary resources in certain applications, but less or not in others. At system-wide level, this results in a certain degree of virgin resource substitution. To this end, preserving functionality, i.e. minimising the recyclate loss of functions via functional recycling, is key. Drawing upon studies on waste management, life cycle assessment and resource dissipation, we link the concept of functionality to substitutability of virgin resources and broader suitability in the circular economy, striving to show the linkages between different perspectives.