Ultrasonic effect on RuO2 nanostructures prepared by direct calcination of two new Ru(II)-organic supramolecular polymers.

ABSTRACT

Two novel Ru(II) complexes [(η6-p-cymene)RuCl(L1)]PF6 (R1) and [(η6-C6H6)RuCl(L1)]PF6 (R3) with ligand (E)-4-(methylthio)-N-((quinolin-2-yl)methylene)benzenamine (L1), were synthesized and investigated using elemental analysis, IR, 1H NMR, 13C NMR spectroscopy and X-ray crystallography. Complexes R1 and R3 have coordination environments with formulated (η6-p-cymene)Ru(N2Cl) and (η6-C6H6)Ru(N2Cl) respectively. The thermal stabilities of compounds R1 and R3 were studied by thermal gravimetric (TG) and differential scanning calorimetry (DSC). The binding of the complexes R1 and R3 to calf thymus DNA (CT DNA) was investigated by using electronic absorption spectra, fluorescence and redox behavior studies. Such experimental data showed that there are interactions between complexes and CT-DNA and the nature of this binding is electrostatic interaction type. Calcination of ultrasonic treated R1 and R3 results in the formation of nanoparticles of RuO2. The nanoparticles were characterized by IR spectroscopy and X-ray diffraction (XRD). Also size and morphology of nanoparticles were investigated by scanning electron microscopy (SEM).