Synthesis of Highly Functionalized Triarylbismuthines by Functional Group Manipulation and Use in Palladium- and Copper-Catalyzed Arylation Reactions.
J Org Chem
; 81(13): 5401-16, 2016 07 01.
Article
en En
| MEDLINE
| ID: mdl-27231755
ABSTRACT
Organobismuthines are an attractive class of organometallic reagents that can be accessed from inexpensive and nontoxic bismuth salts. Triarylbismuthines are particularly interesting due to their air and moisture stability and high functional group tolerance. We report herein a detailed study on the preparation of highly functionalized triarylbismuth reagents by triple functional group manipulation and their use in palladium- and copper-catalyzed C-, N-, and O-arylation reactions.
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Colección:
01-internacional
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MEDLINE
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En
Revista:
J Org Chem
Año:
2016
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Article