Silaphenylmercuric triflate catalyzed reactions: synthesis of a solid-supported mercuric salt catalyst.
Angew Chem Int Ed Engl
; 48(7): 1244-7, 2009.
Article
en En
| MEDLINE
| ID: mdl-19137523
ABSTRACT
Let it flow, let it flow A procedure to generate the first solid-supported mercuric salt, silaphenylmercuric triflate, is described. Silaphenylmercuric triflate showed remarkable catalytic activity for an indole synthesis, furanoyne cyclization, arylyne cyclization, and tandem carbocyclizations. An efficient flow reaction system for indole synthesis and arylyne cyclization is also described (see figure).
Texto completo:
1
Colección:
01-internacional
Banco de datos:
MEDLINE
Asunto principal:
Compuestos Organomercuriales
/
Mesilatos
/
Alquinos
/
Indoles
Idioma:
En
Revista:
Angew Chem Int Ed Engl
Año:
2009
Tipo del documento:
Article
País de afiliación:
Japón