Synthesis of 3ß-tert-Butyldimethylsiloxy-22-phenylthio-23,24-bisnorchola-5,9(11)-diene and Reductive Nucleophilic Attack on a Branched Aliphatic Aldehyde.

Nagai, Toshiya; Hanaya, Kengo; Higashibayashi, Shuhei; Shoji, Mitsuru; Sugai, Takeshi

Nagai, Toshiya; Hanaya, Kengo; Higashibayashi, Shuhei; Shoji, Mitsuru; Sugai, Takeshi.

Afiliación

Nagai T; Department of Pharmaceutical Science, Keio University.
Hanaya K; Department of Pharmaceutical Science, Keio University.
Higashibayashi S; Department of Pharmaceutical Science, Keio University.
Shoji M; Department of Pharmaceutical Science, Keio University.
Sugai T; Department of Pharmaceutical Science, Keio University.

Chem Pharm Bull (Tokyo) ; 66(3): 334-338, 2018.

Article en En | MEDLINE | ID: mdl-29491266

Asunto(s)

Aldehídos/química; Androstenos/síntesis química; Ácidos Cólicos/química; Androstenos/química; Catálisis; Ácidos Cólicos/síntesis química; Complejos de Coordinación/química; Ácidos de Lewis/química; Litio/química; Oxidación-Reducción; Estereoisomerismo

Palabras clave

ene reaction; lithium di-tert-butylbiphenyl (LiDBB); phenyl sulfide; pregna-5,9(11),17(20)-triene; reductive nucleophilic attack

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Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Asunto principal: Ácidos Cólicos / Aldehídos / Androstenos Idioma: En Revista: Chem Pharm Bull (Tokyo) Año: 2018 Tipo del documento: Article

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