Deuteration enhances catalyst lifetime in palladium-catalysed alcohol oxidation.

Armenise, Nicola; Tahiri, Nabil; Eisink, Niek N H M; Denis, Mathieu; Jäger, Manuel; De Vries, Johannes G; Witte, Martin D; Minnaard, Adriaan J

Armenise, Nicola; Tahiri, Nabil; Eisink, Niek N H M; Denis, Mathieu; Jäger, Manuel; De Vries, Johannes G; Witte, Martin D; Minnaard, Adriaan J.

Afiliación

Armenise N; Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 7, 9747 AG Groningen, The Netherlands. A.J.Minnaard@rug.nl.
Tahiri N; Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 7, 9747 AG Groningen, The Netherlands. A.J.Minnaard@rug.nl.
Eisink NN; Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 7, 9747 AG Groningen, The Netherlands. A.J.Minnaard@rug.nl.
Denis M; Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 7, 9747 AG Groningen, The Netherlands. A.J.Minnaard@rug.nl.
Jäger M; Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 7, 9747 AG Groningen, The Netherlands. A.J.Minnaard@rug.nl.
De Vries JG; Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 7, 9747 AG Groningen, The Netherlands. A.J.Minnaard@rug.nl.
Witte MD; Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 7, 9747 AG Groningen, The Netherlands. A.J.Minnaard@rug.nl.
Minnaard AJ; Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 7, 9747 AG Groningen, The Netherlands. A.J.Minnaard@rug.nl.

Chem Commun (Camb) ; 52(10): 2189-91, 2016 Feb 04.

Article en En | MEDLINE | ID: mdl-26725590

ABSTRACT

ABSTRACT

The catalyst palladium/2,9-CD3-phenanthroline has a 1.8 times higher turnover number than its non-deuterated counterpart in the aerobic alcohol oxidation of methyl glucoside and allows the regioselective oxidation with dioxygen as the terminal oxidant.

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Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2016 Tipo del documento: Article País de afiliación: Países Bajos

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