A route to robust thioether-functionalized MOF solid materials displaying heavy metal uptake and the ability to be further oxidized.

Xiao, Guo-Wei; Chen, Teng-Fei; Sun, Xin-Zhan; Guo, Hui; Li, Zhong-Feng; Deng, Yu-Heng; Wan, Chong-Qing

Xiao, Guo-Wei; Chen, Teng-Fei; Sun, Xin-Zhan; Guo, Hui; Li, Zhong-Feng; Deng, Yu-Heng; Wan, Chong-Qing.

Afiliación

Xiao GW; Beijing Key Laboratory for Optical Materials and Photonic Devices, Department of Chemistry, Capital Normal University, Beijing 100048, People's Republic of China. wancq@cnu.edu.cn.
Chen TF; Beijing Key Laboratory for Optical Materials and Photonic Devices, Department of Chemistry, Capital Normal University, Beijing 100048, People's Republic of China. wancq@cnu.edu.cn.
Sun XZ; Beijing Key Laboratory for Optical Materials and Photonic Devices, Department of Chemistry, Capital Normal University, Beijing 100048, People's Republic of China. wancq@cnu.edu.cn.
Guo H; Beijing Key Laboratory for Optical Materials and Photonic Devices, Department of Chemistry, Capital Normal University, Beijing 100048, People's Republic of China. wancq@cnu.edu.cn.
Li ZF; Beijing Key Laboratory for Optical Materials and Photonic Devices, Department of Chemistry, Capital Normal University, Beijing 100048, People's Republic of China. wancq@cnu.edu.cn.
Deng YH; Beijing Key Laboratory for Optical Materials and Photonic Devices, Department of Chemistry, Capital Normal University, Beijing 100048, People's Republic of China. wancq@cnu.edu.cn.
Wan CQ; Beijing Key Laboratory for Optical Materials and Photonic Devices, Department of Chemistry, Capital Normal University, Beijing 100048, People's Republic of China. wancq@cnu.edu.cn and State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Acade

Dalton Trans ; 46(36): 12036-12040, 2017 Sep 28.

Article en En | MEDLINE | ID: mdl-28853748

ABSTRACT

ABSTRACT

Here we developed a facile solvent-assisted ligand exchange method for synthesizing thioether-containing hybrid metal-organic frameworks (MOFs) that cannot be made using direct synthesis. Such a tailored approach provides an alternative method to achieve thioether-based MOFs and its oxidation-decorated materials. These materials showed the ability to take up heavy metals from solution and the ability to capture CO2.

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Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Dalton Trans Asunto de la revista: QUIMICA Año: 2017 Tipo del documento: Article

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