Force-Induced Alignment of Nanofibrillated Bacterial Cellulose for the Enhancement of Cellulose Composite Macrofibers.

Bacterial cellulose, as an important renewable bioresource, exhibits excellent mechanical properties along with intrinsic biodegradability. It is expected to replace non-degradable plastics and reduce severe environmental pollution. In this study, using dry jet-wet spinning and stretching methods, we fabricate cellulose composite macrofibers using nanofibrillated bacterial cellulose (BCNFs) which were obtained by agitated fermentation. Ionic liquid (IL) was used as a solvent to perform wet spinning. In this process, force-induced alignment of BCNFs was applied to enhance the mechanical properties of the macrofibers. The results of scanning electron microscopy revealed the well-aligned structure of BCNF along the fiber axis. The fiber prepared with an extrusion rate of 30 m min-1 and a stretching ratio of 46% exhibited a strength of 174 MPa and a Young's modulus of 13.7 GPa. In addition, we investigated the co-spinning of carboxymethyl cellulose-containing BCNF with chitosan using IL as a "container", which indicated the compatibility of BCNFs with other polysaccharides. Recycling of the ionic liquid was also verified to validate the sustainability of our strategy. This study provides a scalable method to fabricate bacterial cellulose composite fibers, which can be applied in the textile or biomaterial industries with further functionalization.

Enhancing the Mechanical Properties of Regenerated Cellulose through High-Temperature Pre-Gelation.

This paper investigates the effects of pre-gelation on cellulose dissolved in LiCl/DMAc solutions to enhance the properties of regenerated cellulose materials. This study focuses on characterizing the crystallinity, molecular orientation, and mechanical performance of cellulose fibers and hydrogels prepared with and without pre-gelation treatment. X-ray diffraction (XRD) analysis reveals that crystallinity improvement from 55% in untreated fibers to 59% in fibers pre-gelled for 3 and 7 days, indicating a more ordered arrangement of cellulose chains post-regeneration. Additionally, XRD patterns show improved chain alignment in pre-gelled fibers, as indicated by reduced full width at half the maximum of Azimuthal scans. Mechanical testing demonstrates a 30% increase in tensile strength and a doubling of the compression modulus for pre-gelled fibers compared to untreated fibers. These findings underscore the role of pre-gelation in optimizing cellulose material properties for applications ranging from advanced textiles to biomaterials and sustainable packaging. Future research directions include further exploration of the structural and functional benefits of pre-gelation in cellulose processing and its broader implications in material science and engineering.

Transformation of Specific Dispersion Interactions between Cellulose and Polyacrylonitrile in Solutions into Covalent Interactions in Fibers.

Morphological transformations in emulsions of cellulose and polyacrylonitrile (PAN) ternary copolymers containing acrylonitrile, methyl acrylate, and methylsulfonate comonomers in N-methylmorpholine-N-oxide were studied over the entire range of concentrations depending on temperature and intensity of the deformation action. Based on the morphological and rheological features of the system, the temperature-concentration range of spinnability of mixed solutions was determined, and composite fibers were spun. The fibers are characterized by a heterogeneous fibrillar texture. Studies of the structure of the fibers, carried out using X-ray diffraction analysis, revealed a decrease in cellulose crystallinity with an increase in the content of PAN. The study of the thermal properties of the obtained fibers, carried out using DSC, and chemical transformations in them in a wide temperature range by high-temperature diffuse reflection IR spectroscopy made it possible to reveal a new intense exothermic peak on the thermograms at 360 °C, which according to the IR spectra corresponds to the transformation of intermacromolecular physical interactions of the PAN and cellulose into covalent bonds between polymers. In addition, the ester groups found during the thermal treatment of the PAN part of the composite fibers in the pyrolysis zone can have a key effect on the process of their further carbonization.

Efficacy of Large Groove Texture on Rat Sciatic Nerve Regeneration In Vivo Using Polyacrylonitrile Nerve Conduits.

Physical guidance cues play an important role in enhancing the efficiency of nerve conduits for peripheral nerve injury repair. However, very few in vivo investigations have been performed to evaluate the repair efficiency of nerve conduits with micro-grooved inner textures. In this study, polyacrylonitrile nerve conduits were prepared using dry-jet wet spinning, and micro-grooved textures were incorporated on the inner surface. The nerve conduits were applied to treat 10 mm sciatic nerve gaps in Sprague-Dawley (SD) rats. Sixteen weeks following implantation, nerve function was evaluated based on heat sensory tests, electrophysiological assessments and gastrocnemius muscle mass measurements. The thermal latency reaction and gastrocnemii weight of SD rats treated with grooved nerve conduits were almost 25% faster and 60% heavier than those of SD rats treated with smooth nerve conduits. The histological and immunohistochemical stain analyses showed the repair capacity of inner grooved conduits was found to be similar to that of autografts. These results suggest that grooved nerve conduits with groove width larger than 300 µm significantly improve peripheral nerve regeneration by introducing physical guidance cues. The obtained results can support the design of nerve conduits and lead to the improvement of nerve tissue engineering strategies.

Dry-Jet Wet Spinning of Thermally Stable Lignin-Textile Grade Polyacrylonitrile Fibers Regenerated from Chloride-Based Ionic Liquids Compounds.

In this paper, we report on the use of amorphous lignin, a waste by-product of the paper industry, for the production of high performance carbon fibers (CF) as precursor with improved thermal stability and thermo-mechanical properties. The precursor was prepared by blending of lignin with polyacrylonitrile (PAN), which was previously dissolved in an ionic liquid. The fibers thus produced offered very high thermal stability as compared with the fiber consisting of pure PAN. The molecular compatibility, miscibility, and thermal stability of the system were studied by means of shear rheological measurements. The achieved mechanical properties were found to be related to the temperature-dependent relaxation time (consistence parameter) of the spinning dope and the diffusion kinetics of the ionic liquids from the fibers into the coagulation bath. Furthermore, thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), and dynamic mechanical tests (DMA) were utilized to understand in-depth the thermal and the stabilization kinetics of the developed fibers and the impact of lignin on the stabilization process of the fibers. Low molecular weight lignin increased the thermally induced physical shrinkage, suggesting disturbing effects on the semi-crystalline domains of the PAN matrix, and suppressed the chemically induced shrinkage of the fibers. The knowledge gained throughout the present paper allows summarizing a novel avenue to develop lignin-based CF designed with adjusted thermal stability.

Upcycling of cotton polyester blended textile waste to new man-made cellulose fibers.

The creation of a circular economy for cellulose based textile waste is supported by the development of an upcycling method for cotton polyester blended waste garments. We present a separation procedure for cotton and polyester using [DBNH] [OAc], a superbase based ionic liquid, which allows the selective dissolution of the cellulose component. After the removal of PET, the resulting solution could be employed to dry-jet wet spin textile grade cellulose fibers down to the microfiber range (0.75-2.95 dtex) with breaking tenacities (27-48 cN/tex) and elongations (7-9%) comparable to commercial Lyocell fibers made from high-purity dissolving pulp. The treatment time in [DBNH] [OAc] was found to reduce the tensile properties (<52%) and the molar mass distribution (<51%) of PET under certain processing conditions.

The effect of hydration on the micromechanics of regenerated cellulose fibres from ionic liquid solutions of varying draw ratios.

Regenerated cellulose fibres - Ioncell-F, have been prepared with different draw ratios from cellulose solution in 1,5-diazabicyclo[4.3.0]non-5-ene-1-ium acetate ([DBNH]OAc) ionic liquid. Properties of the fibres were investigated in dry and wet conditions. The stiffness of fibres decreased on average 5 times upon the hydration while the tensile strength remained at around 70% of the initial value. The effect of hydration on the deformation mechanisms and mechanical properties was addressed using Raman spectroscopy. Bands located at 1095cm(-1) and 1414cm(-1) corresponding to the glucosidic linkage C-O-C and side groups C-O-H were followed upon straining. Raman band shifts were observed indicating molecular deformations. Moreover, the hydration of fibres altered the shifting rates implying changes in the molecular micromechanics. It is suggested that hydration affects inter-chain hydrogen bonds thus resulting in the slippage of the chains and lower stiffness of fibres. Some discrepancies from the series aggregate model have been observed which is indicative of changes in the deformation mechanisms upon hydration of the fibres.