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Single Scan 2D NMR Spectroscopy on a 25 T Bitter Magnet.
Shapira, Boaz; Shetty, Kiran; Brey, William W; Gan, Zhehong; Frydman, Lucio.
Afiliación
  • Shapira B; Department of Chemical Physics, Weizmann Institute of Science, 76100 Rehovot, Israel.
Chem Phys Lett ; 442(4-6): 478-482, 2007 Jul 16.
Article en En | MEDLINE | ID: mdl-18037970
2D NMR relies on monitoring systematic changes in the phases incurred by spin coherences as a function of an encoding time t(1), whose value changes over the course of independent experiments. The intrinsic multiscan nature of such protocols implies that resistive and/or hybrid magnets, capable of delivering the highest magnetic field strengths but possessing poor temporal stabilities, become unsuitable for 2D NMR acquisitions. It is here shown with a series of homo- and hetero-nuclear examples that such limitations can be bypassed using recently proposed 2D "ultrafast" acquisition schemes, which correlate interactions along all spectral dimensions within a single scan.

Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Chem Phys Lett Año: 2007 Tipo del documento: Article País de afiliación: Israel

Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Chem Phys Lett Año: 2007 Tipo del documento: Article País de afiliación: Israel