Catalytic Isonitrile Insertions and Condensations Initiated by RNC-X Complexation.
Adv Synth Catal
; 356(10): 2135-2196, 2014 Jul 07.
Article
en En
| MEDLINE
| ID: mdl-25484847
ABSTRACT
Isonitriles are delicately poised chemical entities capable of being coaxed to react as nucleophiles or electrophiles. Directing this tunable reactivity with metal and non-metal catalysts provides rapid access to a large array of complex nitrogenous structures ideally functionalized for medicinal applications. Isonitrile insertion into transition metal complexes has featured in numerous synthetic and mechanistic studies, leading to rapid deployment of isonitriles in numerous catalytic processes, including multicomponent reactions (MCR). Covering the literature from 1990-2014, the present review collates reaction types to highlight reactivity trends and allow catalyst comparison.
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1
Colección:
01-internacional
Banco de datos:
MEDLINE
Idioma:
En
Revista:
Adv Synth Catal
Año:
2014
Tipo del documento:
Article
País de afiliación:
Estados Unidos