Single Scan 2D NMR Spectroscopy on a 25 T Bitter Magnet.
Chem Phys Lett
; 442(4-6): 478-482, 2007 Jul 16.
Article
en En
| MEDLINE
| ID: mdl-18037970
2D NMR relies on monitoring systematic changes in the phases incurred by spin coherences as a function of an encoding time t(1), whose value changes over the course of independent experiments. The intrinsic multiscan nature of such protocols implies that resistive and/or hybrid magnets, capable of delivering the highest magnetic field strengths but possessing poor temporal stabilities, become unsuitable for 2D NMR acquisitions. It is here shown with a series of homo- and hetero-nuclear examples that such limitations can be bypassed using recently proposed 2D "ultrafast" acquisition schemes, which correlate interactions along all spectral dimensions within a single scan.
Texto completo:
1
Colección:
01-internacional
Banco de datos:
MEDLINE
Idioma:
En
Revista:
Chem Phys Lett
Año:
2007
Tipo del documento:
Article
País de afiliación:
Israel