Oral bioaccessibility of potentially toxic elements in various urban environmental media.

An important aspect of geochemical studies is determining health hazard of potentially toxic elements (PTEs). Key information on PTEs behaviour in the human body in case of their ingestion is provided with the use of in vitro bioaccessibility tests. We analysed and compared oral bioaccessibility of a wide range of PTEs (As, Cd, Ce, Cr, Cu, Hg, La, Li, Ni, Pb, Sb, Sn, Zn), including some that are not often studied but might pose a human health hazard, in soil, attic dust, street dust, and household dust, using Unified BARGE Method (UBM). Additionally, feasibility of usage of scanning electron microscope techniques in analyses of solid residuals of UBM phases was tested. Results show that bioaccessible fractions (BAFs) of PTEs vary significantly between individual samples of the same medium, between different media and between the gastric and gastro-intestinal phases. In soil, attic dust and street dust, bioaccessibility of individual PTE is mostly higher in gastric than in gastro-intestinal phase. The opposite is true for PTEs in household dust. In all four media, with the exception of Pb in household dust, among the most bioaccessible PTEs in gastric phase are Cd, Cu, Pb, and Zn. During the transition from the stomach to small intestine, the mean BAFs of most elements in soil, attic dust, and street dust decreases. The most bioaccessible PTEs in gastro-intestinal phase are Cu, Cd, Ni, and As. Micromorphological and chemical characterisation at individual particle level before and after bioaccessibility test contribute significantly to the understanding of oral bioaccessibility.

Pollution characteristics, associated risks, and possible sources of heavy metals in road dust collected from different areas of a metropolis in Vietnam.

Road dust samples were collected from different areas in Ho Chi Minh City (HCMC)-the largest city in Vietnam to explore pollution characteristics, ecological and human health risks, and sources of heavy metals (HMs). Results revealed the level of HMs found in the samples from residential and industrial zones of HCMC in the order of Mn > Zn > Cu > Cr > Pb > Ni > Co > As > Cd, Zn > Mn > Cu > Cr > Pb > Ni > Co > As > Cd. Due to the high enrichment of Cu, Zn in residential areas and Cu, Pb, Zn in industrial areas, the HM contamination in these areas remained moderate to severe. The findings also revealed a rising trend in the level of HMs in road dust from the east to the west of HCMC, and a heavy metal contamination hotspot in the west. In addition, industrial areas were more contaminated with HMs, posing greater associated risks than residential areas. Children living in urban areas of HCMC were found to be exposed to unacceptable health risks. Meanwhile, adults living in industrial areas face intolerable cancer risk. Among the nine HMs, Cd, Pb, and Cu posed the greatest ecological risk, while Cr and As were the main culprits behind health risks. HMs in road dust might derive from non-exhaust vehicular emissions, crustal materials, and industrial activities. The results suggested that industrial areas to the west of HCMC should focus more on reducing and controlling severe pollution of HMs.

Assessment of heavy metal pollution and preschool children health risk in urban street dusts from different functional areas in a typical industrial and mining city, NW China.

To assess the pollution characteristics and health risks associated with street dust exposure among preschool children in typical industrial and mining areas, we analyzed heavy metal concentrations of 20 urban street dusts in commercial area (CA), residential area (RA), scientific and educational area (SEA) and industrial and mining area (IMA) from Baiyin, NW China. The average concentrations of Cr, Mn, Ni, Cu, Zn, Cd, Pb, As and Hg were 614.96, 484.25, 1757.74, 6868.86, 893.19, 77.62, 1473.99, 15.01 and 0.59 mg·kg-1, respectively. The ecological risk indexes for Cd, Cu and Hg were found as 20,075.20, 1425.07 and 1174.86, respectively, and the ecological risk was extremely high. The pollution load indexes (PLI) were > 1 for all four functional areas. The total hazard index (THI) for different functional areas were more than 1, and the main exposure pathway for children was ingestion route. Heavy metals in street dust of the IMA had the highest THI for children (43.88), and HI of Pb was being most significant (17.38). In addition, the carcinogenic risk to children via the respiratory route was acceptable. Furthermore, factor analysis and cluster analysis classified heavy metals into two groups, indicating common anthropogenic sources for Cr, Ni, Cu, Zn, Cd, Pb, As and Hg. In conclusion, urban street dusts from industrial and mining area of Baiyin, NW China were found polluted by heavy metals and the pollution would pose an obvious non-carcinogenic risk to preschool children.

Temporal variation of heavy metals in sewage sludge in typical cities in Gansu Province, northwest China.

To investigate the temporal behaviors of heavy metals in sewage sludge in typical cities of industrial, industrial-agricultural, agricultural, or energy focused. Samples were collected every 10 days for a period of 1 year in four types of cities of Lanzhou, Tianshui, Qingyang, and Zhangye. The average annual values for all four cities were Cd (1.59-3.16 mg/kg), Pb (41.9-55.1 mg/kg), Cr (63.8-92.0 mg/kg), Cu (75.7-92.6 mg/kg), Zn (498-612 mg/kg), and Ni (3.66-4.25 mg/kg). The highest values were observed in June for Cd, Cr, and Zn, at Lanzhou and Tianshui. At Qingyang and Zhangye, the Cd, Cr, and Zn contents were stable throughout the year. There was a similar monthly change among the four cities regarding the levels of Ni content, and it was far below the background value. The monthly fluctuations in Cd, Pb, Cr, and Zn are mainly due to street dust effect. For cities with a developed industry, the impact of street dust during the first rains of the year on sewage sludge's heavy metal content must be highlighted as being of particular importance.

Integration of chemical fractionation, Mössbauer spectrometry, and magnetic methods for identification of Fe phases bonding heavy metals in street dust.

Street dust is one of the most important carriers of heavy metals (HMs) originating from natural and anthropogenic sources. The main purpose of the work was to identify which of Fe-bearing phases bind HMs in street dust. Magnetic parameters of the Fe-bearing components, mainly magnetically strong iron oxides, are used to assess the level of HM pollution. Chemical sequential extraction combined with magnetic methods (magnetic susceptibility, magnetization, remanent magnetization) allowed determining the metal-bearing fractions and identifying the iron forms that are mostly associated with traffic-related HMs. The use of Mössbauer spectrometry (MS) supplemented by magnetic methods (thermomagnetic curves and psarameters of hysteresis loops) enabled precise identification and characterization of iron-containing minerals. The classification of HMs into five chemical fractions differing in mobility and bioaccessibility revealed that iron is most abundant (over 95%) in the residual fraction followed by the reducible fraction. HMs were present in reducible fraction in the following order: Pb>Zn>Mn>Cr>Ni>Fe>Cu, while they bound to the residual fraction in the following order: Fe>Ni>Cr>Mn>Pb>Cu>Zn. The signature of the anthropogenic origin of street dust is the presence of strongly nonstoichiometric and defected grains of magnetite and their porous surface. Magnetite also occurs as an admixture with maghemite, and with a significant proportion of hematite. A distinctive feature of street dust is the presence of metallic iron and iron carbides. Magnetic methods are efficient in the screening test to determine the level of HM pollution, while MS helps to identify the iron-bearing minerals through the detection of iron.

Contamination, probabilistic health risk assessment and quantitative source apportionment of potentially toxic metals (PTMs) in street dust of a highly developed city in north of Iran.

Street dust (SD) are the particulates that primarily originated from Earth's crust and secondary alteration and erosion of natural and anthropogenic materials. The multi-dimensional pollution and health risk assessment of potentially toxic metals (PTMs) in these particles remain unknown in the majority of world urban areas. The elemental concentration, mineralogy, and micro-morphology of street dust were determined by inductively coupled plasma mass spectrometry (ICP-MS), SEM-EDX, XRD, and petrographical observation. Multivariate statistical analysis combined with positive matrix factorization (PMF) and Monte-Carlo simulations were applied to source identification and health risk assessment of PTMs. A severe enrichment of Sb, Cu and Zn and moderate contamination of Sn, Pb, and Cr were observed in the samples particularly in the areas with higher loads of traffic. The results of geochemical indices showed that K, Al, Mn, and V have natural/geogenic origins. While Sb, Pb, Cr, Cu, and Zn showed an enrichment relative to the background values with dominant anthropogenic sources. The results were confirmed by source appointment techniques. The results of deterministic and probabilistic health risk assessment by Monte-Carlo simulations revealed the non-carcinogenic nature of As, Mn, and Pb for children mainly through skin and ingestion routes. It can be concluded that the chemical compound of street dust in Gorgan city is affected by both natural (loess deposits) and anthropogenic sources. Also, children are in the risk of exposure to PTMs in street dust more than adults.

Concentrations, distribution and potential health risks of organic ultraviolet absorbents in street dust from Tianjin, a megacity in northern China.

The distribution of organic ultraviolet absorbers (OUVAs) in outdoor dust remains poorly understood, especially in megacities. We measured the concentrations of 11 OUVAs in street dust from Tianjin, China, by a gas chromatography-mass spectrometry, and found total concentrations in the range of 10.3-129 ng/g. These OUVAs were prevalent in the study street dust, but their concentrations were much lower than those in indoor dust reported in other areas previously. Benzophenone and octocrylene were the dominant OUVAs, representing medians of 15.5% and 13.1% of total OUVA concentrations, respectively. Total concentrations of dust OUVAs in the industrial area were higher than the residential, cultural and new urban areas. Source assessment indicated that the OUVAs likely originated mainly from the manufacture and consumption of cosmetics and personal care products, and some may have been from the production and use of OUVA-containing consumer products. The calculated non-carcinogenic risks of OUVAs in street dust were low. Our results further confirmed that the OUVAs were prevalent in the environment, provide useful information for understanding potential risks of these chemicals and developing risk management strategies. Further studies are needed to investigate the occurrence, environmental behaviors and potential risks of these emerging contaminants in outdoor environment.

Human health risk of mercury in street dust: A case study of children in the vicinity of compact fluorescence lamp factory, Hanoi, Vietnam.

Urban dust has been contaminated with toxic heavy metals from various diffused sources. On August 28, 2019, the compact fluorescence lamp (CFL) factory that generates light for Rang Dong Light Source and Vacuum Flask in Hanoi City in Vietnam was accidentally fired. The assessment for Hg contamination and its human health impact 2 months after the incident was conducted in autumn 2019. The heavy Hg pollution is still found near CFL. Additionally, localized Hg pollution by air and wind direction was identified at sites in the northeast direction from CFL. Namely, in the area located downstream of the southwest monsoon wind, Hg had a trend higher than other directions. The hazard quotient (HQ) and the hazard index (HI) were evaluated by four routes of Hg exposure pathways. The HI values for children and adults in the most polluted site (Site 15) were 0.968 and 0.468, respectively. This meant that children who lived around this site and commuted to schools were the most at risk regarding the potential adverse health effects of Hg in street dust around the polluted areas. This study also showed that Hg levels were affected by wind direction and that the higher Hg levels in the most polluted sites resulted from the wind flow to the sites. This study revealed that street dust may be a useful tool for the assessment of human and environmental health.

Polycyclic aromatic hydrocarbons in street dust from different functional areas in Chengdu, China: seasonal variation and health risk assessment.

This is the first investigation that identified seasonal variation, possible sources and health risk of 16 PAHs in street dust sampled park area (PA), educational area (EA), commercial area (CA), residential area (RA), and traffic area (TA) of Chengdu, one of the new first-tier cities in China. The total PAHs (∑16PAHs) concentrations of averaging over two seasons varied from 2.15 to 10.6 mg/kg with a median value of 4.61 mg/kg and in winter (5.48 ± 1.52 mg/kg) were significantly higher than that in summer (4.04 ± 0.91 mg/kg). The highest ∑16PAHs concentration was found in TA (median 6.74 mg/kg). Statistical analysis results indicated that mixture sources of petroleum combustion and combustion of biomass and coal seem to be the primary source of the PAHs in street dust. Carcinogenic risk by incremental lifetime cancer risk (ILCR) model for PAHs in street dust indicates an acceptable potential cancer risk for residents. The same sequences of cancer risk to be observed for both children and adults among different functional areas: TA > CA > EA > RA > PA. The results provided advice for habitants in Chengdu to encourage outdoor activities in parks and residential areas and minimize traffic areas and commercial areas.

Pollution status and human health risk assessment of potentially toxic elements and polycyclic aromatic hydrocarbons in urban street dust of Tyumen city, Russia.

This study investigated levels and sources of pollution and potential health risks associated with potentially toxic elements (PTEs) and polycyclic aromatic hydrocarbons (PAHs) in urban street dust collected from Tyumen city, a large transport centre with one of the highest motorization rates in Russia. Twenty street dust samples were collected from four grades of roads in five different land use areas. Research methods included measurements of physical and chemical properties of street dust, concentrations of 18 PTEs using inductively coupled plasma mass spectrometry, 12 PAHs using high-performance liquid chromatography, and statistical analysis of the data. Concentrations of Ni, Cr, Sb, and Mo, as well as medium and high molecular weight PAHs in urban street dust, were notably higher than in soils within the city, which indicates that transport is the main source of these elements. Concentrations of Cu, Cd, Pb, Zn, Mn, and As in street dust of Tyumen were lower compared to many large cities, while Cr, Ni, and Co were higher. Concentrations of PAH were comparable to other large nonindustrial cities. Total contamination of street dust by both PTEs and PAHs showed more robust relationships with the number of roadway lanes rather than land use. The estimated carcinogenic risks were low in 70% of samples and medium in 30% of samples. Noncarcinogenic risks were attributed to exposure to Co, Ni, V, and As. The total noncarcinogenic risk for adults was found to be negligible, while the risk was found to be moderate for children.

Risk assessment and spatial distribution of heavy metal in street dusts in the densely industrialized area.

Street dust samples can be used as an indicator for pollution monitoring especially in big cities. Various environmental problems have been experienced in Dilovasi, Turkey, and studies have been carried out in many different areas; however, no study has been conducted to examine the heavy metal content in street dusts. Therefore, in this study, 20 heavy metals, namely Si, Fe, Al, Zn, Mn, Ti, Cr, Ba, Pb, Ni, Sr, V, Co, Cd, Sb, As, Sn, Mo, Sc and Ag, in the street dusts of Dilovasi were investigated at 40 sampling points. Samples were analyzed with ICP-MS and ICP-OES. The concentrations were from 0.01 mg/kg for Ag to 42,645.48 mg/kg for Si. The Igeo values were in the range of 0.02 for Ag and 8.03 for V. The average EF value was 29.67, which indicates a very high pollution level. ERI was found as 300.74. This value being 300-600 indicates a considerable ecological risk level for the region. According to PCA, the predominant anthropogenic contribution of metal pollution in this area was due to traffic and vehicle-related activities and industrial activities and their waste. Metal pollution from residential areas and natural resources was relatively low, but it was another source of pollution.

Heavy metal concentrations and health risk assessment in urban soils of Neyshabur, Iran.

This study aimed to determine and analyze heavy metal pollution in the street dust of Neyshabur city of Iran. In this regard, the concentration of ten heavy metals, including Al, Fe, Mn, Zn, Cu, Cr, Ni, Pb, Co, and Cd, was measured at 60 street dust samples. The samples from Neyshabur city in three zones were collected, including high traffic, low traffic, and rural. Twenty samples in each area, 10-sample in summer and 10-sample in winter, were studied. The average concentration of the target heavy metals (mg kg-1) in the street dust samples was as follows: 50514.09 for Al, 42473.33 for Fe, 647.4 for Mn, 230.07 for Zn, 146.44 for Cu, 96.18 for Cr, 73.25 for Ni, 40.56 for Pb, 14.86 for Co, and 1.32 for Cd. Based on the findings, it can be concluded that non-carcinogenic risk assessment for all quantified heavy metals was less than the allowed values. In addition, the carcinogenic risk assessment of these metals indicated high carcinogenic-risk indexes through exposure to Cr for adults and exposure to Cr, Co, and Ni for children. As a consequence of this investigation, efforts to avoid the transmission of heavy metals in the environmental soil of Neyshabur city should be encouraged.

Methylsiloxanes in street dust from Hefei, China: Distribution, sources, and human exposure.

Methylsiloxanes are widely found in the environment and have been of increasing concern because of their strong resistance to degradation and potential toxicity to organisms. However, little is known about the distributions of these chemicals in street dust and the associated human health risks. This study investigated three cyclic (D4-D6) and nine linear methylsiloxanes (L5-L13) in street dust from Hefei, China and found total concentrations in the range of 183-1030 (median, 527) ng/g dry weight. The linear congeners were dominant and represented a median of 85.3% of the total methylsiloxanes. D5 contributed 90.0% of the total concentrations of cyclic methylsiloxanes. In this study, higher concentrations of dust methylsiloxanes were found in the industrial area relative to the other functional areas. A source assessment indicated that the linear and cyclic methylsiloxanes in the street dust were mainly from the industrial and traffic activities, respectively, in addition to important sources of the use of siloxanes-containing products. The estimated median daily intakes of total methylsiloxanes through street dust were 0.037 and 0.476 ng/kg-bw/d for adults and children, respectively, under high-exposure scenarios. More research is needed to characterize the occurrence of methylsiloxane in various exposure sources and the associated adverse effects on human health.

Site environment type - The main factor of urban road dust toxicity?

The main objective of the study was to determine the effects of the water extracts of urban road dust (URD) samples on the growth inhibition and mortality rate of Heterocypris incongruens in various site environment type. We collected 24 samples of the road dust close to highways, main roads, crossroads as well as at other places i.e. residential area, and suburbs. We determined the selected metals (Al, As, Ba, Cd, Co, Cr, Cu, Ga, Mg, Mn, Mo, Ni, Pb, Rb, Sr, Ti, Tl, V and Zn) content of the water extracts of these samples as well as we tested the toxicity of the water extracts of URD samples using a commercial test Ostracodtoxkit F. We observed the lowest values of the growth inhibition of H. incongruens for residential areas and suburbs (<50%). The highest growth inhibition we found for water extracts of URD samples collected at the main roads in the Katowice urban area and crossroads in the urban areas. Although the mortality and growth inhibition of H. incongruens were related to the road traffic emissions it was impossible to clearly relate this finding with the urban site category.

Exploration of the variations and relationships between trace metal enrichment in dust and ecological risks associated with rapid urban expansion.

Trace metals in street dust originate from many natural and anthropogenic sources and may directly or indirectly affect daily life and health. Here, the enrichment factor (EF), an efficient parameter to assess the contamination by trace metals, was evaluated and compared in four different zones of the urban area of Nanchang city during different seasons. Results showed that EFs of trace metals have regional seasonal variations. The EF range of Cr, Ni, Cu, Zn, As, Cd and Pb were found to be (0.76-16.38), (0.66-9.06), (1.09-169.58), (1.52-36.16), (0.44-7.17), (2.07-78.38), (0.95-20.94), respectively. These values indicate minimal to significant pollution. The EF values of Zn, Cd and Pb in street dust show very similar variations as their median and mean values of EF are higher in certain zones, and their seasonal variations are similar. The Ni and As results suggest that anthropogenic influences for these elements are not significant. The Ni may be influenced by land use type rather than point sources and As may be attributed to natural sources. The Principal Component Absolute Scores - Multivariate Linear Regression (PCAS-MLR) model was used to identify the types and contributions of trace metal sources. The main sources of trace metals in dust were found to be industrial discharges and traffic emissions. However, the percentages of their contributions have significant regional differences. The relationship between the EF of trace metals and the ecological risk index (ERI) was also investigated, and indicates that seriously polluted areas correspond to high ERI regions. The land use types and characteristics of the source jointly affects the relationship between EFs and ERI.

Response of antimony distribution in street dust to urban road traffic conditions.

Little is known about the relationship between traffic congestion and antimony (Sb) distribution in street dust, which is essential for Sb control and emission reduction in urban areas. Sb concentrations and mass load of the street dust collected in 19 cities of China were determined before investigating the mechanism of traffic influence on Sb distribution through diverse statistical means. The results showed that the Sb concentrations in each city were 1.10-4.76 times higher than the local background values. Sb concentrations in transportation areas were significantly higher than those in residential and industrial areas, and were significantly affected by road network density. The effect of congestion on Sb load of street dust was influenced by vehicle flowrate. Only when the vehicle flowrate was high, the traffic congestion would promote the increase of Sb load obviously. The improved accounting method showed that the Sb dissipation from brake wear in major Chinese cities were higher than that in Stockholm, Sweden, in 2005. The latent path analysis illustrated that a 1% increase in congestion index was correlated with a 0.886% increase in the Sb load. Compared with Switzerland, which has a typical industrialized Sb consumption pattern, China needs to recycle brake pads in addition to taking various measures to alleviate traffic congestion and reduce brake pad wear, despite the fact that the maximum health risk of Sb was far below the safety threshold. This study will provide valuable insights for urban traffic management and brake pad recycling.

Concentration of heavy metals in street dust: an implication of using different geochemical background data in estimating the level of heavy metal pollution.

Geochemical background data are used to distinguish between the sources of heavy metal (natural or anthropogenic) and to categorize the level of heavy metal pollution. In this study, we present the results of using different geochemical backgrounds (BG1-BG3) to establish the level of heavy metal pollution in street dust in Warsaw, Poland. We applied individual and collective indicators calculated with respect to the following backgrounds: (1) upper continental crust (UCC) (BG1), (2) the regional geochemical background established for Quaternary surface deposits of the Mazovian region (Poland) (parent geological material occurring in the studied area, Warsaw, Poland) (BG2), and (3) the minimal values of the concentration of heavy metals determined for the real street dust sample collectives from Warsaw (BG3). The assessment of the heavy metals pollution of street dust significantly depended on the background values used in the calculation of individual and collective indicators. Street dust was classified as unpolluted for almost all the heavy metals based on the values of indicators calculated for UCC data. The effect of traffic-related pollution was detected more precisely based on the values of indicators calculated for BG2 and BG3. The naturally elevated concentrations of heavy metals in UCC data can be responsible for the underestimation of pollution impact in street dust. When relatively low concentration of heavy metals is only observed, the application of BG2 or BG3 background data, which better correspond to the geogenic material in street dust, allows to realistically reflect the level of pollution from moving vehicles.

Potentially toxic elements and polycyclic aromatic hydrocarbons in street dust of Yazd, a central capital city in Iran: contamination level, source identification, and ecological-health risk assessment.

Contamination level, source, and ecological-health risk of potentially toxic elements (PTEs) and polycyclic aromatic hydrocarbons (PAHs) in the street dust of Yazd, a central capital city in Iran, were investigated for the first time regarding samples collected from 21 sites. Geochemical indices pointed out an enrichment trend of [Formula: see text] and an ecological risk trend of [Formula: see text]. The ecological risk indices of PAHs reflected high ecological risk for pyrene (Pyr). The statistical approach along with the isomeric ratios of PAHs suggested that the traffic-related sources, such as wearing of tires and brake pads, and the vehicular exhaust emissions were greatly responsible for the elevated concentrations of Pb, Cu, Sb, and PAHs, while Al, Ni, Co, V, Mn, As, and, to a lesser extent, Fe, Zn, Mo, and Cr were mainly influenced by geogenic sources. The human health risk assessment of PTEs and PAHs reflected that As, Cr, and Pb pose the highest non-carcinogenic risk in adults and children, compared with other PTEs and also PAHs. The carcinogenic health risk of Pb in the children and PAHs in both subpopulations was high for cancer development.

Spatial distribution and correlations among elements in smaller than 75 µm street dust: ecological and probabilistic health risk assessment.

This study aimed to investigate spatial distribution, correlations among elements and ecological and probabilistic health risk assessment in smaller than 75 µm street dust in Kerman city, Iran. Street dust samples were collected from 35 different points. Elements were detected by ICP-AES. Pollution degree was characterized through Enrichment Factor (EF), Contamination Factor (CF), Geo-accumulation Index (Igeo) and Potential Ecological Risk (PER). The health risk was assessed using the Monte Carlo simulation method. The mean values of elements were in the order of Al > Mn > Zn > Cu > V > Pb > Cr > Ni > Li > As > Co > Mo > Sb > Cd > Ag. The results of Principal Component Analysis (PCA) and Hierarchical Cluster Analysis (HCA) showed that Al, As, Co, Li, Mn and V were possibly derived from natural sources (local soil), while traffic and mining activities were proposed as the main source of Cd, Cr, Cu, Mo, Ni, Pb, Sb and Zn. The order of EF and CF mean values decreased as follows: Mn > Ag > Cu > Zn > Pb > Sb > Mo > Li > Co > V > Cd > As > Cr > Ni. In addition, 73% of Cu and 35% of Zn, Ag and Mn had significant enrichment in the street dust samples. Also, Ag and Mn were categorized in the significant and very significant pollution category. In terms of the PER index, all samples could be classified at low-risk category. Ingestion of street dust was the significant route for exposure of residents of Kerman to the elements studied. No significant ecological hazards and health risks were observed from street dust in the study area in the period of the study. The improvement in the fuels quality and development of green spaces can be suggested to control natural and anthropogenic street dust pollution sources in the Kerman city.

Magnetic monitoring of topsoil and street dust in Xinyang (China) and their environmental implications.

The magnetic measurement is an effective tool to identify the source of pollutants and diagnose the urban pollution. In this study, 132 group samples (that topsoil and street dust were sampled at the same location is regarded as a group) were collected from Xinyang, central eastern China. In addition, the background samples (19 topsoils under woodland around the outskirts) were also sampled. Herein, the aim was to investigate and compare the magnetic characteristics of both topsoil and street dust, and further to discuss the source and environmental implications using magnetic and diffuse reflection spectrum methods. The following points are highlighted: (1) the primary magnetic carrier of both materials was magnetite and that of the background sample were magnetite and maghemite. Furthermore, the ferrimagnetic mineral concentration and magnetic domain follow the order: street dust > topsoil > background sample. (2) The source of both materials was mainly from anthropogenic activities (e.g. industrial and traffic vehicles). The difference between them was the contribution related to natural sources (e.g. parent materials), which was negligible in street dust, and played a secondary role in topsoil. (3) Both materials showed that areas with a higher intensity of anthropogenic activities had higher pollution level, whereas areas with a lower anthropogenic intensity had lower pollution level.