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Integral elastic, vibrational-excitation, electronic-state excitation, ionization, and total cross sections for electron scattering from para-benzoquinone.
Jones, D B; da Costa, R F; Kossoski, F; Varella, M T do N; Bettega, M H F; García, G; Blanco, F; White, R D; Lima, M A P; Brunger, M J.
Afiliación
  • Jones DB; College of Science and Engineering, Flinders University, GPO Box 2100, Adelaide, SA 5001, Australia.
  • da Costa RF; Instituto de Física "Gleb Wataghin," Universidade Estadual de Campinas, 13083-859 Campinas, São Paulo, Brazil.
  • Kossoski F; Instituto de Física "Gleb Wataghin," Universidade Estadual de Campinas, 13083-859 Campinas, São Paulo, Brazil.
  • Varella MTDN; Instituto de Física, Universidade de São Paulo, Rua do Matão 1731, 05508-090 São Paulo, São Paulo, Brazil.
  • Bettega MHF; Departamento de Física, Universidade Federal do Paraná, CP 19044, 81531-990 Curitiba, Paraná, Brazil.
  • García G; Instituto de Física Fundamental, CSIC, Serrano 113-bis, E-28006 Madrid, Spain.
  • Blanco F; Departamento de Física Atómica, Molecular y Nuclear, Universidad Complutense de Madrid, Madrid E-28040, Spain.
  • White RD; College of Science and Engineering, James Cook University, Townsville, Qld 4811, Australia.
  • Lima MAP; Instituto de Física "Gleb Wataghin," Universidade Estadual de Campinas, 13083-859 Campinas, São Paulo, Brazil.
  • Brunger MJ; College of Science and Engineering, Flinders University, GPO Box 2100, Adelaide, SA 5001, Australia.
J Chem Phys ; 148(20): 204305, 2018 May 28.
Article en En | MEDLINE | ID: mdl-29865824
We report absolute experimental integral cross sections (ICSs) for the electron impact excitation of 6 bands (Bands 0-V) of unresolved electronic-states in para-benzoquinone, for incident electron energies between 20 and 40 eV. Absolute vibrational-excitation ICSs, for 3 composite vibrational bands (Bands I-III), are also reported in that same energy range. In addition, ICSs calculated within our independent atom model (IAM) with screening corrected additivity rule (SCAR) formalism, extended to account for interference (I) terms that arise due to the multi-centre nature of the scattering problem, are also reported. The sum of those ICSs gives the IAM-SCAR+I total cross section (TCS) for electron-para-benzoquinone scattering. Where possible, those calculated IAM-SCAR+I ICSs are compared against corresponding results from the present measurements with an acceptable level of accord being obtained. Similarly, we also present results from our Schwinger multichannel method with pseudopotential (SMCPP) calculations. Here elastic ICSs and ICSs corresponding to the Bands 0-III of unresolved electronic-states are presented, with agreement between the SMCPP electronic-state ICSs and those from our measurements being in good qualitative accord. The energy range of our SMCPP computations is 16-50 eV. Using the binary-encounter-Bethe (BEB) approach, total ionization cross sections for this collision system were computed. Those total ionization cross sections were then added to our SMCPP ICS results, to derive SMCPP/BEB TCSs that are typically in very good accord with those from our IAM-SCAR+I approach.

Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Tipo de estudio: Qualitative_research Idioma: En Revista: J Chem Phys Año: 2018 Tipo del documento: Article País de afiliación: Australia

Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Tipo de estudio: Qualitative_research Idioma: En Revista: J Chem Phys Año: 2018 Tipo del documento: Article País de afiliación: Australia