Synthetic, structural, and theoretical investigation of guanidinate complexes containing planar Cu(6) cores.
Inorg Chem
; 48(11): 4619-21, 2009 Jun 01.
Article
en En
| MEDLINE
| ID: mdl-19388654
ABSTRACT
The addition of diethylcyanamide to a tetrahydrofuran solution of lithium dialkylamide LiN(CH(3))(2) or Li NCH(2)CH(2)CH(2) CH(2), Li(PYR), results in the corresponding lithium 1,1,3,3-tetraalkylguanidinate, Li(TAG). The subsequent metathesis reaction of Li(TAG) with CuCl generates hexanuclear copper(I) complexes with the general formula [Cu(mu-TAG)](6), where TAG = DEDMG (1) and DEPYRG (2).
Texto completo:
1
Colección:
01-internacional
Banco de datos:
MEDLINE
Asunto principal:
Compuestos Organometálicos
/
Cobre
/
Guanidinas
Idioma:
En
Revista:
Inorg Chem
Año:
2009
Tipo del documento:
Article
País de afiliación:
Estados Unidos