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An {As4 Cu4 [Cu(H2 O)]12 } Cluster Incorporated within Four [Nb7 O22 ]9- Units.
Li, Li; Dong, Kaili; Ma, Pengtao; Zhang, Chao; Niu, Jingyang; Wang, Jingping.
Afiliación
  • Li L; Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan, 475004, P.R. China.
  • Dong K; Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan, 475004, P.R. China.
  • Ma P; Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan, 475004, P.R. China.
  • Zhang C; Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan, 475004, P.R. China.
  • Niu J; Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan, 475004, P.R. China.
  • Wang J; Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan, 475004, P.R. China.
Chemistry ; 23(67): 16957-16960, 2017 Dec 01.
Article en En | MEDLINE | ID: mdl-29067735
ABSTRACT
A gigantic 16-copper-containing 28-niobate cluster, Na14 K7 H5 {As4 Cu4 [Cu(H2 O)]12 Nb28 O109 }⋅37.5 H2 O (1), has been prepared by a one-pot reaction, which is the first example of arsenic copper clusters containing polyoxoniobate, and the first tetrahedral arrangement of both the Cu cluster and the [Nb7 O22 ]9- subunits.
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Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Chemistry Asunto de la revista: QUIMICA Año: 2017 Tipo del documento: Article
Texto completo
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Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Chemistry Asunto de la revista: QUIMICA Año: 2017 Tipo del documento: Article