Polyhedral magnetite nanocrystals with multiple facets: facile synthesis, structural modelling, magnetic properties and application for high capacity lithium storage.
Chemistry
; 18(2): 488-97, 2012 Jan 09.
Article
en En
| MEDLINE
| ID: mdl-22147554
ABSTRACT
Polyhedral magnetite nanocrystals with multiple facets were synthesised by a low temperature hydrothermal method. Atomistic simulation and calculations on surface attachment energy successfully predicted the polyhedral structure of magnetite nanocrystals with multiple facets. X-ray diffraction, field emission scanning electron microscopy, and high resolution transmission microscopy confirmed the crystal structure of magnetite, which is consistent with the theoretical modelling. The magnetic property measurements show the superspin glass state of the polyhedral nanocrystals, which could originate from the nanometer size of individual single crystals. When applied as an anode material in lithium ion cells, magnetite nanocrystals demonstrated an outstanding electrochemical performance with a high lithium storage capacity, a satisfactory cyclability, and an excellent high rate capacity.
Texto completo:
1
Colección:
01-internacional
Banco de datos:
MEDLINE
Asunto principal:
Óxido Ferrosoférrico
/
Nanopartículas
/
Imanes
/
Litio
Tipo de estudio:
Prognostic_studies
Idioma:
En
Revista:
Chemistry
Asunto de la revista:
QUIMICA
Año:
2012
Tipo del documento:
Article
País de afiliación:
Australia